File name: Pandora156s1_HamptonVA-HU_20230612_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T183647.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230612_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230612T112833.4Z 8563.478164 199 1 6.34 2 71.86 74.28 37.36 152.66 0.00 1 0.00 1 0 17 4.593e-01 2.403e-02 2.605e-01 1.818e-02 4.584590e-01 9.724338e-03 5.033557e-03 -6.000000e+00 2.754760e-01 232.67 -2.00 3.43 -2.00 319.93 0.00e+00 -3.315549e-03 3.078847e-03 5.108470e-04 -6.000000e+00 1.309729e-02 288.57 -2.00 20.00 -2.00 319.14 0.00e+00 3.169 0.000 302.00 328.00 3 4.3186e+00 2.8797e-02 3.9808e-02 -6.0000e+00 6.9061e-01 4.3185e-02 3.4524e-02 2.4401e-02 -6.0000e+00 7.4819e-01 -4.5213e-02 2.6872e-02 1.1472e-02 -6.0000e+00 4.4203e-01 2.1451e-02 1.3734e-02 4.4569e-03 -6.0000e+00 1.8499e-01 1.6921e-04 -2.1445e-04 5.7315e-04 4.2013e-05 -6.0000e+00 1.3785e-02 -4.5759e-03 -1.7951e-07 12 9 9 12 1 1 999.00 24.22 0.75 -0.00458 -0.00619 1 4 1 5 0 3078.880 26.94 20.00 24.22 30.48 14.9 1057.23 900000 -123004 275559 900000 900000 900000 -100289 52578 900000 -43573 -53230 12129 30380 47360 45695 949 14711 -37570 35343 -22304 28933 -61421 59678 -8473 49175 367161 -30589 -23537 76785 2166 55126 -6575 -8315 13688 -2848 14360 8949 39501 5844 26350 7719 12857 -11437 7641 7 17174 4603 13865 -9359 2128 -8887 -1826 12165 225 1380 -5819 7849 1406 6197 -3450 2936 13387 7893 -6117 -456 1057 5452 7345 460 1956 5378 -820 -515 -4453 -1393 1275 776 -7008 -11745 6239 1464 2594 -986 -4222 -2357 -2713 2773 79 -3110 -843 1500 -2872 3070 151 -4374 366 -1724 1197 925 -385 -47 679 -1291 1932 -960 2800 -184 1839 1010 -831 -1585 2090 -1166 -2478 -1109 1362 3491 866 683 -65 -1105 538 1206 -953 -763 1366 3275 -940 -14 -1145 847 -964 1389 -1504 128 191 302 -665 -1148 1753 917 -525 -500 -659 900000 -6175 4882 900000 900000 900000 -3949 932 900000 -1415 -1991 251 598 987 1079 40 594 -2737 1322 -1559 1253 -6650 2115 -609 2306 6505 -3282 -2270 2721 160 2585 -608 -876 1239 -300 1317 923 3499 834 3683 1481 2531 -2994 1685 2 3448 1046 2866 -2460 513 -2554 -535 3377 76 488 -2308 2812 544 2251 -1351 1087 4717 3224 -3149 -234 523 2458 3195 225 1057 3144 -545 -348 -3050 -869 705 391 -3614 -6520 3230 914 1813 -788 -3531 -2057 -2545 2614 80 -3289 -857 1410 -2614 2584 126 -3961 330 -1794 1361 1161 -508 -60 796 -1420 1993 -1064 3198 -228 2354 1383 -1187 -2476 3340 -1953 -4084 -1699 1907 4864 1256 990 -100 -1792 856 1856 -1450 -1169 1959 4410 -1290 -19 -1790 1343 -1655 2427 -2813 248 374 616 -1403 -2463 3623 1844 -1020 -977 -1272 SS 20230612T120735.2Z 8563.505269 221 1 5.08 2 64.27 79.44 34.62 168.31 0.00 1 0.00 1 0 17 7.529e-02 1.222e-02 6.689e-02 1.024e-02 3.400448e-01 5.332904e-03 3.873787e-03 -6.000000e+00 4.464419e-02 232.67 -2.00 3.43 -2.00 318.47 0.00e+00 1.300273e-04 1.081158e-03 4.026996e-04 -6.000000e+00 2.065972e-03 288.58 -2.00 20.00 -2.00 317.61 0.00e+00 2.289 0.000 302.00 328.00 3 4.2936e+00 1.4637e-02 2.8964e-02 -6.0000e+00 1.1193e-01 5.7521e-02 1.6702e-02 1.7569e-02 -6.0000e+00 1.2105e-01 -6.9158e-03 1.0829e-02 8.4168e-03 -6.0000e+00 7.2121e-02 -4.9399e-03 5.5316e-03 2.2587e-03 -6.0000e+00 3.0071e-02 4.6348e-04 -2.2587e-04 3.1593e-04 2.5982e-05 -6.0000e+00 2.1786e-03 -3.8641e-03 -1.9332e-06 12 9 9 12 1 1 999.00 24.22 0.42 -0.00386 -0.00556 1 5 1 5 0 2452.370 26.94 20.00 24.22 30.53 15.1 1057.43 -9785 41854 -4575 12315 -15594 -7509 4788 -27321 15858 -1011 39146 900000 29102 -32733 -5856 -5699 3329 1821 -8491 2110 -5962 12680 1110 508 10048 -2260 2383 -1746 -11240 -3039 -2013 5557 3406 -693 1928 -2802 -2911 1498 1211 -5313 5329 -4789 638 -3471 2276 1798 -1391 1427 -692 -1333 631 1462 1307 1783 -345 1928 620 3289 -689 564 2417 1958 1821 374 290 2143 667 2539 -162 556 768 10 -539 -231 1240 -1377 -737 -1467 -2302 -1831 -624 -1133 -2023 -1208 -1554 -2271 720 -503 1446 1890 1600 -1792 -781 283 72 1185 776 612 -4457 754 -911 128 458 -563 -1208 -563 260 273 691 331 500 489 -205 -137 -209 491 -216 2068 1315 -151 106 441 -346 -815 -276 180 -712 1329 -412 1056 -268 602 -527 -25 -157 1153 -376 -418 -371 800 50 -594 -341 -440 -499 1430 -260 570 -869 -367 216 -1910 809 -65 1729 900000 1652 -4026 -640 -701 402 236 -1281 298 -940 1666 167 81 1558 -416 423 -311 -2080 -508 -351 990 680 -152 402 -594 -652 369 359 -1889 1913 -2033 266 -1539 956 759 -603 593 -291 -569 277 685 658 948 -196 1104 368 1915 -411 328 1398 1203 1220 262 210 1476 457 1647 -111 401 615 8 -475 -198 990 -1030 -519 -972 -1551 -1348 -490 -1002 -1882 -1183 -1618 -2549 833 -588 1683 2152 1808 -1931 -766 272 71 1193 875 737 -6161 1020 -1212 157 540 -653 -1480 -702 338 373 988 485 782 768 -325 -218 -308 699 -297 2818 1898 -226 165 689 -533 -1222 -411 255 -967 1793 -557 1513 -400 939 -857 -41 -264 2022 -698 -797 -690 1523 93 -1069 -589 -752 SS 20230612T121526.9Z 8563.510728 227 1 47.24 2 62.73 80.49 34.32 171.68 0.00 1 0.00 1 0 17 1.726e-02 4.593e-03 5.989e-03 9.073e-04 3.197549e-01 4.706352e-04 3.648656e-03 -6.000000e+00 1.023674e-02 232.67 -2.00 3.43 -2.00 318.73 0.00e+00 1.836138e-04 1.011948e-04 1.245162e-04 -6.000000e+00 4.555836e-04 288.58 -2.00 20.00 -2.00 317.87 0.00e+00 2.171 0.000 302.00 328.00 3 1.8354e+00 1.3040e-03 2.7380e-02 -6.0000e+00 2.5666e-02 2.0452e-02 1.4953e-03 1.6500e-02 -6.0000e+00 2.7753e-02 2.8289e-03 9.8315e-04 7.9616e-03 -6.0000e+00 1.6536e-02 -7.6814e-03 5.0170e-04 2.1662e-03 -6.0000e+00 6.8798e-03 6.3777e-03 -3.2674e-04 2.8224e-05 2.4552e-05 -6.0000e+00 4.9873e-04 -3.5785e-03 6.6726e-05 10 0 0 10 0 0 99.12 24.22 0.32 -0.00358 -0.00603 297 80 1 5 0 159.030 26.94 19.99 24.22 30.37 15.1 1057.36 -5700 -1780 -8489 -6877 -5694 -7124 -8028 -1677 -979 -2213 -2320 -4379 -849 -1833 -594 -64 -1755 -1198 641 -976 874 -44 -53 -304 794 -647 625 -237 -1114 1423 601 1322 1778 -54 -2179 -815 -3062 -1164 -519 204 -749 -624 -1123 -1145 -607 -634 -720 -514 -770 -285 605 567 1286 1244 841 260 1133 252 390 572 775 1194 1154 1098 1125 472 -641 225 2 589 683 369 95 497 -9 255 231 -77 19 165 -464 -919 -832 -1511 -1153 -994 -372 -278 138 38 331 351 165 458 535 721 619 668 64 69 -323 -385 -480 -443 -617 -240 -736 -616 -472 -131 -32 21 -31 -75 147 -145 328 122 143 93 -97 -309 -284 112 332 489 770 788 805 600 262 515 -69 17 -97 -44 -56 179 -245 -173 -158 -138 -239 -390 -244 -82 -438 -337 -251 -332 -394 -86 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