File name: Pandora156s1_HamptonVA-HU_20230816_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T191016.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230816_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230816T132344.3Z 8628.558151 149 1 4.57 2 55.19 99.38 56.44 93.64 0.00 1 0.00 1 0 17 7.811e-03 5.044e-03 3.674e-03 1.380e-03 2.305036e-01 7.107736e-04 2.682022e-03 -6.000000e+00 4.604721e-03 231.50 -2.00 3.43 -2.00 317.00 0.00e+00 1.103556e-05 9.679333e-05 4.402477e-05 -6.000000e+00 2.091169e-04 292.18 -2.00 20.00 -2.00 316.08 0.00e+00 1.747 0.000 302.00 328.00 3 1.6906e+00 1.8830e-03 2.1096e-02 -6.0000e+00 1.1496e-02 1.5086e-02 2.1190e-03 1.1788e-02 -6.0000e+00 1.2443e-02 -7.9917e-04 1.2293e-03 5.6795e-03 -6.0000e+00 7.4368e-03 -3.2010e-03 5.7773e-04 1.5261e-03 -6.0000e+00 3.1067e-03 1.3082e-02 1.7507e-04 4.2063e-05 1.8803e-05 -6.0000e+00 2.2568e-04 9.1519e-03 5.7370e-05 12 1 1 12 1 1 99.97 22.91 0.41 0.00915 0.01047 45 133 1 5 0 95.460 25.90 20.01 22.91 30.71 16.8 995.09 796 -2061 -2227 -2657 -2957 -1438 -345 172 621 -183 -2104 -1089 -325 -107 51 520 129 -34 153 407 -1092 964 600 522 639 -420 403 -90 -125 228 1124 786 1428 684 -1077 -2144 -1095 -564 311 173 -663 -605 -630 -1002 -771 245 -1012 -1282 -876 -119 58 711 1174 931 676 169 930 441 434 155 894 1174 1430 896 897 183 -370 -175 74 669 395 220 179 -3 143 -24 189 -230 -37 144 -407 -978 -1345 -1382 -1185 -1109 -376 -263 -105 84 40 478 260 182 495 737 651 625 240 21 -115 -438 -290 -454 -569 -423 -598 -467 -479 -124 60 24 -16 9 -113 -13 280 224 196 100 -57 -155 -410 300 488 561 945 861 833 552 431 385 -56 -24 -122 -78 -46 215 -146 -232 -350 -219 -327 -336 106 -308 -340 -384 -386 -175 -43 24 95 -30 -349 -182 -59 -22 12 130 34 -9 43 118 -328 283 179 163 211 -145 138 -29 -38 67 337 253 490 244 -376 -731 -392 -231 137 89 -380 -366 -392 -634 -486 152 -626 -773 -512 -68 34 447 779 650 490 126 700 335 325 115 671 930 1220 749 762 162 -303 -136 59 586 352 208 172 -2 128 -22 151 -171 -28 116 -369 -906 -1351 -1466 -1330 -1333 -441 -321 -130 101 49 540 269 176 482 772 753 799 307 27 -145 -556 -344 -536 -712 -522 -778 -635 -680 -186 94 37 -23 13 -158 -17 377 283 262 143 -86 -236 -617 435 672 734 1270 1122 1113 725 601 558 -83 -36 -194 -122 -75 359 -249 -395 -581 -351 -547 -560 SS 20230816T132822.7Z 8628.561374 152 1 4.62 2 54.28 100.19 55.55 94.37 0.00 1 0.00 1 0 17 2.427e-02 9.646e-03 2.090e-02 8.190e-03 2.228403e-01 4.226793e-03 2.529367e-03 -6.000000e+00 1.430099e-02 231.50 -2.00 3.43 -2.00 316.90 0.00e+00 4.729717e-05 5.604775e-04 8.565258e-05 -6.000000e+00 6.497646e-04 292.18 -2.00 20.00 -2.00 315.99 0.00e+00 1.708 0.000 302.00 328.00 3 4.6403e+00 1.1178e-02 2.0465e-02 -6.0000e+00 3.5705e-02 1.7615e-02 1.2560e-02 1.1230e-02 -6.0000e+00 3.8651e-02 2.7742e-03 7.2654e-03 5.3963e-03 -6.0000e+00 2.3099e-02 -3.0691e-03 3.3971e-03 1.4513e-03 -6.0000e+00 9.6450e-03 7.1901e-04 -4.0662e-05 2.4999e-04 1.7439e-05 -6.0000e+00 7.0146e-04 9.2286e-03 -7.9031e-05 12 9 9 12 1 1 999.00 22.92 0.52 0.00923 0.00892 1 6 1 5 0 2217.500 25.90 19.99 22.92 30.91 16.9 997.23 -12610 11564 -7630 -517 -569 5282 -4558 1291 -4293 5367 -7708 -4414 -649 704 3124 3521 7108 23 1808 -636 1515 -2849 3356 -689 990 1938 1302 -1501 -4413 1033 413 -2123 -1448 -1306 -3056 2436 -799 1633 -1761 2629 620 1734 -3404 910 645 -1323 -90 -645 -1649 -1369 743 1766 -1366 1279 1616 -3393 665 292 -437 -377 814 2162 692 2415 47 1745 -350 161 -1788 1240 409 1579 -995 342 -205 1942 -578 931 -2263 -1267 -400 -1368 -783 -1867 -486 -395 866 -1 263 -1137 -134 455 -1142 1069 1547 -134 66 1489 -661 171 203 97 -1118 1127 -216 -60 -1473 223 -438 86 -322 -291 -282 94 -800 245 461 -114 1235 -311 -140 409 811 -212 983 -348 505 1214 -462 830 -497 -362 -442 -584 -103 758 171 159 -246 502 407 535 -820 -1126 -2050 1603 -1302 -77 -76 635 -632 188 -732 873 -1424 -801 -124 150 731 895 1820 6 521 -194 461 -903 1013 -226 337 677 457 -513 -1450 310 128 -724 -525 -487 -1110 812 -292 671 -841 1400 372 1027 -2184 566 401 -835 -58 -408 -1024 -842 462 1156 -926 885 1153 -2600 497 220 -327 -279 607 1684 590 2042 41 1496 -282 123 -1430 1065 372 1504 -988 327 -187 1661 -456 709 -1779 -1017 -356 -1293 -794 -2018 -549 -455 1047 -1 338 -1453 -160 520 -1206 1036 1507 -142 78 1812 -845 221 263 118 -1344 1315 -258 -76 -2008 298 -616 127 -480 -447 -427 140 -1108 326 589 -149 1683 -440 -208 611 1185 -303 1387 -474 647 1571 -593 1118 -718 -518 -646 -875 -161 1183 279 267 -422 851 672 855 -1345 -1845 SS 20230816T133703.4Z 8628.567400 158 1 47.31 2 52.58 101.74 53.87 95.78 0.00 1 0.00 1 0 17 1.065e-02 4.985e-03 6.007e-03 1.917e-03 2.152485e-01 9.843178e-04 2.498785e-03 -6.000000e+00 6.279493e-03 231.50 -2.00 3.43 -2.00 317.49 0.00e+00 -6.824362e-05 1.524914e-04 6.783417e-05 -6.000000e+00 2.851904e-04 292.18 -2.00 20.00 -2.00 316.56 0.00e+00 1.642 0.000 302.00 328.00 3 3.8680e+00 2.6355e-03 1.9801e-02 -6.0000e+00 1.5678e-02 2.4230e-02 2.9763e-03 1.1048e-02 -6.0000e+00 1.6969e-02 7.6656e-03 1.7547e-03 5.3122e-03 -6.0000e+00 1.0142e-02 -7.3132e-03 8.4549e-04 1.4287e-03 -6.0000e+00 4.2364e-03 1.6776e-03 1.4923e-04 5.9764e-05 1.7669e-05 -6.0000e+00 3.0780e-04 9.0296e-03 3.7080e-05 10 0 0 10 0 0 99.99 22.91 0.82 0.00903 0.01015 78 21 1 5 0 606.470 25.90 20.02 22.91 31.46 16.9 1001.66 -461 -896 -3009 -468 -4059 -3707 -5336 2675 -458 -1049 -2380 -485 -1634 -51 125 684 297 -1406 -1125 -1246 2668 -523 1133 -276 786 404 -724 -281 733 805 1236 1639 1182 510 -1905 -1185 -2387 1020 -101 59 -439 -694 -1227 -496 -1269 -304 -678 -730 -658 685 484 620 1193 1178 255 220 737 521 507 789 929 1049 1772 1517 -184 -53 -163 -289 29 432 458 342 56 402 -144 323 189 -78 -204 88 -502 -1039 -978 -1619 -1254 -1059 -51 -200 -180 -116 179 -16 320 479 569 662 425 632 82 164 -410 -310 -735 -356 -518 -487 -668 -405 -387 96 304 -198 288 -104 4 161 55 -48 193 202 66 -124 -78 290 421 846 262 942 613 551 369 273 181 220 -138 -22 -156 136 -142 -197 -177 -182 -314 -439 -53 -112 -389 -56 -449 -386 -589 303 -59 -144 -330 -67 -247 -9 24 140 64 -315 -260 -297 625 -126 272 -70 208 111 -202 -74 196 207 324 456 353 158 -579 -346 -747 355 -42 28 -237 -360 -659 -268 -757 -178 -393 -410 -359 365 267 363 733 760 172 151 512 364 349 537 643 766 1384 1262 -158 -43 -121 -205 21 344 403 319 53 373 -127 259 137 -52 -136 64 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