File name: Pandora156s1_HamptonVA-HU_20240422_L2Fit_fout2c2d20220209p1-8.txt File generation date: 20240423T050947.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v2d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240422_L1_smca1c2d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaLab+Fld 1.8 VP 20220209 First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240422T130351.4Z 8878.544344 284 1 47.12 2 58.66 98.19 129.99 295.35 0.00 1 0.00 1 0 17 8.715e-02 1.224e-02 6.597e-02 8.238e-03 3.297466e-01 4.244830e-03 3.803360e-03 -6.000000e+00 5.122178e-02 229.63 -2.00 3.43 -2.00 318.90 0.00e+00 7.243809e-04 9.496261e-04 4.254864e-04 -6.000000e+00 2.254783e-03 283.72 -2.00 20.00 -2.00 318.15 0.00e+00 1.915 0.000 302.00 328.00 3 5.5990e+00 1.1735e-02 2.5656e-02 -6.0000e+00 1.2769e-01 3.1825e-02 1.3459e-02 1.6785e-02 -6.0000e+00 1.3838e-01 -1.2642e-02 9.1191e-03 8.2741e-03 -6.0000e+00 8.2425e-02 4.3297e-03 4.7045e-03 2.3648e-03 -6.0000e+00 3.4438e-02 1.8325e-04 6.7521e-04 2.5845e-04 2.8457e-05 -6.0000e+00 2.5144e-03 -1.7188e-02 2.4626e-04 12 9 8 11 8 0 99.97 22.71 0.63 -0.01719 -0.01211 18 5 1 5 0 2617.090 25.68 19.99 22.71 15.74 18.9 978.53 23836 42657 -10175 -26901 -475 1566 48027 -34407 29917 -798 -5722 4740 -13181 -8975 21448 -5328 4758 -12286 -4948 -11771 -2856 6800 2916 3263 13321 -4562 -4951 6973 20592 -4011 -5289 5010 9265 2438 -6368 -5708 -6331 14950 2907 -1109 1451 -3859 -7385 680 2793 -2184 -3216 -2420 -1767 -1812 3801 -3729 -292 1362 2676 249 4524 -3765 1534 6084 2671 1787 915 4009 1640 3905 -630 -613 4404 2466 -299 -2021 667 2466 2530 -2121 -1870 583 3901 -3359 -1725 -2909 -102 -2540 -880 -1516 -1351 -156 472 -884 167 122 54 -679 -976 2032 244 -424 -65 1017 113 111 -562 -823 -1564 -171 -1745 488 -477 465 -198 185 794 252 77 -1303 290 -710 366 827 -419 518 423 79 748 -113 261 490 610 1552 133 550 182 -429 278 -399 88 345 352 -734 -177 -751 -116 -171 766 1285 -547 -1662 -21 62 1230 -2229 1142 -44 -342 262 -966 -735 1508 -554 483 -1555 -611 -1620 -370 803 362 423 1659 -712 -788 953 2317 -562 -784 735 1428 427 -1196 -1092 -1268 2755 676 -318 458 -1376 -2837 246 995 -873 -1292 -950 -682 -702 1448 -1644 -133 649 1319 130 2305 -2100 801 2986 1369 972 546 2513 1098 2485 -392 -364 2541 1599 -222 -1637 538 1915 1860 -1496 -1185 335 2161 -2179 -1248 -2386 -89 -2414 -870 -1613 -1526 -182 558 -1044 185 125 51 -605 -880 1920 261 -509 -85 1369 149 137 -642 -912 -1821 -210 -2298 658 -683 701 -322 314 1345 413 118 -1878 393 -979 523 1254 -674 833 668 121 1093 -158 347 629 799 2159 202 874 299 -731 491 -750 173 691 716 -1505 -350 -1437 -212 -308 SS 20240422T133901.1Z 8878.568763 312 1 3.24 2 51.78 104.44 135.98 303.43 0.00 1 0.00 1 0 17 1.594e-01 9.117e-03 3.066e-02 5.738e-03 2.913043e-01 2.953997e-03 3.391471e-03 -6.000000e+00 9.364373e-02 229.64 -2.00 3.43 -2.00 317.60 0.00e+00 -1.123332e-04 4.661575e-04 2.141133e-04 -6.000000e+00 4.125203e-03 283.72 -2.00 20.00 -2.00 316.85 0.00e+00 1.613 0.000 302.00 328.00 3 3.9246e+00 7.8813e-03 2.2044e-02 -6.0000e+00 2.3344e-01 2.0003e-02 8.8910e-03 1.4744e-02 -6.0000e+00 2.5304e-01 7.2423e-03 5.4118e-03 7.1993e-03 -6.0000e+00 1.5071e-01 -8.6541e-03 2.6768e-03 1.9808e-03 -6.0000e+00 6.2935e-02 1.3995e-03 -3.0894e-04 1.7468e-04 2.3682e-05 -6.0000e+00 4.6002e-03 -1.7407e-02 6.0749e-05 12 9 1 12 1 1 999.00 22.70 0.66 -0.01741 -0.01973 2 12 1 5 0 1077.890 25.68 19.99 22.70 16.42 19.0 984.33 -3413 -940 -3413 6354 -9055 -17075 3889 -3298 3980 35550 -10960 -3151 180190 15399 -156 -5019 1006 785 -2682 -1475 3532 476 2497 -481 -4857 545 -3313 207 -4881 1424 -1934 5994 47 2339 -1102 -1182 -1766 -2091 -2160 -1176 1360 900 -1119 -2002 -436 504 232 -89 -774 -311 618 845 1435 1465 -10 449 1035 1139 -594 1558 1145 1517 1156 1391 3 532 -1083 220 -383 424 171 -1645 152 -352 802 -603 990 510 164 -198 70 -1113 -541 -2574 -1418 -482 878 -236 -429 550 145 974 576 429 -507 1607 484 1083 826 -374 53 -944 -959 -323 -786 708 -782 -698 -403 -925 -1010 -1111 168 -187 846 -23 36 72 490 30 79 -192 228 283 12 460 220 1121 1372 1050 727 509 463 373 -325 -29 -310 51 168 -124 -59 -532 -386 -900 -293 -88 -322 560 -846 -1619 307 -311 393 2748 -1373 -371 3967 1896 -26 -919 185 151 -560 -316 740 103 536 -112 -1250 139 -893 52 -1208 339 -491 1524 13 667 -318 -348 -512 -692 -853 -544 653 464 -611 -1123 -241 275 126 -48 -409 -163 332 484 873 942 -7 297 734 770 -404 1076 801 1051 870 1126 3 436 -837 159 -284 342 154 -1537 143 -326 734 -513 747 377 120 -157 60 -1066 -534 -2752 -1583 -543 1039 -295 -548 687 173 1115 605 422 -503 1678 540 1333 1061 -504 70 -1215 -1142 -370 -946 900 -1014 -948 -571 -1335 -1552 -1784 267 -286 1247 -32 49 95 672 45 117 -289 336 423 18 624 299 1450 1801 1474 1045 770 721 570 -522 -50 -526 88 298 -220 -102 -888 -647 -1493 SS 20240422T140100.4Z 8878.584032 321 1 23.91 2 47.57 108.81 139.44 309.30 0.00 1 0.00 1 0 17 2.212e-02 7.075e-03 1.580e-02 4.111e-03 2.697538e-01 2.107928e-03 3.167650e-03 -6.000000e+00 1.299356e-02 229.64 -2.00 3.43 -2.00 317.87 0.00e+00 6.258251e-05 3.508803e-04 1.200668e-04 -6.000000e+00 5.723698e-04 283.72 -2.00 20.00 -2.00 317.10 0.00e+00 1.480 0.000 302.00 328.00 3 4.9840e+00 5.6432e-03 2.0370e-02 -6.0000e+00 3.2391e-02 4.9699e-02 6.3797e-03 1.3734e-02 -6.0000e+00 3.5111e-02 -3.2828e-03 3.8928e-03 6.7104e-03 -6.0000e+00 2.0912e-02 -5.5275e-03 1.9257e-03 1.8524e-03 -6.0000e+00 8.7325e-03 5.6746e-04 -2.0699e-04 1.2733e-04 2.2896e-05 -6.0000e+00 6.3827e-04 -1.6892e-02 8.9906e-05 12 9 1 12 1 1 99.94 22.70 0.18 -0.01689 -0.01845 13 8 1 5 0 1707.380 25.68 19.98 22.70 16.94 19.0 989.46 -3251 -3185 -4409 -5536 -3039 -6764 -6510 -3170 10535 -4343 -1307 -6653 437 -3074 -799 -2527 -955 -1822 8049 4637 1105 2185 3200 3007 -2620 2302 208 329 -2691 3463 -156 -916 1340 629 520 -7505 -5364 -903 -301 2304 -943 406 -806 -1945 539 -828 432 -862 -1167 283 -443 384 538 913 1510 645 836 672 -183 222 944 1125 1796 2069 856 1259 -793 -699 104 -174 410 210 170 1111 96 -211 291 -211 -232 -256 -583 -1613 -1388 -1828 -1459 -1284 -534 -1 -200 -636 -133 292 -294 789 -240 1720 665 1525 523 578 -32 -603 -2 375 -845 -665 459 -343 -769 -115 126 219 192 -119 184 139 20 -917 -103 194 -406 -670 39 -11 627 521 619 890 605 1010 81 454 -490 172 231 117 -104 125 -55 -363 218 -318 -467 -267 -279 -304 -443 -543 -263 -566 -556 -290 940 -481 -142 -772 51 -427 -124 -444 -176 -351 1462 902 228 447 654 642 -626 547 51 78 -612 758 -36 -231 357 178 143 -2147 -1559 -285 -105 924 -439 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