File name: Pandora156s1_HamptonVA-HU_20240627_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T213020.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240627_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240627T114021.6Z 8944.486361 227 1 2.21 2 70.16 75.27 50.70 214.02 0.00 1 0.00 1 0 17 1.668e-01 1.517e-02 2.199e-01 1.287e-02 4.126613e-01 6.752654e-03 4.679533e-03 -6.000000e+00 9.914095e-02 232.71 -2.00 3.43 -2.00 319.42 0.00e+00 1.982143e-03 1.848815e-03 1.826411e-04 -6.000000e+00 4.431122e-03 290.01 -2.00 20.00 -2.00 318.58 0.00e+00 2.914 0.000 302.00 328.00 3 3.2162e+00 1.9289e-02 3.6326e-02 -6.0000e+00 2.4849e-01 3.3057e-02 2.2648e-02 2.1650e-02 -6.0000e+00 2.6837e-01 -1.5210e-02 1.6788e-02 1.0432e-02 -6.0000e+00 1.6005e-01 -6.0689e-03 8.7222e-03 3.4815e-03 -6.0000e+00 6.6891e-02 6.8302e-04 -8.8858e-04 3.9596e-04 3.7155e-05 -6.0000e+00 4.8168e-03 -2.1351e-02 7.3999e-05 12 9 9 12 1 1 999.00 23.26 0.57 -0.02135 -0.02803 1 12 1 5 0 1101.080 26.21 20.00 23.26 28.54 21.2 1006.43 111746 -33963 37772 -1933 93777 33330 1177 41781 -10420 39631 12410 8507 -33231 60842 -7142 26458 12648 2684 10374 17794 6446 -8294 -1482 -20165 -2177 4872 7316 -18410 11956 19627 9235 7348 -712 251 2089 -9016 -27850 4445 2529 3626 3410 6094 -784 -544 -14394 6481 448 2307 -3406 5514 -2155 -3066 12883 -3891 1820 -682 1483 1507 4010 -2760 1722 2578 1613 3017 4720 604 3083 -6850 -2794 2436 1361 1037 -2082 1230 -1241 293 -4074 1655 -2114 -2700 -5261 185 -457 312 -12 -1045 -1672 -997 1807 -752 1661 1256 1467 292 1452 -870 2516 -715 439 421 -613 603 528 800 -1546 420 -1435 -1168 -1248 1704 213 -387 918 -215 -1458 -629 2475 170 -328 822 601 -1241 83 -1014 1221 -2185 1314 809 1153 861 234 -1145 -682 -521 816 159 -637 773 -227 -402 -287 873 -254 -20 1403 -1066 622 -47 1177 497 25 656 -311 777 331 247 -1669 1432 -398 1225 744 187 716 1201 506 -761 -129 -2231 -215 474 712 -2268 1041 1571 877 801 -94 36 290 -1351 -5244 690 480 814 823 1552 -225 -160 -4932 1819 134 678 -1064 1604 -713 -1112 4319 -1652 771 -307 673 691 1774 -1286 774 1213 840 1700 2771 366 1723 -4092 -1646 1508 903 742 -1579 886 -867 195 -2569 921 -1230 -1738 -3761 142 -390 282 -12 -1030 -1765 -1095 1971 -833 1713 1273 1371 262 1308 -874 2603 -860 549 551 -795 759 611 884 -1809 516 -1898 -1540 -1740 2475 323 -627 1497 -345 -2233 -937 3420 242 -492 1296 946 -2004 129 -1629 1842 -3257 1808 1140 1581 1283 382 -1919 -1185 -935 1519 302 -1277 1570 -475 -840 -582 1677 -473 -38 SS 20240627T115834.9Z 8944.499015 233 1 47.40 2 66.63 77.68 52.75 219.02 0.00 1 0.00 1 0 25 1.798e-02 4.347e-03 1.115e-02 1.034e-03 3.569302e-01 5.421182e-04 4.081726e-03 -6.000000e+00 1.068096e-02 232.71 -2.00 3.43 -2.00 319.48 0.00e+00 1.308863e-04 1.452861e-04 1.862047e-04 -6.000000e+00 4.776518e-04 290.01 -2.00 20.00 -2.00 318.61 0.00e+00 2.501 0.000 302.00 328.00 3 1.2898e+00 1.5574e-03 3.1253e-02 -6.0000e+00 2.6770e-02 -5.1734e-03 1.8283e-03 1.8597e-02 -6.0000e+00 2.8918e-02 2.7960e-03 1.3090e-03 8.9681e-03 -6.0000e+00 1.7246e-02 -8.0327e-03 6.7308e-04 2.4496e-03 -6.0000e+00 7.2033e-03 7.6854e-03 -4.1580e-04 3.3079e-05 2.9914e-05 -6.0000e+00 5.1926e-04 -1.8236e-02 4.6415e-05 10 0 0 10 0 0 99.90 23.26 0.26 -0.01824 -0.02136 780 210 1 5 0 60.620 26.21 20.00 23.26 29.56 21.2 1015.48 2903 -798 -6206 -3651 -6085 -11022 -3174 -3783 -454 -9262 -3889 -632 -836 -2792 -773 1670 -1093 -168 -2007 -374 -1275 234 2006 759 -1137 -137 791 -1396 -1090 -1187 962 839 2714 -1708 -1577 -2376 -2139 -1395 -1026 -804 -887 -746 -1046 -646 -1544 -612 -1025 -1046 -870 -780 -75 906 833 780 1096 95 805 318 174 137 840 653 1717 1508 1108 848 134 94 -122 852 710 416 353 399 110 71 -31 173 30 -287 -251 -771 -1068 -1299 -1115 -996 -148 37 224 154 189 557 780 356 769 781 748 661 160 -147 -338 -521 -494 -309 -724 -532 -799 -598 -701 -138 -133 57 -25 89 46 8 303 96 302 -48 -94 -304 -283 -7 326 427 729 792 844 649 229 529 28 109 -195 17 -165 153 -117 -211 -194 -103 -104 -193 67 -22 -188 -106 -166 -328 -91 -122 -16 -351 -158 -26 -38 -139 -44 106 -78 -13 -161 -31 -110 20 190 77 -126 -16 92 -162 -119 -127 106 103 360 -253 -230 -338 -317 -235 -207 -193 -242 -218 -321 -202 -491 -193 -325 -328 -271 -245 -24 316 314 313 462 42 362 145 79 61 376 308 874 837 647 486 72 49 -65 499 467 295 256 285 74 44 -18 91 16 -165 -164 -570 -870 -1131 -1027 -982 -154 40 248 169 198 536 689 298 648 714 764 757 202 -194 -437 -628 -550 -331 -812 -639 -1017 -798 -986 -206 -213 96 -43 146 70 11 415 132 437 -74 -152 -500 -457 -10 487 607 988 1036 1132 939 359 875 48 194 -364 34 -340 323 -253 -457 -408 -208 -203 -369 SS 20240627T132709.7Z 8944.560529 280 1 47.34 2 49.09 89.91 65.51 239.26 0.00 1 0.00 1 0 17 7.608e-03 4.746e-03 1.996e-03 6.066e-04 2.192333e-01 3.136945e-04 2.560471e-03 -6.000000e+00 4.521558e-03 232.71 -2.00 3.43 -2.00 317.56 0.00e+00 -1.274135e-05 4.815265e-05 5.203416e-05 -6.000000e+00 2.021195e-04 290.02 -2.00 20.00 -2.00 316.64 0.00e+00 1.524 0.000 302.00 328.00 3 1.7518e+00 8.4221e-04 1.9075e-02 -6.0000e+00 1.1333e-02 1.4292e-05 9.4909e-04 1.1327e-02 -6.0000e+00 1.2240e-02 4.1979e-03 5.6345e-04 5.4590e-03 -6.0000e+00 7.2999e-03 -6.2196e-03 2.7239e-04 1.4716e-03 -6.0000e+00 3.0503e-03 1.5547e-02 4.6736e-05 1.8987e-05 1.8464e-05 -6.0000e+00 2.1971e-04 -1.9378e-02 1.1350e-04 10 0 0 10 0 0 99.99 23.25 0.25 -0.01938 -0.01903 820 221 1 5 0 57.650 26.11 20.00 23.25 33.56 21.9 1047.93 -887 -1758 -2174 -1662 -3290 -2169 -1383 -1140 87 -603 -673 -698 92 390 263 149 -142 -786 89 180 -399 338 815 573 662 48 330 -259 -180 833 933 1679 632 61 -1292 -1443 -1412 -354 -239 201 -217 -511 -1012 -1116 -1252 -695 -637 -765 -598 -470 271 437 969 1003 908 322 949 405 348 452 938 1027 1514 1146 1098 525 -378 -210 -230 727 572 418 85 336 -71 87 -249 -240 -150 22 -306 -872 -1117 -1403 -1123 -1093 -340 -346 -37 -50 316 231 444 238 477 668 749 674 111 26 -296 -401 -592 -260 -571 -309 -675 -545 -305 -188 4 87 -65 -65 51 -16 384 118 302 159 -45 -254 -246 120 394 545 815 849 852 670 361 400 -3 90 25 -29 -118 71 -125 -240 -131 -108 -338 -399 -93 -206 -265 -193 -351 -212 -137 -124 10 -78 -87 -91 13 60 46 29 -29 -166 19 40 -92 78 206 151 184 14 97 -73 -47 207 234 444 181 18 -383 -409 -415 -116 -93 92 -112 -280 -576 -647 -726 -399 -361 -422 -320 -247 144 246 576 627 590 215 642 277 236 302 631 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