File name: Pandora156s1_HamptonVA-HU_20230323_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T175701.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230323_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230323 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230323T121444.1Z 8482.510233 69 1 48.10 2 76.90 98.75 90.47 78.52 0.00 1 0.00 1 0 33 6.739e-01 1.786e-01 4.787e-01 1.363e-01 5.510295e-01 7.875049e-02 9.615492e-03 -6.000000e+00 4.170615e-01 227.23 -2.00 3.43 -2.00 319.59 0.00e+00 3.880616e-02 1.872207e-02 8.455040e-03 -6.000000e+00 2.400091e-02 280.74 -2.00 20.00 -2.00 318.94 0.00e+00 4.300 0.001 302.00 328.00 3 5.4806e+00 2.1469e-01 5.9503e-02 -6.0000e+00 1.0530e+00 1.2147e+00 2.4358e-01 4.0248e-02 -6.0000e+00 1.1614e+00 -9.7459e-01 1.4437e-01 1.9895e-02 -6.0000e+00 6.7390e-01 4.1434e-01 7.5809e-02 7.6724e-03 -6.0000e+00 2.7823e-01 8.2564e-06 -1.7076e-02 4.0962e-03 2.0258e-04 -6.0000e+00 2.2174e-02 -7.7650e-03 4.6919e-04 12 9 8 11 8 0 82.83 22.81 4.90 -0.00777 -0.13608 22 6 1 5 0 2185.870 25.79 19.99 22.81 18.39 13.0 1044.82 53656 -7772 900000 900000 900000 -21245 900000 -23371 900000 900000 900000 15241 30608 900000 900000 900000 74723 900000 51485 900000 368978 900000 17740 900000 -38378 900000 -51065 900000 900000 900000 85454 900000 900000 900000 900000 -82873 900000 9509 90022 35658 900000 -2096 228381 41390 900000 71527 246518 900000 22600 109952 900000 109509 37818 152237 14165 101527 -42176 64980 -2379 900000 -7828 106108 184491 86577 51084 5978 900000 68950 175321 24844 67529 -8758 69820 -16891 41686 36421 74995 9244 30399 2146 3515 -4878 -11866 -17800 18264 22085 -24913 24630 -15811 -7701 -33034 16593 -4512 49559 -20326 -13120 14383 6458 16277 8797 44394 -17581 15205 -1024 15672 6223 10053 -3008 -17381 23602 11108 -6920 7207 4289 -3111 17600 -11104 15801 -7977 7270 -8168 17378 11482 22158 -9524 -2470 14867 6753 -71 -21857 8763 -7307 -1083 -15620 7402 -7836 13017 -8665 -2319 8284 26521 -2800 12894 -10650 7090 -1622 900000 900000 900000 -5023 900000 -3738 900000 900000 900000 2014 4044 900000 900000 900000 9874 900000 8693 900000 48755 900000 3776 900000 -10706 900000 -12370 900000 900000 900000 11291 900000 900000 900000 900000 -48668 900000 1955 11895 6652 900000 -600 30177 8686 900000 12231 32574 900000 7026 14528 900000 15321 11464 20116 5835 17361 -27555 14647 -999 900000 -3286 14845 24378 18169 17074 3346 900000 19293 23166 10621 20470 -6194 23336 -13260 17173 14437 18070 3880 9924 984 1830 -3223 -9500 -16464 12351 14934 -28272 17804 -17696 -8021 -43393 12510 -3858 22727 -18011 -11320 10621 5973 15688 10188 37612 -26783 15246 -1083 13155 5853 9611 -3437 -24182 23298 13555 -11080 10700 6668 -5054 21888 -17262 18176 -11842 9719 -13395 22557 15528 25833 -14583 -3359 16177 7611 -84 -33807 11034 -11870 -1768 -30716 11967 -15408 21753 -18521 -4704 15131 39578 -5331 19643 -19287 SS 20230323T122432.2Z 8482.517039 72 1 45.14 2 74.97 100.31 88.58 79.90 0.00 1 0.00 1 0 17 2.031e-01 7.206e-03 1.687e-01 5.329e-03 4.645629e-01 2.790498e-03 5.180007e-03 -6.000000e+00 1.178853e-01 227.23 -2.00 3.43 -2.00 320.39 0.00e+00 -1.700994e-04 9.928417e-04 4.656744e-04 -6.000000e+00 5.182489e-03 280.74 -2.00 20.00 -2.00 319.75 0.00e+00 3.781 0.001 302.00 328.00 3 2.9793e+00 8.4281e-03 4.4470e-02 -6.0000e+00 2.9246e-01 5.7147e-02 1.0320e-02 2.3880e-02 -6.0000e+00 3.1814e-01 -2.0386e-02 8.8685e-03 1.1791e-02 -6.0000e+00 1.8948e-01 -1.0800e-03 4.4829e-03 3.3422e-03 -6.0000e+00 7.8977e-02 3.6113e-04 -6.8978e-04 1.6837e-04 4.3136e-05 -6.0000e+00 5.8587e-03 4.2222e-03 9.3363e-06 12 9 1 12 1 1 99.79 22.81 0.37 0.00422 -0.00096 37 11 1 5 0 1183.190 25.79 20.00 22.81 18.98 13.0 1049.52 -88528 18983 15543 -35982 -84424 -64801 18187 -56278 -17350 -37055 116678 115272 -3542 -15777 2565 -49 -26549 -10241 -21852 -6102 -9957 6086 1624 116 -19772 3826 -128 -12700 396 -17199 -4050 6484 -2876 2080 8192 -8555 -2031 -4181 1475 -1697 6013 -1744 2194 151 2316 18757 2809 -1774 1317 3169 -457 -711 3521 4210 1177 2396 -4670 -1718 1064 703 1669 1699 890 442 2476 897 2012 -1502 -607 -307 1634 -1108 -3 154 968 1257 -333 864 -1072 -18 -1746 -1220 -529 -1145 -1039 -1006 173 276 252 444 371 -1855 -1501 318 1191 895 -43 629 635 219 -613 -734 355 736 -524 -570 -473 -290 -665 132 -248 229 -153 -151 -131 874 -419 -307 189 -228 -221 -64 281 29 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1.180574e-03 -6.000000e+00 2.142759e-03 280.74 -2.00 20.00 -2.00 319.35 0.00e+00 3.406 0.001 302.00 328.00 3 3.2171e+00 8.1158e-03 4.0403e-02 -6.0000e+00 1.2092e-01 2.6106e-02 9.7491e-03 2.2611e-02 -6.0000e+00 1.3154e-01 1.5743e-02 8.0228e-03 1.0859e-02 -6.0000e+00 7.8345e-02 -1.7821e-02 4.1161e-03 2.9510e-03 -6.0000e+00 3.2650e-02 4.3364e-04 -8.9276e-04 1.7000e-04 4.0594e-05 -6.0000e+00 2.4226e-03 4.3738e-03 -1.8375e-05 12 9 1 12 1 1 99.95 22.81 0.49 0.00437 -0.00233 19 11 1 5 0 1146.700 25.79 20.00 22.81 19.19 13.1 1051.68 -18164 -19285 -40385 -35248 18357 -52857 -15358 -6420 -13160 24843 -14747 3560 7445 20038 -11708 13677 606 -1579 2177 4572 1138 5860 -4386 -1572 8469 -9280 5618 9994 -4776 -2810 -3844 385 13960 -5276 -2444 -4730 -4741 -7340 249 -4994 -979 -1502 -4129 210 -510 -1261 147 935 1048 1806 -2178 2012 2480 -804 -569 1658 -836 807 1526 943 1841 2315 29 650 1228 -1019 1313 -624 838 933 415 1089 744 638 239 1327 -865 493 358 173 -732 -772 -1801 -409 -1810 -817 -112 -733 -236 980 -118 780 1925 -550 864 1485 483 879 919 -737 273 -230 -1337 3 -74 -354 -281 -918 -792 217 -1012 -39 310 -494 72 363 -153 -461 -219 -446 -204 -240 -554 648 791 200 1274 783 731 655 -46 24 813 151 777 22 -573 -44 -223 258 -137 -356 -619 -58 -286 -351 -961 -777 218 -1240 -263 -115 -286 400 -367 79 182 519 -496 517 29 -82 116 250 67 330 -283 -106 557 -773 411 679 -359 -208 -311 34 1192 -584 -258 -500 -534 -987 37 -947 -202 -336 -991 49 -122 -306 35 222 251 440 -588 568 756 -272 -203 600 -319 306 566 347 681 906 13 311 613 -509 607 -288 400 498 248 690 482 402 142 712 -430 229 171 93 -453 -539 -1399 -334 -1592 -761 -110 -756 -245 989 -114 692 1565 -441 707 1331 492 1004 1150 -970 344 -270 -1462 3 -82 -418 -349 -1210 -1104 324 -1649 -67 532 -825 112 528 -216 -666 -331 -718 -339 -400 -904 1012 1184 287 1736 1048 1021 998 -77 42 1479 287 1548 44 -1200 -95 -485 554 -286 -711 -1270 -118 SS 20230323T124831.2Z 8482.533694 85 1 46.73 2 70.29 104.23 83.94 83.26 0.00 1 0.00 1 0 25 2.207e-02 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