File name: Pandora156s1_HamptonVA-HU_20240520_L2Fit_fout2c2d20220209p1-8.txt File generation date: 20240521T050658.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v2d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240520_L1_smca1c2d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaLab+Fld 1.8 VP 20220209 First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240520T124847.6Z 8906.533885 247 1 18.07 2 57.02 88.57 143.74 308.74 0.00 1 0.00 1 0 17 3.532e-02 1.254e-02 3.853e-02 9.295e-03 2.594218e-01 4.816027e-03 3.075570e-03 -6.000000e+00 2.091416e-02 231.58 -2.00 3.43 -2.00 318.00 0.00e+00 1.530641e-03 8.280352e-04 4.585029e-04 -6.000000e+00 9.246607e-04 286.50 -2.00 20.00 -2.00 317.17 0.00e+00 1.831 0.000 302.00 328.00 3 5.5948e+00 1.2999e-02 2.2894e-02 -6.0000e+00 5.2336e-02 5.5723e-02 1.4708e-02 1.4055e-02 -6.0000e+00 5.6605e-02 1.6974e-02 8.9854e-03 6.4883e-03 -6.0000e+00 3.3718e-02 -1.5779e-02 4.4370e-03 2.4236e-03 -6.0000e+00 1.4074e-02 2.2168e-04 -1.4036e-04 2.9096e-04 2.6144e-05 -6.0000e+00 1.0198e-03 -2.0465e-02 1.5872e-04 12 9 9 12 1 1 99.99 23.08 1.34 -0.02047 -0.02152 6 5 1 5 0 2579.750 26.00 20.00 23.08 23.24 20.0 1016.37 -10198 -8521 1498 7675 -8006 2994 -4410 2118 10843 6573 -10505 -10511 10808 -7337 -7592 -192 -223 654 2384 -7387 14803 -8519 2428 -2923 -1403 -3361 -1849 2836 3313 1263 6927 -3109 -303 -556 1037 5912 -3286 161 -2368 5114 597 -547 -2276 -2173 1071 297 2354 -1312 -1199 849 1624 1037 3892 -66 -2920 -2304 3465 919 3099 2334 230 1305 2479 100 424 908 1485 -384 -965 -667 -321 3044 -670 419 234 -1916 -5305 -3734 -556 -1461 722 -2314 -1485 -1649 -3054 160 201 530 715 -1599 1540 1056 1663 584 -502 1155 1836 75 -39 156 254 619 -557 1915 -1108 -14 -1134 245 -450 -404 -318 505 375 907 -541 39 -1994 -1457 -217 -498 -780 -858 1144 -615 535 1222 1116 -186 2297 882 -162 518 -436 -164 108 -192 1460 1019 729 17 -1699 -234 -1179 -200 -832 -768 128 635 -662 219 -352 174 909 615 -1179 -1191 1078 -1006 -1200 -32 -39 119 443 -1570 2592 -1888 484 -638 -317 -807 -443 627 685 257 1366 -731 -75 -146 261 1357 -855 46 -817 1930 265 -262 -1152 -1122 538 150 1158 -655 -585 402 784 535 2080 -39 -1833 -1471 2128 583 1900 1423 145 853 1732 77 337 694 1043 -259 -660 -497 -266 2610 -612 372 199 -1526 -3932 -2505 -355 -1010 548 -2019 -1400 -1650 -3271 178 238 654 899 -2033 1807 1147 1638 540 -466 1126 1963 90 -51 214 337 764 -644 2095 -1303 -18 -1508 336 -650 -615 -513 842 626 1443 -810 54 -2661 -1941 -300 -736 -1219 -1365 1759 -935 769 1657 1441 -234 2851 1179 -233 775 -677 -260 177 -335 2616 1887 1379 32 -3222 -421 -2071 -343 SS 20240520T130237.2Z 8906.543486 254 1 47.52 2 54.26 90.64 145.78 313.14 0.00 1 0.00 1 0 25 2.852e-02 8.254e-03 2.254e-02 6.049e-03 2.443172e-01 3.123107e-03 2.829565e-03 -6.000000e+00 1.688068e-02 231.58 -2.00 3.43 -2.00 317.84 0.00e+00 1.055087e-03 5.156031e-04 1.107490e-04 -6.000000e+00 7.464796e-04 286.50 -2.00 20.00 -2.00 317.01 0.00e+00 1.707 0.000 302.00 328.00 3 5.2539e+00 8.4080e-03 2.1248e-02 -6.0000e+00 4.2242e-02 5.8840e-02 9.4895e-03 1.2511e-02 -6.0000e+00 4.5691e-02 4.0689e-03 5.7303e-03 6.0753e-03 -6.0000e+00 2.7217e-02 -8.0989e-03 2.8036e-03 1.8200e-03 -6.0000e+00 1.1358e-02 3.6279e-04 -1.0343e-05 1.8907e-04 2.0910e-05 -6.0000e+00 8.2325e-04 -1.9749e-02 1.2946e-04 11 8 0 10 0 0 99.99 23.07 0.66 -0.01975 -0.01983 35 9 1 5 0 1357.310 26.00 20.00 23.07 23.46 20.3 1019.90 2298 -1924 1976 -11488 -5799 587 -2550 -1169 3534 -3645 19779 -2910 4087 -3716 -6593 3108 3487 3855 855 3277 -432 -6811 -2532 -2055 7241 728 -1948 555 2906 2728 622 2654 3132 -767 -92 -2567 -11055 -1851 2539 -1399 -90 -827 -1908 -2208 -1265 -681 -803 -1021 -1193 100 -1568 3739 1890 892 2161 469 1673 1042 -191 215 1848 168 2166 969 1611 713 -30 -234 609 -104 1291 1180 289 -427 -1153 730 -671 17 -518 332 -961 -510 -880 -2116 -1620 -1181 -668 192 353 -1087 299 44 720 -382 1680 -883 960 314 286 1176 59 -1404 -728 -181 -294 480 -736 -726 -891 -70 -76 474 -10 -517 -101 453 230 495 83 -424 165 112 363 545 516 449 456 922 296 705 -70 125 368 -179 -120 -96 -538 135 265 60 -268 -431 -365 -157 203 -198 203 -1305 -562 50 -226 -112 360 -425 1838 -341 484 -541 -1128 536 637 726 172 667 -94 -1575 -563 -471 1591 178 -494 132 632 570 136 608 769 -205 -24 -696 -3163 -582 849 -573 -41 -402 -970 -1147 -652 -372 -434 -540 -616 51 -823 1975 1081 542 1348 304 1092 688 -126 140 1193 116 1578 766 1306 562 -22 -162 420 -79 1074 1053 266 -391 -1011 577 -484 11 -336 229 -753 -442 -833 -2146 -1725 -1339 -803 239 448 -1385 358 49 719 -358 1530 -880 1035 377 374 1579 77 -1754 -838 -201 -342 595 -973 -1005 -1289 -106 -122 783 -17 -823 -149 610 295 637 113 -617 252 175 555 808 732 606 626 1210 395 995 -99 197 553 -277 -193 -163 -959 245 491 112 -488 -760 -621 -281 SS 20240520T131608.4Z 8906.552875 264 1 16.81 2 51.57 92.73 147.63 317.87 0.00 1 0.00 1 0 17 8.487e-03 4.951e-03 2.123e-03 7.398e-04 2.275304e-01 3.806323e-04 2.664488e-03 -6.000000e+00 5.024221e-03 231.58 -2.00 3.43 -2.00 317.24 0.00e+00 1.380376e-04 5.373815e-05 4.560524e-05 -6.000000e+00 2.221553e-04 286.50 -2.00 20.00 -2.00 316.42 0.00e+00 1.605 0.000 302.00 328.00 3 1.5803e+00 1.0104e-03 1.9925e-02 -6.0000e+00 1.2573e-02 2.3173e-02 1.1340e-03 1.1682e-02 -6.0000e+00 1.3599e-02 4.0106e-03 6.6634e-04 5.6475e-03 -6.0000e+00 8.1003e-03 -6.1280e-03 3.1796e-04 1.5321e-03 -6.0000e+00 3.3808e-03 1.6621e-02 1.1752e-04 2.2881e-05 1.9330e-05 -6.0000e+00 2.4501e-04 -1.9977e-02 1.4520e-04 12 1 1 12 1 1 99.99 23.08 0.31 -0.01998 -0.01909 262 199 1 5 0 63.890 26.00 20.00 23.08 23.80 20.2 1022.31 -302 -1180 -2124 -2645 -3632 -3177 -2028 -1073 807 -524 -395 -955 -628 -494 540 -396 -372 -682 324 467 388 223 544 363 222 244 174 -554 -884 1059 1097 1846 1620 727 -1516 -1698 -1446 -309 -288 371 -248 -861 -924 -931 -1096 -359 -659 -781 -447 -409 571 624 1013 1139 789 386 1169 740 578 534 989 822 1501 1005 1088 314 -314 -315 -181 573 524 141 25 33 -5 285 21 -13 -117 -78 -469 -949 -1221 -1476 -1142 -1170 -392 -361 -64 -231 154 175 422 317 438 702 708 736 195 76 -180 -332 -535 -270 -425 -249 -598 -565 -355 -212 -59 80 -53 -83 -55 -35 340 151 372 138 -28 -174 -166 120 503 609 718 890 936 694 432 441 23 -78 -39 -48 -124 64 -98 -236 -173 -193 -401 -403 -37 -160 -302 -363 -455 -367 -236 -136 112 -79 -60 -146 -103 -91 111 -91 -90 -171 83 124 106 61 149 103 67 77 55 -170 -254 284 298 530 501 237 -493 -528 -464 -111 -122 185 -139 -518 -523 -536 -632 -225 -409 -472 -262 -236 334 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