File name: Pandora156s1_HamptonVA-HU_20230704_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T184734.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230704_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230704 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230704T105552.6Z 8585.455470 212 1 47.93 2 79.08 69.49 92.65 238.29 0.00 1 0.00 1 0 25 4.176e-01 2.874e-02 3.523e-01 2.219e-02 6.486964e-01 1.297044e-02 7.129430e-03 -6.000000e+00 2.510784e-01 232.65 -2.00 3.43 -2.00 321.44 0.00e+00 -4.484380e-03 6.722328e-03 3.979987e-04 -6.000000e+00 1.306331e-02 290.54 -2.00 20.00 -2.00 320.78 0.00e+00 5.083 0.002 302.00 328.00 3 3.1881e+00 4.7753e-02 6.1269e-02 -6.0000e+00 6.3028e-01 3.4440e-01 6.2546e-02 3.4994e-02 -6.0000e+00 6.8420e-01 -5.4593e-01 5.0742e-02 1.7036e-02 -6.0000e+00 4.0627e-01 2.4230e-01 2.3838e-02 6.7183e-03 -6.0000e+00 1.7201e-01 6.7957e-05 -2.0475e-03 7.1287e-04 8.4959e-05 -6.0000e+00 1.3134e-02 -1.8340e-04 -1.3693e-04 12 8 8 10 0 0 99.94 24.31 1.15 -0.00018 -0.01557 35 9 1 5 0 1368.980 27.05 20.00 24.31 31.87 15.6 1037.97 900000 -91584 900000 900000 900000 -51528 -82981 -169627 900000 -111896 2037 -105069 900000 900000 -99465 17075 -106728 900000 31518 -16455 -11178 900000 -60492 900000 -21126 900000 -44069 -9543 900000 211032 900000 900000 53074 21399 99112 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683 2300 1719 -1307 1267 -1492 -1200 799 672 3048 -11 867 1838 -3118 -1983 -200 -5864 3545 -3323 493 1582 -2042 2973 -1127 1500 -756 1314 -570 -2393 346 -1638 -4029 -1588 -2033 -3414 -1157 -3299 -1127 -223 2222 -2335 -1836 -1797 1415 4072 -1696 -679 -692 -3922 4442 6988 -1591 4159 1227 1426 8405 3029 3168 -3212 667 -635 -4571 1391 -419 4193 2553 171 -1017 -411 -2650 -1228 -3494 SS 20230704T110454.2Z 8585.461738 218 1 47.53 2 77.39 70.73 94.11 239.57 0.00 1 0.00 1 0 25 3.443e-01 1.422e-02 3.055e-01 1.118e-02 5.716980e-01 6.283427e-03 6.351299e-03 -6.000000e+00 2.071552e-01 232.65 -2.00 3.43 -2.00 321.29 0.00e+00 2.194740e-03 3.150089e-03 1.671280e-03 -6.000000e+00 1.044601e-02 290.54 -2.00 20.00 -2.00 320.60 0.00e+00 4.451 0.001 302.00 328.00 3 2.8482e+00 2.2751e-02 5.4898e-02 -6.0000e+00 5.2123e-01 4.5669e-02 2.9877e-02 3.4019e-02 -6.0000e+00 5.6512e-01 -7.1094e-02 2.6890e-02 1.4723e-02 -6.0000e+00 3.3344e-01 2.6446e-02 1.2901e-02 5.7412e-03 -6.0000e+00 1.3937e-01 1.9256e-04 -1.6764e-03 3.6362e-04 5.8185e-05 -6.0000e+00 1.0311e-02 -2.5194e-03 -3.8486e-05 12 8 8 10 0 0 99.93 24.31 0.14 -0.00252 -0.01512 73 20 1 5 0 650.990 27.05 20.00 24.31 31.94 15.6 1038.34 144609 -181701 900000 900000 -100696 900000 96292 900000 -138785 900000 900000 104882 -30448 900000 -10752 900000 -69310 -30717 56630 333 -43080 5729 -98548 -21876 17665 -40189 77975 35930 45360 5387 -16449 -32563 113 23579 57604 -2284 39915 -26653 6347 75419 12102 22606 807 19801 6806 468 -10081 9324 -17395 -4110 -2313 13150 11492 325 8157 -3006 5466 -2459 889 -3651 6450 -2884 5766 126 10627 1638 6014 3797 -2189 3757 451 -2764 -1941 4571 -8755 6330 2131 1555 -2273 14 1529 -2366 -833 1205 -132 -1155 -3047 1056 1070 823 5339 58 1412 1176 -333 -382 2684 245 432 440 -510 -1358 -1387 -1053 -4009 -1188 -16 -1572 36 1055 -2695 -627 -693 1091 -569 675 1493 -1543 -281 895 -328 868 764 -479 542 -232 1778 222 349 1301 1032 110 710 -690 717 125 -29 -432 -298 -134 -458 -87 68 -206 1575 -3609 900000 900000 -1097 900000 1049 900000 -2401 900000 900000 1142 -332 900000 -132 900000 -1954 -690 617 6 -1242 109 -5177 -611 361 -1468 955 660 741 136 -582 -1502 5 835 1451 -103 1250 -1776 370 2824 923 1695 80 1675 667 50 -1214 944 -2374 -516 -310 1677 1642 56 1401 -605 1047 -517 178 -753 1219 -639 1308 34 2764 468 1595 1029 -668 1218 170 -1156 -822 1763 -3612 2044 654 490 -780 5 633 -1169 -452 690 -81 -773 -2206 767 790 600 3540 38 906 738 -223 -288 2118 227 444 475 -542 -1351 -1260 -968 -3933 -1211 -17 -1802 44 1300 -3800 -934 -1065 1619 -869 964 2050 -2223 -420 1399 -535 1390 1187 -728 785 -325 2347 292 484 1981 1743 202 1369 -1416 1538 287 -71 -1069 -746 -331 -1098 -197 147 -439 SS 20230704T110947.3Z 8585.465131 221 1 47.09 2 76.47 71.39 94.91 240.25 0.00 1 0.00 1 0 17 2.316e-01 8.676e-03 2.584e-01 5.945e-03 5.457495e-01 3.262379e-03 6.043824e-03 -6.000000e+00 1.373575e-01 232.65 -2.00 3.43 -2.00 321.04 0.00e+00 7.211291e-04 1.518047e-03 1.465357e-03 -6.000000e+00 6.280177e-03 290.54 -2.00 20.00 -2.00 320.33 0.00e+00 4.169 0.001 302.00 328.00 3 2.2891e+00 1.1215e-02 5.1403e-02 -6.0000e+00 3.4409e-01 2.4603e-02 1.4771e-02 3.1476e-02 -6.0000e+00 3.7214e-01 -1.5395e-02 1.3274e-02 1.4053e-02 -6.0000e+00 2.2197e-01 -2.9299e-03 6.3965e-03 4.8464e-03 -6.0000e+00 9.3430e-02 4.5299e-04 -8.1213e-04 1.8746e-04 5.0349e-05 -6.0000e+00 6.7422e-03 -3.5233e-03 4.1256e-05 11 9 0 11 8 0 99.94 24.32 0.31 -0.00352 -0.00963 102 27 1 5 0 461.550 27.05 20.00 24.32 32.03 15.6 1039.53 900000 25392 900000 -47663 124875 -108093 -9834 -121670 -89794 -38229 24725 41743 30860 -25464 -40180 -35948 -55034 -19318 -31948 40892 -25487 27744 -4659 6407 -13027 20576 13376 11668 25419 3397 6128 -12738 -2097 -14264 1144 -4422 -1579 18134 -12119 -1413 -4228 -4512 999 2747 -9243 2421 -2775 1157 -4722 191 3994 6001 4421 19192 -9278 2342 1381 -557 1994 280 3206 -2188 2589 3978 3877 -2263 2129 -1863 3845 -250 1153 -563 246 2149 304 2981 -853 1401 -1573 2040 -3896 1287 -1768 -48 -1498 -851 -250 34 -535 421 680 -115 596 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