File name: Pandora156s1_HamptonVA-HU_20230615_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T183835.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230615_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230615T105931.9Z 8566.458008 134 1 47.55 2 77.41 70.17 53.06 92.53 0.00 1 0.00 1 0 17 4.791e-01 1.723e-02 3.718e-01 1.239e-02 6.299119e-01 7.105843e-03 7.446858e-03 -6.000000e+00 2.903820e-01 232.82 -2.00 3.43 -2.00 321.40 0.00e+00 1.027873e-02 3.716357e-03 3.051417e-03 -6.000000e+00 1.493174e-02 288.86 -2.00 20.00 -2.00 320.77 0.00e+00 4.457 0.001 302.00 328.00 3 2.9593e+00 2.5898e-02 5.6131e-02 -6.0000e+00 7.3375e-01 8.7794e-02 3.5457e-02 3.4455e-02 -6.0000e+00 7.9734e-01 -9.5516e-02 3.3417e-02 2.2498e-02 -6.0000e+00 4.6752e-01 3.0569e-02 1.5643e-02 1.1360e-02 -6.0000e+00 1.9459e-01 1.5369e-04 -5.8503e-04 3.8790e-04 1.6518e-04 -6.0000e+00 1.4431e-02 -3.3771e-03 4.7628e-05 12 9 8 11 8 0 97.94 24.34 0.96 -0.00338 -0.00777 58 16 1 5 0 819.650 27.05 20.00 24.34 28.32 15.0 1033.98 -213666 900000 -269084 900000 -164772 900000 -174934 900000 900000 -62827 900000 900000 -79 -110244 900000 -79885 120019 21990 900000 27851 900000 54524 33782 -14666 204561 21692 -28361 -88125 4473 -24102 98261 55156 -4288 26349 -32790 24308 -24820 -21155 -2699 44924 -26301 4539 -4967 13195 12448 -12128 -3309 3693 29237 2854 5157 9006 10640 6267 3190 -5515 7785 4696 6879 -866 522 12705 12558 8756 381 11639 3291 11439 -1312 1405 -1086 655 2651 -6566 1836 132 330 -9856 2329 -3022 4837 -4398 1652 -2242 1808 -277 3797 1447 4302 -5 -1143 27 3322 3213 4391 -2104 -528 -1433 115 55 -947 -2051 -163 -4828 -1866 -2491 -1307 -3232 13 -2697 499 -1476 1158 -1349 1537 -1697 1963 -125 1424 511 543 233 499 43 293 2308 1744 1820 305 892 825 861 -122 33 89 239 -514 -662 26 127 -160 -1007 562 -571 -2776 900000 -8240 900000 -1988 900000 -2110 900000 900000 -758 900000 900000 -1 -1637 900000 -1526 1448 265 900000 336 900000 658 408 -251 2468 283 -627 -3543 72 -557 1185 832 -138 689 -1549 635 -1123 -1063 -136 1671 -2274 315 -404 942 926 -1195 -309 334 2145 290 560 1050 1348 901 503 -987 1252 784 1106 -149 91 2120 2373 1945 100 2761 830 2679 -372 438 -390 247 994 -2607 624 42 94 -3042 679 -1075 1877 -2158 852 -1294 1065 -178 2481 1010 2962 -4 -778 17 1900 1812 2608 -1515 -434 -1368 121 61 -1031 -2086 -148 -4359 -1689 -2419 -1326 -3551 15 -3502 697 -2278 1799 -2120 2244 -2427 2638 -175 2067 789 861 365 752 63 411 3047 2231 2298 416 1354 1395 1579 -240 68 196 556 -1254 -1654 65 314 -383 -2290 1195 -1211 SS 20230615T112902.1Z 8566.478497 150 1 47.25 2 71.80 74.12 47.28 97.13 0.00 1 0.00 1 0 25 9.163e-02 4.564e-03 3.750e-02 1.550e-03 4.658550e-01 8.273922e-04 5.211395e-03 -6.000000e+00 5.436401e-02 232.82 -2.00 3.43 -2.00 320.34 0.00e+00 7.031658e-04 2.968496e-04 5.440649e-04 -6.000000e+00 2.420998e-03 288.86 -2.00 20.00 -2.00 319.56 0.00e+00 3.159 0.000 302.00 328.00 3 1.3750e+00 2.5523e-03 4.0091e-02 -6.0000e+00 1.3634e-01 2.1862e-02 3.1399e-03 2.4752e-02 -6.0000e+00 1.4740e-01 1.3738e-03 2.5838e-03 1.1774e-02 -6.0000e+00 8.7829e-02 -1.1787e-02 1.3011e-03 3.4896e-03 -6.0000e+00 3.6543e-02 3.1947e-03 -6.2976e-04 4.8852e-05 4.0919e-05 -6.0000e+00 2.6472e-03 -3.8741e-03 6.0310e-05 10 0 0 10 0 0 98.68 24.33 0.29 -0.00387 -0.00861 298 80 1 5 0 158.540 27.05 20.00 24.33 28.13 15.0 1033.11 -49470 8330 -19995 -39670 -44775 4285 -55137 5924 -28914 -9498 -9010 -11775 -9621 5126 -5069 -14208 -2972 -116 1921 -2191 -1487 -9221 -5014 -6198 5139 -7700 -306 2098 -2883 -1627 -545 1231 5733 1194 -5385 -937 -4128 -4263 -1390 -2 -2045 -1150 -607 -648 -1425 -693 14 -445 -710 -309 691 277 1593 806 731 668 273 296 287 42 663 1910 1935 1312 1228 1020 -291 553 469 1623 641 748 55 522 -56 -45 -293 310 -613 -129 -8 -529 -1265 -1842 -1177 -1244 -165 -116 389 644 497 486 677 128 377 585 898 415 148 259 -231 -351 -703 -416 -637 -346 -765 -717 -232 -246 44 31 -164 -198 215 175 204 171 370 -223 -248 -579 -282 64 421 861 675 1038 352 418 90 222 -166 111 -3 -12 -123 247 -171 12 -126 -65 -229 -180 -698 77 -262 -625 -688 39 -959 63 -499 -147 -145 -209 -195 109 -144 -517 -108 -4 77 -97 -68 -459 -246 -330 265 -479 -18 118 -165 -92 -33 85 428 101 -481 -78 -377 -451 -173 0 -351 -212 -117 -128 -287 -140 3 -91 -147 -66 156 69 426 234 225 214 91 100 95 14 218 659 737 554 549 451 -124 230 205 783 350 437 33 303 -31 -23 -133 133 -273 -64 -5 -345 -917 -1437 -969 -1097 -153 -112 380 618 452 410 530 97 295 505 875 459 180 329 -287 -405 -746 -425 -679 -393 -921 -909 -311 -356 69 51 -278 -327 334 255 287 244 553 -356 -409 -960 -453 99 625 1216 914 1368 487 633 149 392 -306 213 -7 -26 -276 567 -399 28 -282 -138 -470 -365 SS 20230615T113415.3Z 8566.482122 153 1 34.25 2 70.80 74.81 46.26 98.00 0.00 1 0.00 1 0 25 7.623e-02 5.773e-03 5.245e-02 2.738e-03 4.451419e-01 1.440486e-03 5.045529e-03 -6.000000e+00 4.522876e-02 232.82 -2.00 3.43 -2.00 320.00 0.00e+00 7.679932e-04 4.719693e-04 4.798963e-04 -6.000000e+00 2.014176e-03 288.86 -2.00 20.00 -2.00 319.22 0.00e+00 3.004 0.000 302.00 328.00 3 2.5323e+00 4.2838e-03 3.8204e-02 -6.0000e+00 1.1343e-01 3.2996e-02 5.1882e-03 2.3632e-02 -6.0000e+00 1.2263e-01 -6.8850e-03 4.1375e-03 1.1229e-02 -6.0000e+00 7.3070e-02 -5.9158e-03 2.1138e-03 3.2785e-03 -6.0000e+00 3.0403e-02 1.1879e-03 -6.6089e-04 8.4797e-05 3.7950e-05 -6.0000e+00 2.2024e-03 -3.8928e-03 6.2980e-05 12 1 1 12 1 1 99.96 24.33 0.38 -0.00389 -0.00886 71 27 1 5 0 473.260 27.05 20.00 24.33 28.33 15.0 1034.56 -41872 -11236 12582 -32354 -44224 7648 -18163 -32183 15311 3843 -8647 -19788 -757 -8929 -3386 -8698 2545 -2174 -3234 -8111 1609 -7039 -826 2139 -7221 -11695 1852 1519 -7185 -419 -2537 4039 -2677 2216 -1606 -2400 -5900 4288 -5418 -2974 -815 1172 -299 -1916 -696 1117 -1651 -1055 2622 -1698 1346 1993 1732 -611 2564 1929 -841 -522 690 1271 -24 396 2289 2152 912 898 78 219 -1099 1185 191 113 1772 727 -437 -58 257 569 -1248 -481 913 -1575 -1230 -1219 -726 -1300 -336 417 965 -427 561 708 -19 561 902 749 324 704 146 119 -407 151 -2027 -512 -230 -75 -1053 -878 -487 -124 -292 -13 327 -185 194 47 529 -315 -79 -66 -266 -490 126 249 249 550 1025 756 344 579 502 399 -138 211 48 87 -305 89 -254 -12 48 -216 -331 -336 -749 -171 161 -639 -909 90 -291 -670 225 69 -182 -497 -18 -281 -121 -381 110 -106 -171 -474 88 -427 -48 130 -519 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