File name: Pandora156s1_HamptonVA-HU_20240925_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240926T050418.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20240925_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20240925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240925T164245.1Z 9034.696355 423 1 3.39 2 38.40 174.34 61.89 284.67 0.00 1 0.00 1 0 17 7.863e-03 5.615e-03 2.066e-03 1.267e-03 1.636629e-01 6.572612e-04 1.960891e-03 -6.000000e+00 4.593874e-03 228.32 -2.00 3.43 -2.00 315.42 0.00e+00 1.471607e-04 6.266879e-05 1.923037e-05 -6.000000e+00 2.080525e-04 289.07 -2.00 20.00 -2.00 314.68 0.00e+00 1.275 0.000 302.00 328.00 3 2.0535e+00 1.6961e-03 1.5182e-02 -6.0000e+00 1.1394e-02 1.5736e-02 1.8894e-03 8.2851e-03 -6.0000e+00 1.2355e-02 3.8943e-03 1.0767e-03 4.0494e-03 -6.0000e+00 7.3908e-03 -4.9576e-03 4.7510e-04 1.1212e-03 -6.0000e+00 3.1086e-03 1.6410e-02 -1.7161e-04 3.8127e-05 1.5717e-05 -6.0000e+00 2.2687e-04 -1.1833e-02 5.3385e-05 12 1 1 12 1 1 74.29 23.26 0.39 -0.01183 -0.01312 23 90 1 5 0 140.990 26.21 20.00 23.26 31.72 22.9 1025.38 -830 58 -338 -2536 -3950 -2289 -562 1072 588 340 -662 -672 938 -38 253 752 -154 35 251 573 375 232 48 590 994 736 98 -1061 482 972 1051 1713 1484 613 -465 -1544 -1278 -427 56 300 -798 -585 -1036 -1241 -1029 -596 -1031 -703 -786 -668 168 1216 1126 1070 694 703 607 335 402 244 1143 975 1339 837 854 429 -237 -322 -47 388 336 42 -162 262 4 -9 -310 -120 49 -33 -537 -951 -1283 -1360 -991 -1272 -434 -339 -290 -153 89 290 421 299 538 679 788 651 229 44 -272 -468 -301 -156 -388 -309 -649 -580 -383 -130 131 73 -115 15 144 45 269 180 408 53 78 -335 -409 196 584 625 858 979 838 761 416 431 -94 -58 -186 -73 -212 -27 -132 -138 -118 -204 -355 -577 -222 17 -100 -723 -1021 -592 -145 299 166 102 -199 -200 290 -13 97 312 -67 16 114 265 177 110 23 286 503 386 52 -541 224 425 460 781 716 308 -227 -728 -624 -234 33 206 -615 -439 -803 -975 -804 -460 -785 -558 -600 -498 126 949 926 848 571 587 515 287 339 204 959 859 1261 840 871 417 -212 -268 -39 351 336 42 -166 263 4 -8 -265 -101 40 -29 -484 -949 -1388 -1440 -1103 -1522 -549 -418 -365 -190 112 335 473 310 550 733 863 784 279 55 -332 -572 -344 -175 -459 -392 -814 -758 -520 -184 194 104 -162 21 189 58 329 222 528 69 108 -475 -575 266 755 821 1066 1165 1006 961 555 597 -124 -77 -260 -107 -326 -41 -201 -210 -176 -315 -533 -860 SS 20240925T165049.8Z 9034.701965 426 1 13.18 2 38.29 177.59 63.41 285.61 0.00 1 0.00 1 0 17 7.291e-03 5.467e-03 1.906e-03 1.089e-03 1.630332e-01 5.621440e-04 1.953146e-03 -6.000000e+00 4.260580e-03 228.32 -2.00 3.43 -2.00 315.71 0.00e+00 1.484065e-04 5.719416e-05 2.412181e-05 -6.000000e+00 1.929289e-04 289.07 -2.00 20.00 -2.00 314.95 0.00e+00 1.273 0.000 302.00 328.00 3 2.8934e+00 1.4529e-03 1.5154e-02 -6.0000e+00 1.0567e-02 2.2908e-02 1.6210e-03 8.2674e-03 -6.0000e+00 1.1457e-02 3.5512e-03 9.2633e-04 4.0417e-03 -6.0000e+00 6.8541e-03 -5.0209e-03 4.1363e-04 1.1197e-03 -6.0000e+00 2.8836e-03 7.0915e-03 1.8992e-04 3.3155e-05 1.5491e-05 -6.0000e+00 2.1036e-04 -1.2157e-02 1.1312e-04 12 1 1 12 1 1 99.78 23.27 0.13 -0.01216 -0.01073 43 43 1 5 0 299.340 26.21 20.00 23.27 32.58 23.0 1033.10 185 -170 -1399 -1732 -3025 -1591 -744 1064 881 63 -264 -416 -657 999 415 670 96 -257 205 196 -249 -19 755 -232 594 249 556 -530 -182 425 706 1873 1552 410 -1574 -1371 -1813 -561 -252 25 -610 -543 -1137 -405 -909 -372 -540 -621 -249 -387 444 676 1052 1017 990 366 922 451 158 397 1192 954 1724 874 946 327 -394 -445 -524 812 295 52 -223 94 -124 150 -177 57 -190 124 -376 -904 -1197 -1426 -1306 -1197 -368 -443 -132 -410 155 -19 249 372 654 812 668 560 252 97 -230 -283 -418 -108 -543 -299 -647 -456 -417 -16 -56 163 90 52 128 -7 388 98 433 221 -39 -402 -256 199 496 455 936 918 924 674 447 425 -78 104 -128 -78 -183 33 -156 -216 -323 -207 -406 -426 46 -46 -388 -457 -722 -346 -163 252 231 18 -73 -115 -192 319 148 259 39 -106 86 84 -110 -8 329 -105 280 114 272 -249 -79 173 287 789 693 191 -721 -597 -823 -284 -141 16 -444 -417 -849 -304 -684 -294 -419 -464 -179 -271 313 500 817 825 829 295 750 370 129 338 1021 808 1553 841 925 305 -337 -378 -447 745 283 54 -236 97 -123 137 -154 45 -147 101 -344 -864 -1238 -1557 -1503 -1393 -452 -570 -173 -531 190 -21 268 369 637 835 753 656 320 127 -292 -335 -491 -125 -661 -368 -843 -618 -587 -23 -81 244 134 73 174 -9 487 124 543 298 -56 -561 -372 280 665 578 1190 1119 1135 872 577 569 -106 145 -185 -112 -277 52 -247 -344 -505 -314 -598 -655 SS 20240925T165730.5Z 9034.706603 433 1 36.88 2 38.26 180.29 64.65 286.39 0.00 1 0.00 1 0 17 1.084e-02 6.771e-03 6.286e-03 3.167e-03 1.624749e-01 1.630625e-03 1.926472e-03 -6.000000e+00 6.333941e-03 228.32 -2.00 3.43 -2.00 316.27 0.00e+00 7.990351e-05 1.849621e-04 3.784306e-05 -6.000000e+00 2.868433e-04 289.07 -2.00 20.00 -2.00 315.45 0.00e+00 1.272 0.000 302.00 328.00 3 5.2113e+00 4.2499e-03 1.5115e-02 -6.0000e+00 1.5710e-02 3.5000e-02 4.7574e-03 8.1944e-03 -6.0000e+00 1.7034e-02 8.3279e-03 2.7229e-03 4.0078e-03 -6.0000e+00 1.0190e-02 -7.3192e-03 1.2353e-03 1.1138e-03 -6.0000e+00 4.2865e-03 6.9543e-04 2.5557e-05 9.7397e-05 1.4577e-05 -6.0000e+00 3.1276e-04 -1.1865e-02 8.8249e-05 12 9 1 12 1 1 99.92 23.27 0.75 -0.01186 -0.01167 17 6 1 5 0 2048.120 26.11 20.00 23.27 32.75 23.5 1036.04 -5589 1265 -2383 -932 -2453 -1387 -2686 852 -305 2075 -773 -3994 -707 -1017 854 -183 1177 1658 1628 -864 64 719 590 -684 819 461 42 -834 -469 241 1282 2803 1746 579 -811 -2152 -282 -368 -642 736 790 -311 -795 -878 -340 77 -1691 -839 -880 -674 1284 339 1037 829 891 787 900 272 300 118 1070 652 1346 1289 1740 -35 -653 -463 -714 757 -47 53 -25 766 -130 182 -119 -325 18 -269 -1499 -871 -1579 -1939 -1077 -1509 -69 58 137 -16 308 -194 375 -634 445 868 1020 786 405 117 567 -869 -1216 -818 -1182 -204 -732 -304 -281 316 -75 153 91 -23 58 -128 -242 -104 417 -533 118 193 486 165 796 798 511 1160 293 1015 108 536 -260 74 13 128 0 659 -483 -36 -327 -355 -710 -706 -1252 287 -572 -209 -498 -258 -515 173 -70 487 -185 -979 -178 -284 260 -61 402 573 578 -322 24 268 221 -268 330 193 18 -338 -175 84 444 1002 666 231 -316 -808 -108 -159 -329 435 518 -217 -574 -642 -246 55 -1209 -573 -579 -432 818 229 733 613 679 611 708 216 235 92 834 535 1175 1193 1630 -31 -540 -357 -553 630 -44 52 -26 760 -124 159 -101 -251 13 -215 -1345 -799 -1574 -2043 -1187 -1790 -86 75 181 -21 382 -222 386 -651 445 915 1095 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