File name: Pandora156s1_HamptonVA-HU_20230422_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T181244.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230422_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230422T112352.0Z 8512.474908 61 1 14.62 2 78.76 83.11 94.22 58.26 0.00 1 0.00 1 0 25 4.300e-01 1.103e-02 2.785e-01 6.141e-03 6.171399e-01 3.385079e-03 6.738763e-03 -6.000000e+00 2.528621e-01 229.55 -2.00 3.43 -2.00 321.23 0.00e+00 -3.301315e-03 1.655993e-03 9.347911e-04 -6.000000e+00 1.178589e-02 283.61 -2.00 20.00 -2.00 320.64 0.00e+00 4.952 0.002 302.00 328.00 3 1.2673e+00 1.1664e-02 5.9066e-02 -6.0000e+00 6.2992e-01 5.7603e-02 1.6010e-02 3.2873e-02 -6.0000e+00 6.8388e-01 -7.4965e-02 1.5721e-02 1.7178e-02 -6.0000e+00 4.0788e-01 2.5434e-02 7.4140e-03 5.7200e-03 -6.0000e+00 1.7176e-01 5.6459e-04 -6.9807e-04 1.9006e-04 7.5381e-05 -6.0000e+00 1.2591e-02 -2.3804e-03 4.9246e-05 12 9 9 12 1 1 52.92 23.96 0.54 -0.00238 -0.00763 33 30 1 5 0 424.800 26.73 20.00 23.96 24.90 13.9 1051.16 -238463 900000 900000 -152537 900000 -63538 -34633 -55569 -109217 -145852 -35414 -43439 -136941 216162 -69847 900000 116570 -63361 -26123 96806 -37623 900000 25533 -35011 -5209 19021 6395 -54330 53061 -34937 77164 -32230 1771 33694 -4095 -16089 -6208 -9543 13921 11939 -11455 -26 11377 -3113 3009 7000 -1435 22800 1853 -4256 8649 6463 6595 13175 913 -254 6104 6383 -5975 7788 -2900 9763 4285 -1877 5838 3154 -1225 -2933 -2088 3542 5218 1288 -881 477 -1295 1423 312 -4983 1178 3130 -993 -650 -845 -1100 1098 -930 -1846 -586 555 -1459 1267 -783 2580 2566 12 127 1130 -409 122 -58 -1274 -565 825 -834 -1216 -1250 -2061 -290 -1222 -497 835 267 -418 744 -469 888 529 -922 -588 814 -475 -106 497 -732 1355 391 734 1069 515 675 748 -203 52 34 -41 -427 375 -374 42 261 -674 347 72 -654 -4816 900000 900000 -1765 900000 -380 -207 -333 -1133 -2444 -212 -312 -3005 1294 -1198 900000 698 -1517 -469 579 -841 900000 326 -908 -112 349 138 -2102 726 -1101 957 -1312 59 901 -160 -700 -263 -491 700 748 -1051 -2 962 -313 287 648 -147 1865 194 -501 980 838 947 1940 164 -49 1152 1222 -1275 1414 -589 1858 961 -502 1558 871 -345 -848 -641 1167 1907 526 -375 194 -501 486 98 -1600 376 1120 -434 -326 -475 -671 699 -646 -1374 -449 426 -1124 902 -532 1599 1569 8 96 969 -407 135 -67 -1457 -593 779 -765 -1161 -1275 -2241 -329 -1502 -667 1226 400 -653 1134 -738 1307 760 -1368 -912 1315 -798 -176 789 -1136 1986 556 1002 1436 738 1078 1327 -369 99 69 -88 -981 893 -918 103 639 -1594 768 151 -1373 SS 20230422T112908.7Z 8512.478573 64 1 11.43 2 77.71 83.88 93.35 59.05 0.00 1 0.00 1 0 25 3.080e-01 7.677e-03 1.388e-01 4.292e-03 5.709208e-01 2.298501e-03 6.218065e-03 -6.000000e+00 1.805068e-01 229.55 -2.00 3.43 -2.00 320.97 0.00e+00 2.413327e-03 1.029057e-03 3.908829e-04 -6.000000e+00 7.959058e-03 283.61 -2.00 20.00 -2.00 320.35 0.00e+00 4.561 0.002 302.00 328.00 3 9.3985e-01 7.5254e-03 5.4319e-02 -6.0000e+00 4.4986e-01 8.3666e-02 9.8437e-03 3.0017e-02 -6.0000e+00 4.8808e-01 -6.3889e-02 9.2438e-03 1.5096e-02 -6.0000e+00 2.9068e-01 1.5117e-02 4.4812e-03 5.2211e-03 -6.0000e+00 1.2107e-01 1.1497e-03 -9.0203e-04 1.3122e-04 5.9598e-05 -6.0000e+00 8.8891e-03 -2.3786e-03 4.9232e-05 12 9 1 12 1 1 45.07 23.97 0.23 -0.00238 -0.00916 41 47 1 5 0 267.850 26.73 20.00 23.97 25.18 13.8 1053.23 -126450 -75199 -58995 -59302 -110641 -105895 -67656 -76107 -93020 -126998 -71244 -107117 -29256 -117721 -56091 -18084 -59012 -15325 -19881 -23158 -12375 197 -12649 -15092 -14825 37824 -8611 18645 -13246 -2082 3669 -5054 2424 5581 -5937 -1538 -8374 8754 4380 1222 299 778 2145 1842 3337 -445 1224 1886 3918 -526 1610 1284 8816 1367 1780 2090 4980 3766 487 117 3842 3896 3009 1819 1580 2127 690 218 -1025 1193 1237 -501 182 1393 -247 -119 1269 -451 -727 171 -310 -1725 -855 -1408 -990 -1065 -663 334 399 148 107 210 124 456 124 -191 748 1034 -456 563 -46 -341 -1126 -1574 -1329 -273 -1530 -672 -403 -87 -325 122 -167 84 214 328 113 81 395 -75 481 -166 -70 -46 253 610 912 642 747 952 190 206 62 -23 -244 -180 -365 133 -313 92 97 15 -446 -75 -1437 -607 -441 -477 -1290 -1140 -566 -784 -1196 -2506 -918 -2018 -330 -3766 -1208 -344 -1782 -355 -487 -623 -335 5 -358 -471 -501 804 -299 486 -465 -68 128 -226 116 284 -338 -82 -510 522 308 107 30 85 246 219 398 -56 155 242 508 -75 244 217 1521 276 382 468 1121 868 114 27 868 941 819 560 524 704 225 71 -360 462 539 -238 88 641 -108 -47 452 -157 -267 71 -151 -978 -536 -954 -711 -818 -538 280 340 124 85 156 86 310 89 -155 689 1085 -540 692 -56 -382 -1157 -1555 -1356 -294 -1765 -815 -522 -123 -474 191 -270 133 322 499 167 122 623 -118 770 -266 -109 -73 389 895 1284 891 1094 1547 321 375 120 -46 -523 -409 -870 323 -774 224 227 33 -950 -158 SS 20230422T113415.0Z 8512.482118 67 1 46.81 2 76.70 84.63 92.49 59.79 0.00 1 0.00 1 0 25 1.938e-01 5.175e-03 1.204e-01 2.283e-03 5.344560e-01 1.228841e-03 5.893337e-03 -6.000000e+00 1.135893e-01 229.55 -2.00 3.43 -2.00 320.93 0.00e+00 7.114757e-05 5.319003e-04 9.983838e-04 -6.000000e+00 5.008748e-03 283.61 -2.00 20.00 -2.00 320.29 0.00e+00 4.237 0.001 302.00 328.00 3 8.1297e-01 4.0097e-03 5.0870e-02 -6.0000e+00 2.8309e-01 2.2179e-02 5.1992e-03 2.8901e-02 -6.0000e+00 3.0716e-01 -8.2995e-03 4.8663e-03 1.4011e-02 -6.0000e+00 1.8293e-01 -6.6605e-03 2.3732e-03 4.0234e-03 -6.0000e+00 7.6177e-02 1.8946e-03 -6.6970e-04 7.1967e-05 5.1926e-05 -6.0000e+00 5.5949e-03 -1.6565e-03 2.9557e-05 10 0 0 10 0 0 97.32 23.97 0.31 -0.00166 -0.00669 276 74 1 5 0 169.540 26.73 20.00 23.97 25.35 13.9 1054.95 -82304 -26796 20015 -16350 -101986 -86257 -4325 -69053 -588 -52426 81207 -62163 19771 -58345 -3842 -39791 4408 4722 12799 -12516 12162 -6771 -12104 -12296 -8217 -7243 -15588 -3658 -5656 9231 -4422 13733 -7490 1041 -13182 2094 -12131 -3065 -931 4321 -4062 2030 -645 -884 -786 1434 -2155 -534 -2159 2403 987 1443 3585 1562 -348 -253 -711 -1337 1485 1758 3112 1221 2717 2092 1376 -510 960 -432 659 430 2414 -36 487 606 795 -691 726 255 374 -376 13 -447 -1570 -1564 -1601 -955 -388 624 -105 573 -272 1617 285 668 -214 1358 413 558 -124 262 -304 -179 -379 -492 -725 -635 -699 -1137 -96 -231 -2 -145 320 -300 300 -115 637 -236 33 52 28 -331 -318 81 93 400 609 811 422 657 119 544 -203 22 -302 -8 -127 190 -137 15 -129 52 -11 -293 -702 -154 78 -91 -1249 -880 -21 -730 -4 -593 256 -900 150 -1202 -56 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