File name: Pandora156s1_HamptonVA-HU_20240905_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T221236.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240905_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240905T113035.1Z 9014.479572 53 1 21.71 2 80.76 88.77 107.00 82.69 0.00 1 0.00 1 0 33 6.401e-01 2.190e-02 3.676e-01 1.118e-02 7.270534e-01 6.588628e-03 8.254820e-03 -6.000000e+00 3.942124e-01 230.02 -2.00 3.43 -2.00 321.81 0.00e+00 -4.511875e-03 4.036276e-03 5.388376e-03 -6.000000e+00 2.168078e-02 290.86 -2.00 20.00 -2.00 321.22 0.00e+00 5.913 0.003 302.00 328.00 3 1.3067e+00 2.6919e-02 7.5910e-02 -6.0000e+00 9.8210e-01 2.2408e-01 3.9403e-02 5.6023e-02 -6.0000e+00 1.0732e+00 -4.1117e-01 3.6505e-02 2.6121e-02 -6.0000e+00 6.3630e-01 1.7637e-01 1.6199e-02 5.9407e-03 -6.0000e+00 2.6522e-01 2.0096e-04 -1.8904e-03 3.5187e-04 1.0637e-04 -6.0000e+00 1.9684e-02 -7.6922e-03 -6.1692e-05 12 9 9 12 1 1 99.89 23.27 0.45 -0.00769 -0.02190 31 19 1 5 0 677.760 26.21 20.00 23.27 26.19 22.5 969.39 900000 900000 -97556 900000 900000 900000 900000 -186455 -115975 -64866 -98385 -153587 -260138 -152851 900000 18358 900000 900000 900000 272602 -7911 900000 -24482 900000 -8152 900000 900000 -4995 -74288 75922 41268 -40202 80378 27643 900000 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-1366 164 -196 724 -1218 -2008 -1150 1482 -190 -2729 1781 -743 303 -123 43 3821 1656 -972 -758 -1467 -1876 -1092 -940 -1765 -1335 -1658 -2544 -1994 -1941 -881 -1130 -614 -1478 -1606 1690 25 470 -348 -486 -326 -1644 -363 2102 312 2591 16 1282 2540 2901 2159 1776 468 2790 1037 245 368 -42 1065 -492 -1037 -519 107 -784 65 -3983 SS 20240905T113920.0Z 9014.485649 57 1 47.29 2 79.02 90.08 105.34 84.06 0.00 1 0.00 1 0 29 3.839e-01 8.979e-03 3.273e-01 7.980e-03 6.438975e-01 4.473989e-03 7.004565e-03 -6.000000e+00 2.294254e-01 230.02 -2.00 3.43 -2.00 321.50 0.00e+00 4.025804e-03 2.452737e-03 7.182522e-04 -6.000000e+00 1.063123e-02 290.86 -2.00 20.00 -2.00 320.85 0.00e+00 5.057 0.002 302.00 328.00 3 1.6551e+00 1.6923e-02 6.1054e-02 -6.0000e+00 5.7344e-01 7.9030e-02 2.3642e-02 3.6128e-02 -6.0000e+00 6.2300e-01 -7.3102e-02 2.2458e-02 1.7554e-02 -6.0000e+00 3.6853e-01 1.6526e-02 1.0438e-02 8.3312e-03 -6.0000e+00 1.5398e-01 3.3004e-04 -5.5259e-04 2.4787e-04 8.8613e-05 -6.0000e+00 1.1381e-02 -9.2473e-03 5.4969e-05 11 8 0 10 0 0 99.88 23.27 0.31 -0.00925 -0.01340 112 30 1 5 0 422.150 26.11 20.00 23.27 26.71 22.7 973.83 900000 -152436 -175892 -31317 -189886 -87199 900000 -132226 900000 -33901 28810 -85149 900000 -131826 56520 -50384 -66273 -65907 900000 -18936 -18104 -51228 128849 -40380 -47730 -43271 9178 -6827 -39289 709 63754 6445 -24323 39932 1714 -1615 -28909 -20434 -22482 -15468 9287 -12119 17785 -1530 15460 -6044 3174 5233 2347 3252 6984 -5930 9285 801 2707 -1268 3027 5854 2633 -4352 498 10494 4519 5738 2449 3430 5542 -5110 1819 2299 3238 -39 674 -527 622 -2356 -1030 2117 66 -1085 3674 -445 -863 243 -1310 532 -217 -230 45 -39 -931 -1670 664 1127 473 237 33 1341 -819 880 -792 -810 -1000 825 -1338 1399 -2124 115 -274 -693 -837 -76 -445 -446 321 -85 1881 -101 -463 377 -1029 -97 390 581 119 328 317 1602 347 150 826 537 -152 206 -761 151 -545 81 192 305 -45 221 -69 -845 900000 -1185 -1795 -244 -2123 -678 900000 -1028 900000 -264 224 -662 900000 -2307 440 -612 -1095 -1217 900000 -258 -255 -1021 1002 -805 -1114 -1031 143 -124 -917 12 694 150 -851 869 52 -53 -1236 -934 -1278 -992 537 -954 1106 -120 1052 -523 258 430 208 303 689 -746 1115 114 408 -209 496 945 433 -753 83 1704 876 1244 597 842 1306 -1354 480 684 1076 -14 252 -193 210 -743 -293 566 19 -366 1396 -204 -445 134 -781 333 -145 -160 32 -27 -623 -1052 386 643 289 165 27 1228 -859 957 -858 -811 -911 700 -1195 1298 -2158 121 -313 -877 -1180 -115 -707 -702 480 -121 2560 -143 -690 588 -1670 -153 594 853 169 447 445 2190 511 233 1419 1007 -305 433 -1721 361 -1367 208 497 780 -110 513 -153 -1852 SS 20240905T115015.0Z 9014.493229 60 1 47.22 2 76.84 91.74 103.26 85.74 0.00 1 0.00 1 0 25 2.204e-01 5.504e-03 1.697e-01 2.355e-03 5.586842e-01 1.278271e-03 6.208937e-03 -6.000000e+00 1.295221e-01 230.02 -2.00 3.43 -2.00 321.02 0.00e+00 1.303058e-03 5.906321e-04 7.955836e-04 -6.000000e+00 5.874820e-03 290.86 -2.00 20.00 -2.00 320.30 0.00e+00 4.280 0.001 302.00 328.00 3 7.9418e-01 4.3883e-03 5.1872e-02 -6.0000e+00 3.2235e-01 3.4554e-02 5.7853e-03 3.0241e-02 -6.0000e+00 3.4904e-01 -9.6660e-03 5.2274e-03 1.4378e-02 -6.0000e+00 2.0874e-01 -7.8568e-03 2.5269e-03 4.9122e-03 -6.0000e+00 8.7614e-02 1.7912e-03 -7.0522e-04 7.3576e-05 5.5157e-05 -6.0000e+00 6.3630e-03 -9.3780e-03 3.7674e-05 10 0 0 10 0 0 98.93 23.28 0.30 -0.00938 -0.01468 255 69 1 5 0 185.140 26.21 20.00 23.28 26.96 22.5 975.18 -105837 58878 -96712 30585 -95610 78726 -66705 -4093 -92008 11584 -45873 -9835 -55535 2446 -53473 -5763 -7257 -21126 10220 -30607 -8930 9199 -12431 -13225 -1078 -30732 23164 -20762 -13980 -8927 -6309 -17519 3686 -8451 4205 -11479 -2756 -1274 1019 -6353 -2148 34 -1960 4467 -2209 -515 147 -3135 -388 -219 -366 2962 516 2388 3025 -599 1254 1190 -336 3003 -388 2585 2798 2780 1462 3084 236 1037 29 1768 177 890 12 1066 -112 743 -220 -415 -871 573 -623 -1773 -839 -1801 -322 -1564 -135 -52 393 -18 1041 -207 1399 -226 563 415 908 628 321 -2 -68 -334 -1131 -521 -592 -658 -1081 -198 -913 -102 -328 -50 149 20 63 644 173 289 116 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