File name: Pandora156s1_HamptonVA-HU_20240714_L2Fit_fout2c2d20220209p1-8.txt File generation date: 20240715T052313.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v2d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240714_L1_smca1c2d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaLab+Fld 1.8 VP 20220209 First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240714T104959.8Z 8961.451387 57 1 47.47 2 81.25 69.54 154.89 345.17 0.00 1 0.00 1 0 25 6.017e-01 2.145e-02 3.848e-01 1.582e-02 7.877347e-01 9.904969e-03 9.076158e-03 -6.000000e+00 3.776203e-01 232.55 -2.00 3.43 -2.00 322.05 0.00e+00 -7.982186e-03 6.482425e-03 9.980582e-03 -6.000000e+00 2.514812e-02 291.51 -2.00 20.00 -2.00 321.50 0.00e+00 6.200 0.004 302.00 328.00 3 1.6601e+00 4.3361e-02 9.4787e-02 -6.0000e+00 9.5331e-01 1.4905e-01 6.4345e-02 8.8564e-02 -6.0000e+00 1.0436e+00 -2.6554e-01 6.2062e-02 3.2601e-02 -6.0000e+00 6.2100e-01 1.0659e-01 2.7456e-02 7.1823e-03 -6.0000e+00 2.5804e-01 1.0072e-04 -1.0353e-03 5.1065e-04 1.4095e-04 -6.0000e+00 1.9504e-02 -1.7130e-02 1.0936e-04 12 8 8 10 0 0 -18.31 23.18 1.00 -0.01713 -0.02491 53 14 1 5 0 894.710 26.11 19.99 23.18 33.43 21.8 1030.24 -223351 900000 900000 900000 900000 900000 -248890 -292802 -18015 900000 -62946 900000 900000 900000 900000 900000 900000 900000 900000 -181740 900000 -79169 156931 -78899 900000 900000 900000 900000 -110806 900000 900000 -98172 -73196 16397 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4743 3343 -855 1072 -1869 1376 -661 372 1222 2191 1291 266 866 -924 -476 -1535 -1388 1272 1426 562 2309 -209 -243 2002 -1265 -167 -136 2197 -3902 865 -2781 2606 1471 682 -2059 252 -2349 62 -5116 -4077 1540 -39 -790 -1063 2096 941 -6064 -3029 -407 -472 1448 4748 -1077 -210 1371 3119 -852 3318 1676 966 458 2655 -1557 2727 -555 820 1346 1229 -2334 839 -885 -2955 802 -1940 SS 20240714T110129.8Z 8961.459372 61 1 47.35 2 79.09 71.14 155.38 351.47 0.00 1 0.00 1 0 25 5.220e-01 1.066e-02 3.060e-01 5.989e-03 6.505686e-01 3.367108e-03 7.137911e-03 -6.000000e+00 3.121109e-01 232.55 -2.00 3.43 -2.00 321.55 0.00e+00 3.404457e-03 1.849958e-03 5.474304e-04 -6.000000e+00 1.416564e-02 291.51 -2.00 20.00 -2.00 320.90 0.00e+00 5.084 0.002 302.00 328.00 3 1.2541e+00 1.2905e-02 6.1370e-02 -6.0000e+00 7.8247e-01 1.0693e-01 1.7893e-02 3.5060e-02 -6.0000e+00 8.4551e-01 -1.4853e-01 1.6670e-02 1.7981e-02 -6.0000e+00 5.0298e-01 4.9664e-02 7.7330e-03 7.1326e-03 -6.0000e+00 2.1007e-01 4.7664e-04 -4.5526e-04 1.8487e-04 8.8392e-05 -6.0000e+00 1.5438e-02 -1.7943e-02 9.8361e-05 12 8 8 10 0 0 10.34 23.18 0.38 -0.01794 -0.02136 134 36 1 5 0 353.240 26.11 20.00 23.18 33.92 22.0 1034.38 -209876 -86514 -183462 900000 -250580 163023 -154042 900000 -181609 -107586 -125333 79389 -98353 7153 -30061 99943 -10651 -65157 -9529 -5848 145991 -52509 178869 -50620 -17565 -44706 621 -30060 97829 -36413 -8411 -21535 9265 42128 -12739 15928 -20217 -1050 -4494 -7767 -10971 4343 -4443 12002 -33 14254 6075 3179 7454 -4533 19826 -1869 8953 -3053 7577 794 13207 153 6856 -807 7429 1825 5641 -5512 7894 3916 1041 1609 7622 6297 615 3531 1694 3999 0 205 -3168 -20 -1556 -1465 -2895 -609 -1023 -2338 -933 -1512 500 417 -16 -727 249 -265 1201 -1264 472 28 -801 747 -1027 2357 -946 85 -2261 -361 -1605 1200 -2034 -363 -1219 -6 -760 246 -88 564 321 -225 -772 49 114 -625 674 -325 376 581 110 953 738 993 300 153 421 711 201 298 -725 273 -235 426 -447 85 -237 -87 -362 -69 -2451 -505 -2206 900000 -5595 952 -1323 900000 -2620 -813 -1205 464 -1041 42 -263 584 -109 -1284 -118 -75 852 -1131 1044 -1182 -321 -1142 10 -680 607 -904 -181 -637 237 861 -456 419 -804 -40 -215 -465 -785 293 -349 832 -3 1009 479 266 623 -453 1700 -223 1065 -448 1076 127 1938 26 1073 -134 1144 317 1058 -1308 1789 942 253 391 1855 1756 205 1235 617 1383 0 63 -911 -5 -448 -484 -1145 -273 -517 -1299 -545 -950 327 286 -11 -506 164 -164 690 -731 284 19 -641 679 -1068 2513 -1025 85 -2094 -310 -1432 1112 -2061 -384 -1400 -7 -1068 373 -139 886 485 -326 -1090 70 171 -994 1088 -525 582 867 159 1314 984 1301 419 240 734 1349 408 638 -1667 662 -601 1109 -1189 224 -601 -209 -822 -153 SS 20240714T111218.4Z 8961.466879 64 1 47.37 2 77.04 72.63 155.61 357.55 0.00 1 0.00 1 0 17 2.528e-01 6.136e-03 1.628e-01 2.900e-03 5.675980e-01 1.593285e-03 6.289736e-03 -6.000000e+00 1.502622e-01 232.55 -2.00 3.43 -2.00 321.09 0.00e+00 1.353186e-03 7.578501e-04 3.457484e-04 -6.000000e+00 7.007275e-03 291.52 -2.00 20.00 -2.00 320.38 0.00e+00 4.338 0.001 302.00 328.00 3 1.0230e+00 5.5673e-03 5.2705e-02 -6.0000e+00 3.7707e-01 2.0906e-02 7.4040e-03 3.0259e-02 -6.0000e+00 4.0756e-01 -2.4531e-02 6.7420e-03 1.4852e-02 -6.0000e+00 2.4268e-01 -1.9743e-04 3.2380e-03 4.8440e-03 -6.0000e+00 1.0184e-01 1.3400e-03 -6.7434e-04 9.1027e-05 5.8337e-05 -6.0000e+00 7.3050e-03 -1.7324e-02 5.5531e-05 10 0 0 10 0 0 -10.36 23.18 0.35 -0.01732 -0.02239 241 65 1 5 0 196.520 26.11 20.00 23.18 34.40 21.9 1038.23 -163006 -23841 900000 42473 -102347 -144157 -108953 -29517 2469 900000 -36199 -34767 -47272 -13400 31626 46446 -13070 -4664 16772 -28146 -22388 -2777 27456 1526 -26962 -16271 -17235 -6129 -12570 -991 -13850 -14225 -14375 13210 -3706 -9931 -6078 452 -8241 -2557 -585 595 4050 3265 -2426 -2607 -726 -2287 -1023 5348 3374 1534 -216 3386 2980 207 1725 3280 1273 259 -971 1387 807 5349 1754 2005 541 -70 -655 802 1456 605 -141 -135 -203 311 74 1064 716 -1831 -1423 -1540 -815 -1560 -583 -900 -782 -598 -555 1229 1057 568 746 -788 -131 660 1191 1118 167 -140 -788 299 70 69 -576 -342 -1877 -1250 -610 390 567 -84 -2 -336 248 432 374 333 419 -406 -415 -385 382 341 82 -18 135 182 777 682 521 476 -618 -378 -230 -82 203 189 -297 -94 -179 117 236 -237 -1969 -94 900000 120 -842 -1742 -980 -150 10 900000 -266 -275 -508 -129 241 368 -214 -78 247 -692 -544 -57 427 33 -854 -497 -551 -173 -370 -27 -474 -575 -675 519 -174 -486 -302 24 -592 -210 -55 60 420 355 -284 -311 -87 -283 -129 662 462 238 -38 619 587 44 376 716 280 57 -217 322 210 1485 546 628 167 -22 -214 291 593 268 -64 -60 -85 118 26 349 245 -727 -658 -819 -481 -1001 -395 -654 -604 -483 -456 980 805 405 498 -518 -90 501 1030 1105 186 -165 -918 320 69 64 -556 -352 -2077 -1454 -754 521 834 -134 -3 -550 385 632 529 477 630 -652 -690 -636 607 524 121 -26 184 244 1085 1055 893 882 -1224 -783 -504 -192 493 473 -688 -217 -437 270 519 -515 SS 20240714T112237.6Z 8961.474047 67 1 47.30 2 75.06 74.04 155.63 3.40 0.00 1 0.00 1 0 25 1.074e-01 4.239e-03 6.277e-02 1.799e-03 5.026002e-01 9.708027e-04 5.599460e-03 -6.000000e+00 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