File name: Pandora156s1_HamptonVA-HU_20230721_L2Fit_fout2c2d20220209p1-8.txt File generation date: 20230723T190506.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v2d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230721_L1_smca1c2d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaLab+Fld 1.8 VP 20220209 First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230721T111618.0Z 8602.469652 80 1 47.51 2 76.99 74.03 113.32 53.90 0.00 1 0.00 1 0 25 3.850e-01 1.462e-02 2.449e-01 6.924e-03 5.520678e-01 3.778205e-03 6.166520e-03 -6.000000e+00 2.291356e-01 232.37 -2.00 3.43 -2.00 321.15 0.00e+00 5.792004e-03 1.811859e-03 9.453781e-04 -6.000000e+00 1.131991e-02 291.68 -2.00 20.00 -2.00 320.41 0.00e+00 4.324 0.001 302.00 328.00 3 2.2395e+00 1.3291e-02 5.1888e-02 -6.0000e+00 5.7510e-01 7.4677e-02 1.7326e-02 2.8877e-02 -6.0000e+00 6.2301e-01 -9.0178e-02 1.5011e-02 1.5279e-02 -6.0000e+00 3.6960e-01 2.9463e-02 7.2172e-03 6.7215e-03 -6.0000e+00 1.5428e-01 4.0170e-04 -9.7943e-04 2.1700e-04 8.5706e-05 -6.0000e+00 1.1365e-02 8.6647e-03 -1.9632e-05 12 9 8 11 8 0 99.83 22.87 0.19 0.00866 0.00130 111 30 1 5 0 427.630 25.79 20.00 22.87 32.65 16.3 1021.97 -102354 -41394 133757 -126561 -94682 -73144 -231326 900000 -60733 -104906 900000 900000 -47763 114927 -51882 -34044 14321 -46663 144723 -69257 -3752 15742 44163 -43295 -19580 -12210 -37340 33491 22612 -1151 103397 7869 17418 20157 -2879 5588 -9774 11989 6682 34408 -2039 6002 13228 23541 5716 6562 -8052 12030 5308 6937 12569 8100 917 7265 -7792 -5792 4711 527 4779 5604 1502 4675 6147 158 4747 -35 -2552 10517 4459 3218 4374 1111 -1055 3129 -1429 1397 4080 435 -1861 4627 -907 568 -1587 -3404 -887 -1528 -2061 546 379 -890 1366 107 629 -1191 -1760 -804 955 -721 13 915 -620 -812 -1138 -2868 -683 -1814 -2250 385 -245 -464 -118 214 -628 491 -612 131 1716 -92 171 643 -680 -491 704 -495 1118 1266 1050 1990 578 647 427 560 196 -46 -765 -72 1030 -404 -760 377 -560 227 -82 -756 -1080 -279 903 -2136 -1079 -648 -9828 900000 -615 -1770 900000 900000 -645 776 -1160 -761 224 -1476 977 -3156 -92 319 735 -1717 -653 -397 -1591 738 549 -35 1349 295 683 833 -148 259 -565 647 459 2134 -206 608 1317 2195 651 759 -1101 1375 670 904 1681 1254 167 1343 -1775 -1344 1012 119 1016 1168 334 1087 1577 48 1470 -11 -818 2959 1419 1170 1759 492 -483 1329 -593 511 1330 143 -659 1761 -426 300 -949 -2223 -601 -1115 -1603 431 303 -710 1010 75 409 -773 -1218 -621 831 -729 14 1049 -700 -848 -1090 -2696 -656 -1881 -2474 437 -301 -624 -173 337 -1020 770 -923 185 2328 -130 254 1006 -1107 -790 1085 -747 1702 1845 1476 2737 856 1062 725 1088 377 -92 -1651 -164 2418 -985 -1882 913 -1317 501 -185 -1707 SS 20230721T113532.9Z 8602.483020 86 1 47.26 2 73.27 76.67 110.30 57.57 0.00 1 0.00 1 0 25 6.769e-02 4.939e-03 4.608e-02 1.823e-03 4.496629e-01 9.673146e-04 5.025882e-03 -6.000000e+00 4.001769e-02 232.37 -2.00 3.43 -2.00 320.37 0.00e+00 2.212949e-04 3.518250e-04 2.675223e-04 -6.000000e+00 1.808153e-03 291.68 -2.00 20.00 -2.00 319.54 0.00e+00 3.419 0.001 302.00 328.00 3 1.3081e+00 3.0185e-03 4.1447e-02 -6.0000e+00 1.0015e-01 4.1497e-03 3.7284e-03 2.3454e-02 -6.0000e+00 1.0834e-01 2.1408e-03 3.0014e-03 1.1261e-02 -6.0000e+00 6.4679e-02 -9.7141e-03 1.5098e-03 3.1008e-03 -6.0000e+00 2.6951e-02 2.7844e-03 -5.2426e-04 5.8095e-05 3.8362e-05 -6.0000e+00 1.9563e-03 8.3637e-03 -3.7002e-05 10 0 0 10 0 0 99.86 22.88 0.35 0.00836 0.00442 317 85 1 5 0 149.060 25.90 20.00 22.88 33.95 16.2 1032.61 12977 -15574 16700 -13291 -2415 -38505 1864 1541 -20917 -27340 -5054 -16435 -37148 -3303 1816 7246 -7113 2745 -9114 -7082 -13466 1123 -14593 8489 3036 -1760 -7795 -3979 345 -5766 -7683 2389 2053 -4447 -2190 -1093 -2478 -3097 2986 -2388 -2594 -1434 272 -3574 337 545 -237 -1224 -33 1265 -284 -200 2739 2641 -836 236 182 487 -173 1783 1069 329 2144 1872 1246 1160 -169 256 -194 1401 1424 320 240 1205 62 -435 -347 510 -128 -66 -309 -651 -1434 -1044 -1152 -1098 -350 386 123 107 579 782 765 254 1503 697 601 115 290 -257 -443 -565 -515 -649 -358 -716 -1284 -842 -318 -107 -165 96 312 -210 -95 469 419 -74 -178 305 -396 -214 -91 183 255 909 634 459 607 629 360 94 -80 84 -91 -60 86 41 -230 -141 140 -224 -255 -102 107 -196 161 -169 -25 -567 20 19 -359 -542 -83 -328 -1066 -82 51 224 -279 105 -421 -338 -710 52 -815 405 166 -107 -512 -244 20 -351 -523 167 162 -400 -189 -92 -227 -333 367 -370 -456 -268 52 -734 67 109 -48 -253 -7 266 -65 -50 726 753 -261 76 60 163 -57 571 351 116 822 789 554 505 -71 106 -85 680 771 187 142 687 34 -215 -156 217 -57 -33 -178 -425 -1039 -805 -946 -965 -324 369 120 102 520 650 592 191 1166 604 590 128 353 -325 -541 -640 -537 -662 -382 -821 -1559 -1075 -429 -156 -260 160 523 -343 -145 672 584 -105 -268 486 -656 -352 -147 282 379 1281 858 611 847 960 599 167 -148 162 -186 -130 194 94 -539 -327 314 -479 -525 -207 SS 20230721T114051.7Z 8602.486709 90 1 2.93 2 72.24 77.40 109.44 58.55 0.00 1 0.00 1 0 25 8.836e-02 9.672e-03 1.171e-01 8.134e-03 4.178967e-01 4.244042e-03 4.681903e-03 -6.000000e+00 5.229974e-02 232.37 -2.00 3.43 -2.00 319.61 0.00e+00 1.995885e-03 1.242742e-03 2.530550e-04 -6.000000e+00 2.361704e-03 291.68 -2.00 20.00 -2.00 318.74 0.00e+00 3.232 0.001 302.00 328.00 3 2.5732e+00 1.2342e-02 3.8886e-02 -6.0000e+00 1.3088e-01 1.9976e-02 1.4679e-02 2.1638e-02 -6.0000e+00 1.4153e-01 -1.0992e-02 1.0952e-02 1.0601e-02 -6.0000e+00 8.4507e-02 -3.1662e-04 5.6424e-03 3.6661e-03 -6.0000e+00 3.5256e-02 9.6638e-04 6.8877e-04 2.4995e-04 3.9682e-05 -6.0000e+00 2.5532e-03 3.5785e-03 7.9661e-05 12 9 9 12 1 1 -119.45 22.88 0.42 0.00358 0.00875 3 19 1 5 0 687.000 25.79 19.99 22.88 34.40 16.2 1035.63 1319 -26942 17317 14407 14298 -46511 -44214 -17305 -22562 -36391 551 10812 -7544 -32197 -7421 -6808 64 8703 -4026 -19982 14944 14194 6034 -11584 -5834 -4781 -1902 -8736 -2728 3130 -3933 5358 768 -2538 -3306 7296 -876 8098 190 6578 834 3000 -2219 -1044 -3703 2552 -1437 4055 342 4320 3054 1407 -650 -81 844 -274 1423 -3319 3242 -1298 2498 -1090 2308 2588 2731 -5198 395 1687 1994 -2172 699 404 630 -692 -456 -231 -908 639 -1054 -693 -2444 999 -2207 -1932 -1232 1622 826 -617 649 -243 1098 1192 140 84 620 234 -1016 -752 1137 503 -619 -718 -428 -695 -1249 221 -808 -693 -659 718 543 960 207 310 767 431 -686 237 425 -803 -342 -1593 170 484 530 -163 -314 894 1403 517 162 -494 -337 265 -688 -16 -542 1720 -435 317 -524 7 -349 -177 22 -665 307 256 234 -1271 -1247 -444 -646 -1283 15 278 -271 -1689 -363 -381 4 491 -275 -1682 969 934 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