File name: Pandora156s1_HamptonVA-HU_20231006_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T193823.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20231006_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20231006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231006T113628.9Z 8679.483668 241 1 46.99 2 84.59 100.59 12.04 223.33 0.00 1 0.00 1 0 33 8.985e-01 1.036e-01 5.771e-01 7.428e-02 8.417939e-01 4.352785e-02 9.156399e-03 -6.000000e+00 5.509391e-01 227.40 -2.00 3.43 -2.00 321.97 0.00e+00 2.274523e-03 1.693983e-02 9.337217e-03 -6.000000e+00 2.623688e-02 288.00 -2.00 20.00 -2.00 321.37 0.00e+00 9.243 0.013 302.00 328.00 3 2.2987e-01 1.4789e-01 1.1790e-01 -6.0000e+00 1.3710e+00 1.8274e+00 1.7555e-01 9.1500e-02 -6.0000e+00 1.4983e+00 -1.8153e+00 9.9116e-02 2.5463e-02 -6.0000e+00 8.9196e-01 6.0323e-01 5.2847e-02 1.2833e-02 -6.0000e+00 3.7231e-01 1.4278e-05 -8.1745e-05 2.2654e-03 1.3682e-04 -6.0000e+00 2.7368e-02 8.4058e-03 1.4743e-04 12 8 8 10 0 0 -9.28 23.02 0.89 0.00841 0.00779 22 6 1 5 0 2135.320 26.00 20.01 23.02 27.42 17.7 997.95 145362 328896 -9215 69937 110530 -77768 -86123 -7499 900000 -46294 -13496 -26677 900000 900000 900000 77448 900000 900000 900000 108332 320975 900000 23520 23567 -42410 -21010 900000 5415 -85826 900000 -28800 50905 77602 900000 -39977 33507 221 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26326 -3681 27840 8186 -57110 -5193 8324 7938 9591 9082 11040 11071 10356 4256 5826 -11977 7831 -3112 4060 -317 5931 8395 -581 15991 8724 11189 -3294 9097 -7622 -3830 16206 9043 2686 9334 7914 11886 4443 7689 7598 9293 -1695 4344 7418 -4789 7619 -8583 -8104 -16455 9913 4431 -11187 -11689 5661 -7301 -5317 2421 3936 -11678 -2988 8015 5739 3920 5758 9854 -2768 -10601 6983 -1221 3174 3520 -1674 -7609 3662 1760 -1570 -6391 5253 -4744 -662 7112 975 4282 -4227 SS 20231006T114722.8Z 8679.491236 244 1 47.22 2 82.46 102.28 13.61 231.25 0.00 1 0.00 1 0 17 5.654e-01 2.220e-02 3.560e-01 1.346e-02 7.646607e-01 8.127251e-03 9.435678e-03 -6.000000e+00 3.408898e-01 227.40 -2.00 3.43 -2.00 322.12 0.00e+00 1.541190e-02 5.262722e-03 5.248421e-03 -6.000000e+00 1.975583e-02 288.00 -2.00 20.00 -2.00 321.59 0.00e+00 7.063 0.006 302.00 328.00 3 3.5863e-01 3.4552e-02 8.1944e-02 -6.0000e+00 8.5531e-01 5.3934e-01 4.9403e-02 4.2185e-02 -6.0000e+00 9.3890e-01 -6.4046e-01 4.6777e-02 2.6162e-02 -6.0000e+00 5.4491e-01 2.4048e-01 2.0874e-02 1.4381e-02 -6.0000e+00 2.3093e-01 1.4898e-04 -1.1332e-03 4.2112e-04 2.9208e-04 -6.0000e+00 1.7369e-02 1.0038e-02 -1.7916e-05 12 8 8 10 0 0 31.74 23.03 0.26 0.01004 0.00152 88 24 1 5 0 536.440 26.00 20.00 23.03 27.87 17.7 1002.07 900000 900000 -180464 -275977 900000 900000 900000 -209910 900000 900000 900000 900000 -147485 900000 900000 900000 -70684 -50954 900000 900000 900000 10582 900000 -46901 60075 -83752 -118185 73367 900000 900000 -64779 5586 900000 153702 -9246 9484 13840 70584 87026 -24498 73077 900000 236894 14436 -20774 143658 97768 69456 12624 5864 51061 80815 43945 7864 17515 34114 28674 10712 32552 27745 39502 19187 10796 7464 34187 28201 14839 -714 6627 10898 14452 5210 6880 6474 15950 1733 -3108 1781 12595 -5318 -2040 -1116 1862 3074 -6167 -4611 4468 -1016 1779 -3828 179 1065 -1198 -3086 -4879 -1883 2275 2528 -5495 -1111 -94 -907 -5463 759 359 -1803 700 -1821 -3607 -487 503 -873 -1322 -1164 -817 188 -1431 2513 1947 1997 364 -454 1970 2876 -637 -640 364 1201 1774 1969 284 66 568 307 -810 -574 -117 569 -743 332 521 922 -90 -2412 900000 900000 -2753 -10627 900000 900000 900000 -3714 900000 900000 900000 900000 -2269 900000 900000 900000 -1305 -862 900000 900000 900000 138 900000 -830 786 -2191 -4364 959 900000 900000 -1944 110 900000 2010 -249 217 317 1038 1280 -1206 1613 900000 3098 644 -1358 1996 2238 2214 709 379 2462 3237 2802 732 1563 2651 2382 1055 2504 2198 3035 1860 1304 1068 4103 3666 2192 -126 1178 2104 3002 1254 1630 1464 3006 339 -588 321 2248 -1350 -600 -378 686 1206 -2818 -2206 2059 -514 884 -1973 84 465 -513 -1363 -2413 -1053 1442 1867 -4963 -1011 -82 -736 -4178 517 254 -1385 556 -1593 -3521 -519 601 -1166 -1854 -1627 -1101 241 -1841 3203 2634 2839 534 -654 2654 3706 -822 -799 437 1440 2310 2934 487 124 1146 661 -1886 -1420 -301 1481 -1976 860 1282 2116 -196 -5354 SS 20231006T120631.2Z 8679.504528 249 1 47.26 2 78.75 105.32 16.74 241.63 0.00 1 0.00 1 0 25 2.384e-01 4.649e-03 1.889e-01 2.507e-03 5.753180e-01 1.355794e-03 6.317606e-03 -6.000000e+00 1.383758e-01 227.40 -2.00 3.43 -2.00 321.24 0.00e+00 1.078944e-03 6.782013e-04 1.345473e-03 -6.000000e+00 6.269911e-03 288.00 -2.00 20.00 -2.00 320.58 0.00e+00 4.948 0.002 302.00 328.00 3 1.6300e-01 4.8009e-03 5.8068e-02 -6.0000e+00 3.4257e-01 1.0585e-02 6.5072e-03 3.2388e-02 -6.0000e+00 3.7224e-01 1.3596e-02 6.2188e-03 1.4972e-02 -6.0000e+00 2.2265e-01 -1.6254e-02 2.9537e-03 5.1010e-03 -6.0000e+00 9.3349e-02 1.8152e-03 -7.2256e-04 7.8291e-05 5.7343e-05 -6.0000e+00 6.8813e-03 9.4408e-03 -4.2264e-05 10 0 0 10 0 0 12.37 23.02 0.29 0.00944 0.00401 364 98 1 5 0 129.810 26.00 20.00 23.02 29.53 17.8 1015.31 -91698 21268 -51688 -40618 -102736 160076 -56825 -57259 -47950 -64917 -54922 -43485 36350 -31726 -50263 -14076 -8977 -15760 -8624 -11056 6640 -41256 13238 7159 -10203 -31830 20827 -4100 -17529 -9100 -17059 -6957 7456 3684 -11112 -14149 -12073 -8569 1616 -83 -2861 912 -1129 102 3842 783 -3736 759 -1631 -222 1099 -1393 1351 865 2252 -205 1542 432 2538 408 -1583 694 2582 1075 1427 1649 672 48 267 2915 222 307 762 1206 179 126 -863 -580 -165 8 -569 -416 -1612 -1955 -1058 -921 -238 234 232 309 1261 215 757 -78 518 377 934 695 103 458 -22 -119 -784 -556 -1060 -418 -965 -573 -414 -109 -180 174 173 -253 94 691 142 -207 -8 -150 -226 -493 -161 72 249 432 568 689 582 404 177 453 -185 85 -148 -128 -279 380 -240 -153 -142 197 -121 8 -471 52 -227 -159 -703 391 -264 -308 -270 -476 -389 -308 142 -310 -737 -172 -119 -247 -137 -192 101 -1029 201 126 -235 -973 387 -96 -463 -231 -538 -235 252 141 -489 -637 -576 -465 97 -6 -249 83 -112 10 380 82 -416 83 -189 -27 144 -208 217 152 418 -41 314 90 510 82 -333 154 629 298 421 485 194 14 84 1013 89 131 328 500 70 45 -283 -185 -56 3 -259 -216 -944 -1235 -706 -657 -178 182 183 238 913 147 484 -50 351 288 817 695 114 528 -25 -123 -747 -511 -1021 -428 -1048 -658 -510 -147 -269 277 283 -407 143 992 200 -299 -12 -241 -372 -803 -252 109 363 603 764 918 827 642 312 855 -369 179 -330 -304 -691 957 -616 -388 -344 451 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