File name: Pandora156s1_HamptonVA-HU_20230521_L2Fit_fout2c2d20220209p1-8.txt File generation date: 20240202T172204.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v2d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230521_L1_smca1c2d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaLab+Fld 1.8 VP 20220209 First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230521T150617.8Z 8541.629372 237 1 18.72 2 30.25 115.73 46.44 86.16 0.00 1 0.00 1 0 17 8.692e-03 5.841e-03 3.258e-03 1.692e-03 1.724320e-01 8.774105e-04 2.032840e-03 -6.000000e+00 5.132810e-03 231.58 -2.00 3.43 -2.00 316.12 0.00e+00 1.393776e-04 9.496148e-05 2.427750e-05 -6.000000e+00 2.273825e-04 286.50 -2.00 20.00 -2.00 315.35 0.00e+00 1.157 0.000 302.00 328.00 3 3.8506e+00 2.2949e-03 1.4621e-02 -6.0000e+00 1.2843e-02 3.0722e-02 2.5616e-03 8.8022e-03 -6.0000e+00 1.3905e-02 7.6754e-04 1.4615e-03 4.2725e-03 -6.0000e+00 8.2822e-03 -3.5088e-03 6.5617e-04 1.1682e-03 -6.0000e+00 3.4453e-03 2.9605e-03 2.0467e-04 5.1403e-05 1.5433e-05 -6.0000e+00 2.5101e-04 -4.2909e-04 1.4052e-04 12 1 1 12 1 1 99.98 23.76 0.31 -0.00043 0.00111 35 24 1 5 0 515.060 26.51 20.00 23.76 25.26 14.4 1027.82 -603 377 -2810 -2110 -3863 -1326 547 1831 849 -720 -1444 584 -529 509 -1322 -212 -346 85 740 389 636 108 983 1041 746 408 221 -401 744 925 1903 2395 785 606 -912 -756 -1230 -855 -693 46 -718 -89 -1129 -779 -1769 -771 -1038 -1167 -566 -696 213 1052 1246 1320 1086 334 909 383 212 869 956 657 1899 926 1195 429 -480 -444 -649 747 299 286 -43 162 -11 336 351 107 -69 -167 -549 -1241 -983 -1351 -1137 -1293 -368 -504 -36 -316 84 25 72 -103 832 1045 839 538 165 195 -140 -309 -345 -153 -668 -220 -524 -502 -309 70 -254 -71 -115 -216 17 -55 228 209 409 200 47 -226 -174 121 669 727 996 773 775 803 505 477 93 48 -75 -87 -287 122 -238 -189 -78 -552 -280 -518 -126 84 -658 -494 -821 -256 106 387 200 -181 -363 143 -139 148 -435 -75 -126 32 280 151 252 43 387 424 319 181 98 -170 289 340 698 919 324 258 -377 -299 -511 -403 -385 28 -482 -63 -822 -571 -1305 -559 -739 -803 -373 -450 148 717 893 986 838 265 725 308 169 679 758 549 1680 876 1141 390 -401 -371 -514 640 285 289 -45 164 -11 297 297 83 -53 -137 -470 -1179 -1005 -1457 -1293 -1579 -445 -638 -46 -401 106 29 76 -101 798 1063 938 662 207 250 -184 -380 -396 -173 -805 -284 -712 -670 -428 101 -385 -110 -177 -313 24 -72 283 261 538 282 67 -325 -247 177 926 954 1236 925 939 1024 681 665 133 70 -107 -131 -450 197 -392 -310 -125 -862 -424 -778 SS 20230521T151048.7Z 8541.632508 240 1 48.14 2 29.44 117.10 45.56 86.76 0.00 1 0.00 1 0 17 2.402e-02 1.108e-02 1.617e-02 7.426e-03 1.777586e-01 3.847965e-03 2.052936e-03 -6.000000e+00 1.417230e-02 231.58 -2.00 3.43 -2.00 316.56 0.00e+00 4.303843e-05 4.572916e-04 3.711267e-05 -6.000000e+00 6.279333e-04 286.50 -2.00 20.00 -2.00 315.73 0.00e+00 1.148 0.000 302.00 328.00 3 6.4700e+00 1.0149e-02 1.4680e-02 -6.0000e+00 3.5462e-02 5.7979e-02 1.1362e-02 8.9847e-03 -6.0000e+00 3.8405e-02 -1.2901e-03 6.5080e-03 4.3542e-03 -6.0000e+00 2.2873e-02 -2.0144e-03 2.9464e-03 1.1861e-03 -6.0000e+00 9.5071e-03 2.1302e-04 -1.0476e-04 2.3151e-04 1.5421e-05 -6.0000e+00 6.9373e-04 6.8846e-04 -2.4213e-05 12 8 8 10 0 0 99.78 23.76 0.78 0.00069 -0.00010 13 3 1 5 0 3702.180 26.62 20.00 23.76 25.42 14.5 1030.29 -4287 -11663 -10923 5341 4217 -715 -6693 784 -5234 5033 -4677 2286 1313 9011 -736 4486 -177 826 -1065 4922 930 2080 1557 2240 1843 -2094 1258 1296 -3403 4329 1883 1461 3780 676 3829 -1197 -2186 -2796 2267 208 -1142 -539 -262 -1340 -1167 -1579 1403 -615 682 -2152 108 -1342 1382 154 155 438 1370 340 314 -1231 1339 1116 374 299 746 224 -2515 -847 -574 1670 634 -453 1828 -906 -276 800 -504 -757 1755 -1010 -474 -1196 -1109 -933 -987 15 449 1308 -738 -149 -263 413 -852 -1288 -703 716 744 327 1 -364 3710 -1364 -618 -1436 -627 244 -1494 -339 1274 -679 831 415 272 80 -200 467 -1519 -284 -262 -1153 -321 1375 1312 -153 839 1292 -1832 169 1439 995 -1170 1198 -816 -1169 924 712 -879 219 73 -112 352 -127 -283 -597 -845 -2670 -2511 980 698 -116 -1189 143 -1117 1016 -1030 468 290 2054 -206 1287 -55 259 -350 1562 312 687 520 769 665 -811 470 458 -1167 1400 630 517 1383 262 1375 -434 -839 -1231 1123 122 -751 -370 -184 -960 -831 -1119 944 -407 430 -1368 69 -911 961 113 117 336 1056 265 241 -951 1024 900 326 275 692 197 -2068 -644 -441 1377 584 -448 1797 -897 -258 677 -387 -535 1190 -755 -392 -1098 -1096 -968 -1082 17 553 1665 -973 -192 -320 457 -865 -1218 -658 703 801 388 2 -478 4498 -1620 -681 -1579 -723 299 -1959 -459 1762 -1002 1266 652 420 117 -270 574 -1961 -366 -356 -1576 -459 1964 1849 -228 1182 1716 -2381 208 1767 1293 -1635 1692 -1194 -1750 1410 1148 -1502 380 128 -199 605 -213 -460 -966 SS 20230521T152054.1Z 8541.639515 243 1 4.60 2 27.67 120.40 43.59 88.12 0.00 1 0.00 1 0 17 7.469e-03 5.687e-03 7.011e-04 4.392e-04 1.670525e-01 2.304961e-04 1.974185e-03 -6.000000e+00 4.409709e-03 231.58 -2.00 3.43 -2.00 315.33 0.00e+00 1.820040e-04 2.124153e-05 1.947241e-05 -6.000000e+00 1.953541e-04 286.51 -2.00 20.00 -2.00 314.64 0.00e+00 1.129 0.000 302.00 328.00 3 3.3382e-01 5.9751e-04 1.4215e-02 -6.0000e+00 1.1034e-02 1.9354e-02 6.6324e-04 8.5114e-03 -6.0000e+00 1.1947e-02 -3.1959e-05 3.7803e-04 4.1288e-03 -6.0000e+00 7.1159e-03 -3.4598e-03 1.6539e-04 1.1297e-03 -6.0000e+00 2.9594e-03 1.0419e-01 5.5461e-06 1.3242e-05 1.5932e-05 -6.0000e+00 2.1569e-04 -2.1131e-04 9.1531e-05 12 1 1 12 1 1 96.82 23.77 0.31 -0.00021 -0.00017 179 502 1 5 0 23.510 26.51 20.00 23.77 26.41 14.3 1036.41 -705 -626 -1435 -1923 -3205 -1685 -247 1391 1230 -83 -854 -660 -435 350 538 584 173 134 408 385 223 165 635 499 718 305 351 -308 -99 700 1158 1775 1437 447 -1177 -1189 -1154 -299 -111 136 -607 -788 -1243 -1113 -1072 -686 -853 -731 -624 -577 466 874 1071 1008 871 431 965 504 306 390 1016 1018 1518 868 798 234 -610 -286 -202 729 344 170 -32 154 -65 238 50 -26 -51 57 -382 -852 -1165 -1461 -1239 -1358 -528 -498 -238 -268 53 225 371 371 575 712 794 584 81 15 -252 -277 -357 -109 -443 -167 -671 -498 -445 -267 -80 11 -29 10 36 90 371 195 365 127 29 -224 -147 302 539 727 974 1023 881 644 351 376 -44 25 -126 -84 -144 104 -196 -295 -270 -204 -512 -539 -195 -187 -438 -556 -838 -445 -66 401 357 -26 -263 -202 -141 125 214 251 77 61 190 184 108 80 307 250 376 152 190 -159 -47 314 521 834 716 231 -592 -573 -582 -170 -68 97 -445 -609 -991 -895 -859 -543 -662 -546 -487 -440 359 704 837 823 734 371 837 441 264 334 876 923 1468 830 773 232 -554 -243 -173 679 330 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