File name: Pandora156s1_HamptonVA-HU_20240808_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T220418.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240808_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240808 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240808T141326.7Z 8986.592670 154 1 20.18 2 44.47 106.20 89.36 91.78 0.00 1 0.00 1 0 17 2.003e-02 7.567e-03 1.335e-02 5.691e-03 1.894521e-01 2.961694e-03 2.211171e-03 -6.000000e+00 1.186696e-02 231.75 -2.00 3.43 -2.00 316.74 0.00e+00 -2.996322e-04 3.734725e-04 1.159948e-04 -6.000000e+00 5.369441e-04 292.08 -2.00 20.00 -2.00 315.84 0.00e+00 1.399 0.000 302.00 328.00 3 5.5852e+00 7.8225e-03 1.7057e-02 -6.0000e+00 2.9650e-02 4.4870e-02 8.7584e-03 9.6972e-03 -6.0000e+00 3.2035e-02 1.4059e-04 5.0316e-03 4.6706e-03 -6.0000e+00 1.9146e-02 -5.5122e-03 2.3297e-03 1.3282e-03 -6.0000e+00 8.0349e-03 3.9781e-04 -1.6807e-04 1.7570e-04 1.6508e-05 -6.0000e+00 5.7845e-04 -2.0839e-02 8.6821e-05 12 9 1 12 1 1 99.98 23.18 0.99 -0.02084 -0.02210 7 5 1 5 0 2521.230 26.11 20.00 23.18 29.82 22.4 991.49 3229 1485 -350 -4499 5187 220 5140 -2786 6784 -2142 15417 -220 -2100 -2008 -1411 -461 -1593 946 -1451 2490 -1879 -721 -1023 -385 -5252 2483 -1389 -415 575 -1029 1605 4652 -426 -2542 219 -1153 284 -1992 241 -243 761 -1319 -577 -823 -89 -715 -1745 -1200 1059 -1943 -237 -641 2475 1678 984 1416 1831 -59 -419 1763 600 714 2164 1397 943 1661 -836 -772 -903 361 -278 238 -284 40 602 -638 364 -306 -316 252 -433 -745 -532 -301 -1022 -1976 425 384 -602 -226 -256 -314 70 -71 932 23 -192 680 124 384 369 -1010 -814 -126 42 -167 -473 -491 62 -600 83 -178 570 248 -376 298 -528 -210 -74 451 -159 338 214 426 -191 1142 -376 846 542 999 -785 541 234 78 -552 -175 251 100 226 223 138 -447 -166 -1017 525 269 -66 -851 799 33 742 -478 1179 -433 2621 -43 -447 -474 -371 -131 -479 283 -458 776 -626 -237 -338 -131 -1970 896 -525 -149 189 -325 493 1459 -149 -946 77 -416 98 -792 111 -132 456 -857 -384 -556 -60 -477 -1158 -766 638 -1179 -144 -411 1624 1162 711 1039 1361 -45 -317 1286 447 556 1779 1232 856 1430 -674 -581 -680 292 -252 229 -283 40 560 -553 300 -231 -231 195 -375 -671 -518 -309 -1114 -2329 521 493 -798 -296 -318 -359 72 -68 925 23 -210 808 161 513 478 -1241 -930 -140 49 -209 -625 -677 89 -903 131 -289 914 380 -535 387 -656 -261 -96 624 -235 509 319 615 -265 1488 -472 1072 693 1338 -1060 749 332 113 -835 -278 415 170 392 388 236 -745 -267 -1630 SS 20240808T144830.1Z 8986.617016 170 1 47.28 2 37.91 114.26 82.64 97.08 0.00 1 0.00 1 0 17 1.181e-02 6.321e-03 6.764e-03 3.130e-03 1.635948e-01 1.625076e-03 1.914251e-03 -6.000000e+00 6.996180e-03 231.74 -2.00 3.43 -2.00 316.61 0.00e+00 5.201897e-04 1.981903e-04 2.670077e-05 -6.000000e+00 3.164881e-04 292.08 -2.00 20.00 -2.00 315.72 0.00e+00 1.266 0.000 302.00 328.00 3 4.8141e+00 4.2723e-03 1.5201e-02 -6.0000e+00 1.7480e-02 3.0387e-02 4.7806e-03 8.3848e-03 -6.0000e+00 1.8885e-02 7.0635e-03 2.7420e-03 4.0409e-03 -6.0000e+00 1.1287e-02 -7.8101e-03 1.2586e-03 1.1568e-03 -6.0000e+00 4.7376e-03 1.0339e-03 1.1273e-06 9.6186e-05 1.4060e-05 -6.0000e+00 3.4096e-04 -2.0508e-02 1.5600e-04 10 0 0 10 0 0 99.99 23.18 0.18 -0.02051 -0.02050 77 21 1 5 0 613.900 26.11 19.99 23.18 31.26 22.3 1002.12 551 -133 4001 -940 -2215 -2477 -6165 488 -190 1516 -532 -1126 -418 283 1959 -1155 -3922 173 255 1134 942 90 -289 -575 3331 -664 -547 -1034 121 249 2163 2066 1020 1429 552 -3198 -1329 -1345 -200 125 2096 -181 -1584 -999 -2219 30 -840 -821 -1719 -462 748 -91 959 2038 1430 727 881 -215 471 1406 1039 299 1660 805 1661 701 -520 -882 -27 53 624 681 102 678 -439 193 -74 -364 -78 -112 -1181 -974 -1688 -1596 -1735 -498 -653 21 -43 -93 329 258 280 -393 273 800 495 598 403 346 246 -437 -487 -483 -177 -225 -749 -553 -181 18 217 196 22 11 -170 -106 201 -327 298 437 130 97 100 -188 318 268 638 580 879 439 303 370 102 -547 125 -116 -172 -24 -80 170 -193 66 -360 -521 99 -26 779 -184 -393 -434 -1128 91 -40 329 -118 -247 -96 72 543 -360 -1309 56 85 385 328 32 -101 -208 1212 -260 -215 -392 42 82 692 692 365 529 199 -1138 -478 -544 -94 69 1259 -118 -1076 -685 -1537 20 -560 -528 -1075 -278 450 -58 636 1396 1019 530 651 -161 347 1015 761 231 1355 704 1471 598 -409 -697 -21 44 540 631 98 638 -430 173 -60 -269 -55 -84 -997 -906 -1710 -1703 -1954 -594 -832 26 -55 -116 419 303 298 -385 260 800 542 719 526 467 323 -540 -562 -545 -209 -285 -1007 -776 -262 28 343 320 35 17 -241 -139 248 -405 385 605 192 146 150 -275 444 355 797 694 1052 553 403 511 143 -788 186 -182 -282 -40 -139 293 -329 110 -579 -828 SS 20240808T145726.4Z 8986.623222 173 1 39.34 2 36.30 116.62 80.94 98.46 0.00 1 0.00 1 0 17 1.267e-02 6.733e-03 7.496e-03 3.732e-03 1.622072e-01 1.946017e-03 1.887345e-03 -6.000000e+00 7.506787e-03 231.74 -2.00 3.43 -2.00 316.25 0.00e+00 3.318269e-04 2.198764e-04 3.012775e-05 -6.000000e+00 3.395308e-04 292.08 -2.00 20.00 -2.00 315.38 0.00e+00 1.240 0.000 302.00 328.00 3 5.5316e+00 5.1043e-03 1.4923e-02 -6.0000e+00 1.8756e-02 3.7917e-02 5.6958e-03 8.2579e-03 -6.0000e+00 2.0262e-02 6.1481e-03 3.2565e-03 3.9870e-03 -6.0000e+00 1.2110e-02 -9.6507e-03 1.4727e-03 1.1085e-03 -6.0000e+00 5.0840e-03 5.1891e-04 2.1921e-04 1.1481e-04 1.4348e-05 -6.0000e+00 3.6578e-04 -2.1091e-02 1.8205e-04 12 9 1 12 1 1 99.83 23.19 0.34 -0.02109 -0.01944 14 5 1 5 0 2622.220 26.11 20.00 23.19 31.62 22.4 1005.38 -693 -3064 -1762 -5724 -1202 -5108 67 -1182 1369 -592 169 464 -2778 1486 802 550 1230 705 2422 1981 -491 1202 960 -525 151 -281 1194 -3181 -610 6214 677 542 1763 723 -1905 -2526 -1896 -1208 -201 650 -83 -169 -954 -192 -1155 89 -574 -405 -1239 -354 107 809 169 1292 900 -381 1386 1190 -1538 362 2107 556 1607 614 578 217 285 -589 -915 354 1150 351 173 478 -506 398 75 -75 -308 -689 -727 -525 -1644 -1724 -1289 -845 135 -326 415 486 292 303 -523 -510 573 -180 -271 640 572 385 -418 -235 -753 -707 -943 -321 -600 -322 -109 399 -229 -456 257 -413 372 316 -66 285 8 123 354 124 864 -255 -103 1015 943 582 356 527 426 430 102 -317 333 37 275 211 -238 -13 -378 -858 -136 -540 -138 -685 -398 -1284 -231 -938 13 -245 307 -134 40 109 -712 404 245 183 423 248 859 724 -188 451 361 -206 62 -119 501 -1335 -231 2072 238 199 676 290 -760 -963 -739 -526 -102 383 -55 -119 -694 -140 -851 64 -410 -279 -828 -229 70 547 121 956 691 -301 1092 944 -1239 283 1635 458 1404 575 553 198 237 -460 -713 295 1056 348 176 480 -492 353 60 -55 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