File name: Pandora156s1_HamptonVA-HU_20240909_L2Fit_fout2c2d20220209p1-8.txt File generation date: 20240910T051050.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v2d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240909_L1_smca1c2d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaLab+Fld 1.8 VP 20220209 First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240909T115235.3Z 9018.494853 66 1 47.80 2 77.00 93.54 146.10 77.41 0.00 1 0.00 1 0 40 4.402e-01 1.806e-02 2.477e-01 6.542e-03 5.895993e-01 3.672320e-03 6.541323e-03 -6.000000e+00 2.619812e-01 229.74 -2.00 3.43 -2.00 321.05 0.00e+00 2.427512e-03 1.741961e-03 4.573598e-04 -6.000000e+00 1.338751e-02 290.60 -2.00 20.00 -2.00 320.35 0.00e+00 4.328 0.001 302.00 328.00 3 2.6362e+00 1.2710e-02 5.3025e-02 -6.0000e+00 6.5465e-01 1.5666e-01 1.6647e-02 3.1344e-02 -6.0000e+00 7.1124e-01 -1.5459e-01 1.4637e-02 1.5276e-02 -6.0000e+00 4.2263e-01 6.0401e-02 7.0546e-03 5.6225e-03 -6.0000e+00 1.7814e-01 2.5001e-04 -5.9840e-04 2.0708e-04 6.4225e-05 -6.0000e+00 1.3057e-02 -1.1021e-02 -2.5465e-05 12 8 8 10 0 0 -11.67 23.25 0.61 -0.01102 -0.01552 35 9 1 5 0 1365.590 26.11 20.00 23.25 23.05 22.3 948.48 -197821 900000 -63498 900000 -152718 -130530 -49253 100845 900000 900000 -170328 -37175 900000 60192 900000 -157812 900000 159021 176506 2756 97676 900000 900000 92143 20398 5818 900000 80964 -28785 6665 -14459 5789 7222 -1964 -4480 43110 46264 10050 -13145 15084 27149 15011 1602 -614 29030 8680 18641 -9234 9165 12174 12563 -2074 7676 12082 14384 8653 2547 199 3640 10470 2774 5556 5232 10127 11572 4569 1531 5441 6170 1347 -5709 1223 3986 369 -235 -3486 1447 -805 -1487 -5551 1644 751 -130 -2751 -2745 -1070 -1556 170 118 346 -327 312 -1481 -343 700 2303 -1123 109 -551 502 -1163 -971 -926 -1498 -623 -1471 -1161 -1340 -288 -1962 -27 -1082 371 -292 665 -603 767 276 401 -1071 260 462 88 303 1694 1356 1400 2580 659 1887 426 1218 166 146 -117 -38 140 90 -617 -360 306 -695 -28 -1317 -4974 900000 -562 900000 -3026 -1986 -349 642 900000 900000 -5846 -368 900000 383 900000 -11727 900000 1013 1124 59 878 900000 900000 967 474 156 900000 1092 -1069 190 -574 221 314 -97 -225 1389 1525 550 -1037 1142 2085 1339 172 -70 2632 979 1935 -1219 1099 1487 1657 -351 1297 2118 2630 1653 566 43 794 2087 603 1251 1317 2717 3295 1402 470 1604 1912 493 -2519 539 1740 162 -97 -1344 483 -264 -515 -2284 736 389 -76 -1773 -1880 -770 -1192 133 94 270 -244 216 -979 -219 467 1699 -984 108 -612 579 -1331 -1026 -889 -1379 -587 -1491 -1238 -1516 -346 -2622 -39 -1709 596 -464 1000 -868 1056 388 590 -1688 415 729 135 447 2372 1827 1813 3243 891 2798 710 2177 316 291 -249 -85 328 216 -1423 -869 704 -1529 -59 -2719 SS 20240909T120253.9Z 9018.502013 69 1 47.46 2 74.95 95.13 144.18 79.51 0.00 1 0.00 1 0 25 1.530e-01 5.739e-03 1.394e-01 2.858e-03 5.199037e-01 1.532284e-03 5.812455e-03 -6.000000e+00 8.980845e-02 229.74 -2.00 3.43 -2.00 320.68 0.00e+00 1.700684e-03 6.303148e-04 3.835629e-04 -6.000000e+00 4.072975e-03 290.60 -2.00 20.00 -2.00 319.93 0.00e+00 3.775 0.001 302.00 328.00 3 1.8507e+00 4.9706e-03 4.6359e-02 -6.0000e+00 2.2338e-01 4.9444e-02 6.3402e-03 2.7339e-02 -6.0000e+00 2.4192e-01 -1.5046e-04 5.5097e-03 1.3296e-02 -6.0000e+00 1.4469e-01 -9.9548e-03 2.7276e-03 4.5966e-03 -6.0000e+00 6.0763e-02 1.0250e-03 -4.2533e-04 8.9383e-05 5.2227e-05 -6.0000e+00 4.4151e-03 -1.0361e-02 5.3643e-05 10 0 0 10 0 0 48.98 23.26 0.29 -0.01036 -0.01356 113 30 1 5 0 419.890 26.11 20.00 23.26 23.48 22.2 952.39 28710 -69514 -26565 -30213 95051 -53188 -16920 -32201 -30633 -47546 -18849 -34002 -32131 -1062 -40337 -25262 -16286 -14982 -24997 -2876 -7679 -6286 -12194 9082 -11909 32031 -7859 -12051 -1123 -11615 10947 -380 -3651 -2375 -3836 -981 872 -12066 11908 3966 -5352 -2941 -2222 585 308 1082 -647 -514 1128 2355 -2371 4493 2329 1825 1411 1076 -936 -8 -2546 2426 -651 2163 1972 -115 1763 880 -230 -1224 677 1107 3525 203 333 488 -173 -63 478 -707 24 431 -1111 -860 -1718 733 -969 -1022 -654 -81 -126 58 621 1001 495 1019 1228 602 1134 236 200 -28 -2 -634 -611 -1246 -648 -847 -547 -671 -805 -346 -207 -133 -195 76 60 874 385 329 91 -35 -291 -343 -133 22 247 393 511 868 1354 813 435 288 -201 -139 -172 -311 52 -191 -210 166 -91 8 -4 -205 104 -795 -215 -253 265 -504 -118 -296 -316 -636 -200 -455 -502 -15 -1046 -669 -445 -443 -885 -87 -253 -207 -439 284 -498 920 -346 -544 -44 -518 433 -20 -223 -156 -256 -62 57 -1046 986 428 -727 -425 -336 89 48 169 -104 -84 185 398 -452 883 513 437 361 289 -265 -2 -732 652 -183 628 636 -42 677 340 -87 -460 263 480 1675 107 179 254 -85 -28 193 -276 10 194 -590 -520 -1163 520 -743 -838 -567 -73 -115 52 527 787 365 723 907 497 1063 253 238 -34 -2 -720 -633 -1244 -665 -931 -633 -821 -1050 -489 -320 -219 -329 126 94 1278 546 473 137 -57 -483 -567 -213 34 366 556 693 1147 1865 1239 732 521 -383 -277 -362 -693 120 -455 -508 398 -211 17 -9 -423 SS 20240909T121343.7Z 9018.509534 72 1 47.20 2 72.80 96.83 142.16 81.58 0.00 1 0.00 1 0 25 7.227e-02 4.608e-03 3.858e-02 1.692e-03 4.633838e-01 8.892152e-04 5.189771e-03 -6.000000e+00 4.243568e-02 229.73 -2.00 3.43 -2.00 320.12 0.00e+00 1.469255e-03 3.104610e-04 2.247281e-04 -6.000000e+00 1.924549e-03 290.60 -2.00 20.00 -2.00 319.32 0.00e+00 3.331 0.001 302.00 328.00 3 1.4551e+00 2.6974e-03 4.0905e-02 -6.0000e+00 1.0555e-01 4.5681e-02 3.3042e-03 2.3927e-02 -6.0000e+00 1.1431e-01 3.6200e-03 2.7133e-03 1.1740e-02 -6.0000e+00 6.8368e-02 -1.2003e-02 1.3832e-03 3.7917e-03 -6.0000e+00 2.8711e-02 2.4889e-03 -4.7040e-04 5.2487e-05 4.1023e-05 -6.0000e+00 2.0863e-03 -1.0698e-02 3.2352e-05 10 0 0 10 0 0 62.42 23.27 0.30 -0.01070 -0.01423 206 55 1 5 0 228.980 26.21 20.00 23.27 24.10 22.2 956.66 -39404 -20423 -18988 -21153 3130 -36241 -17166 -26708 -21985 -13476 -6235 -12258 -8851 -26383 6196 3065 -773 -2463 -861 -3175 -1098 -1627 -6023 -4562 -8921 -1207 -6041 671 -6971 -3510 -4092 69 3112 -542 -48 -3262 -2346 -3008 -618 1009 -938 -2416 -2531 -1898 -803 -1259 -451 228 -289 366 -449 1020 160 1032 619 1125 1427 1855 224 249 984 1820 896 1910 996 982 -173 407 175 823 166 558 104 89 -55 233 63 -506 342 375 270 -977 -1273 -1516 -1241 -1161 -201 80 -2 259 132 617 356 1011 647 796 1069 766 102 144 -204 -379 -882 -318 -584 -621 -881 -879 -517 -209 -21 -10 -3 -62 197 232 408 78 164 -96 -88 -354 -129 88 236 579 711 676 543 596 -157 218 32 85 44 -86 -158 55 -243 -284 -30 -125 69 -63 -503 -251 -248 -279 33 -495 -224 -432 -350 -236 -106 -237 -193 -760 172 93 -27 -96 -35 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