File name: Pandora156s1_HamptonVA-HU_20240629_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T213218.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240629_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240629T105402.4Z 8946.454195 208 1 47.29 2 79.09 69.10 32.25 163.25 0.00 1 0.00 1 0 25 4.567e-01 1.084e-02 2.939e-01 6.819e-03 6.458671e-01 3.828886e-03 7.140150e-03 -6.000000e+00 2.730141e-01 232.69 -2.00 3.43 -2.00 321.62 0.00e+00 6.666818e-03 2.150976e-03 4.978236e-04 -6.000000e+00 1.240038e-02 290.19 -2.00 20.00 -2.00 321.00 0.00e+00 5.088 0.002 302.00 328.00 3 1.4780e+00 1.4828e-02 6.1883e-02 -6.0000e+00 6.8522e-01 1.2708e-01 2.0423e-02 3.7122e-02 -6.0000e+00 7.4133e-01 -1.7194e-01 1.9035e-02 1.8200e-02 -6.0000e+00 4.4172e-01 6.1344e-02 8.8140e-03 9.9277e-03 -6.0000e+00 1.8372e-01 3.7703e-04 -8.5594e-04 2.1057e-04 1.1090e-04 -6.0000e+00 1.3212e-02 -1.7176e-02 4.8824e-05 12 8 8 10 0 0 99.40 23.22 0.52 -0.01718 -0.02361 108 29 1 5 0 437.750 26.11 20.00 23.22 32.20 21.5 1035.00 17331 37106 -137102 -178230 -188152 -31898 -232395 -123136 -197879 -60846 -171162 -62113 900000 -52293 -41821 -55322 -63200 900000 -22555 -27829 -74912 13436 -26601 13270 -16781 -47624 -11085 -21165 -44140 -52321 7797 -31836 112697 -36708 -10644 -26461 31023 13722 -658 -21052 10981 25312 3336 6551 -1098 13212 3984 7217 7648 6080 15942 3226 -185 11377 23210 11816 5753 2529 9771 5883 766 1519 8300 10105 7132 -10112 1944 7654 4605 1784 642 2694 1566 5049 -3132 315 -724 2016 -1632 -2503 1295 -1780 721 -2492 -967 -1853 -607 643 -516 -989 1421 733 -1674 -1567 960 -1259 -1192 -1012 -326 320 298 -28 -719 -111 -1625 -345 -1620 -176 582 -462 -90 9 128 486 281 208 277 -32 -27 -458 -285 -210 271 125 -353 495 887 593 1218 880 245 618 -30 140 -64 82 -555 77 -261 242 -70 -163 -188 -254 115 247 -1155 -2291 -2502 -212 -4738 -928 -3508 -405 -2655 -413 900000 -440 -408 -760 -1092 900000 -320 -444 -1992 149 -448 170 -290 -1182 -211 -442 -1076 -1461 148 -1016 1070 -1611 -363 -1106 766 463 -29 -1362 594 1394 228 453 -84 966 307 596 657 526 1461 350 -23 1377 2866 1597 854 392 1390 855 127 250 1541 1948 1549 -2662 445 1781 1094 492 202 896 538 1627 -1023 97 -205 536 -475 -845 497 -762 338 -1308 -532 -1100 -378 414 -342 -651 934 453 -1000 -918 581 -881 -967 -945 -318 329 301 -29 -664 -96 -1466 -328 -1652 -188 664 -587 -127 13 192 720 429 302 391 -46 -40 -735 -471 -344 425 189 -520 695 1195 789 1703 1381 434 1186 -61 302 -147 201 -1434 204 -653 641 -179 -394 -430 -570 SS 20240629T110450.8Z 8946.461699 211 1 47.32 2 77.07 70.57 31.68 168.11 0.00 1 0.00 1 0 17 2.732e-01 5.884e-03 2.399e-01 3.190e-03 5.762867e-01 1.752683e-03 6.316571e-03 -6.000000e+00 1.622835e-01 232.69 -2.00 3.43 -2.00 321.13 0.00e+00 2.797991e-04 8.339569e-04 1.007064e-03 -6.000000e+00 7.263484e-03 290.19 -2.00 20.00 -2.00 320.44 0.00e+00 4.349 0.001 302.00 328.00 3 1.1066e+00 6.1133e-03 5.3398e-02 -6.0000e+00 4.0669e-01 1.7723e-02 8.1625e-03 3.1828e-02 -6.0000e+00 4.3932e-01 -5.2231e-03 7.5477e-03 1.5087e-02 -6.0000e+00 2.6203e-01 -1.0704e-02 3.6128e-03 4.8248e-03 -6.0000e+00 1.0946e-01 1.2073e-03 -4.0624e-04 9.9634e-05 5.4576e-05 -6.0000e+00 7.8904e-03 -1.7505e-02 5.6112e-05 10 0 0 10 0 0 99.06 23.23 0.40 -0.01751 -0.02056 230 62 1 5 0 205.680 26.11 20.00 23.23 32.69 21.4 1037.97 -109125 -107803 -112570 -54853 2786 25123 156967 20375 75387 126572 -41572 -40663 -9731 -36337 -17207 -43730 -33774 -45863 -17883 -17450 234 -33502 -35550 -16359 -7972 -4139 -18012 3409 3330 7131 12160 28546 8332 0 4583 -5222 -6013 -8716 5661 -3530 -2758 -5583 -2269 -8240 -3620 -2789 111 -4473 2332 1202 3450 -2062 6266 6023 6205 4649 5227 793 -1576 365 1354 -907 -58 98 1785 -523 -1227 -1134 -892 -643 2096 1817 313 464 981 433 1274 -68 2211 412 287 93 -620 -1948 -1493 -1002 -1224 -471 447 926 -75 498 90 679 -20 709 1866 1109 232 704 138 -102 -1379 -119 -539 -583 -845 -461 -1227 -656 -222 -302 -458 -129 149 -22 335 315 204 49 -118 208 -69 0 259 699 509 1243 707 678 85 45 -184 -113 -461 19 -76 130 3 91 -155 -130 -86 -66 -747 -872 -1051 -290 9 78 488 63 235 394 -298 -316 -67 -407 -198 -789 -631 -1070 -345 -358 4 -865 -973 -402 -198 -107 -555 84 80 169 306 719 298 0 190 -234 -288 -499 343 -286 -257 -587 -245 -979 -418 -325 13 -550 276 151 462 -325 1004 1055 1166 934 1088 176 -354 79 292 -212 -15 28 548 -166 -380 -350 -291 -236 844 791 142 205 404 163 433 -23 742 159 130 48 -364 -1253 -1018 -728 -947 -378 363 737 -58 354 60 440 -14 538 1604 1096 259 822 159 -110 -1366 -111 -519 -601 -923 -530 -1522 -884 -329 -484 -760 -210 232 -32 473 451 308 79 -195 340 -110 0 383 986 691 1644 987 1048 146 84 -363 -233 -1013 43 -186 325 8 230 -377 -300 -190 -142 SS 20240629T111412.2Z 8946.468197 214 1 1.76 2 75.30 71.83 31.33 172.43 0.00 1 0.00 1 0 17 3.346e-01 9.435e-03 2.310e-01 6.875e-03 5.107159e-01 3.732366e-03 5.667132e-03 -6.000000e+00 2.009756e-01 232.69 -2.00 3.43 -2.00 320.40 0.00e+00 -1.348189e-04 1.432795e-03 3.872997e-04 -6.000000e+00 9.866478e-03 290.19 -2.00 20.00 -2.00 319.64 0.00e+00 3.860 0.001 302.00 328.00 3 1.1422e+00 1.1717e-02 4.6974e-02 -6.0000e+00 5.0214e-01 -7.2302e-03 1.4640e-02 2.6852e-02 -6.0000e+00 5.4276e-01 2.3298e-02 1.2605e-02 1.2914e-02 -6.0000e+00 3.2297e-01 -2.0025e-02 6.3288e-03 3.5776e-03 -6.0000e+00 1.3543e-01 2.0005e-03 -4.3786e-04 2.1488e-04 4.3763e-05 -6.0000e+00 1.0017e-02 -1.7882e-02 7.8544e-05 12 9 9 12 1 1 99.41 23.23 0.29 -0.01788 -0.02117 8 66 1 5 0 193.430 26.11 20.00 23.23 33.00 21.5 1040.09 47394 -83322 900000 900000 900000 -131119 900000 -34894 27915 315437 72872 51739 -26273 25641 -18351 11748 -39311 -10266 -17727 -2155 -18397 -4896 -14975 31494 -5412 -858 900000 40336 -4952 -21168 7192 4991 41598 -8860 37398 15465 14617 -10179 -344 -14903 537 3467 -4187 2134 -4660 1661 -168 -3543 -5901 4540 3972 2569 -2213 -1875 3318 5084 -353 2358 2210 2752 92 -2114 3180 3338 2069 -3572 843 -1266 1903 -941 -971 1372 2151 1718 73 728 -703 1329 -213 1289 877 537 -1080 -1955 -3456 -1826 -59 -190 -163 -225 -32 624 1362 -1060 936 1025 1548 1303 509 485 331 -154 -1016 196 -629 -645 -738 -1523 164 -170 -909 -310 -607 -301 22 -260 -66 1242 -398 254 1664 -247 -391 644 115 44 677 193 882 194 713 624 -168 -667 -284 -97 -346 447 -652 -180 520 232 -107 -358 318 -1149 900000 900000 900000 -2894 900000 -358 187 2113 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