File name: Pandora156s1_HamptonVA-HU_20241010_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20241015T190257.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20241010_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20241010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241010T132303.8Z 9049.557683 96 1 47.39 2 65.68 120.49 147.99 84.49 0.00 1 0.00 1 0 17 4.244e-02 6.567e-03 3.038e-02 4.075e-03 3.098429e-01 2.076293e-03 3.589978e-03 -6.000000e+00 2.467610e-02 226.92 -2.00 3.43 -2.00 319.03 0.00e+00 -6.612479e-04 4.831521e-04 1.004495e-04 -6.000000e+00 1.115314e-03 287.45 -2.00 20.00 -2.00 318.17 0.00e+00 2.411 0.000 302.00 328.00 3 3.8997e+00 5.7774e-03 2.8664e-02 -6.0000e+00 6.1036e-02 7.3578e-03 6.6899e-03 1.5689e-02 -6.0000e+00 6.6255e-02 2.0782e-02 4.5067e-03 7.7006e-03 -6.0000e+00 3.9640e-02 -1.5800e-02 2.3206e-03 2.2193e-03 -6.0000e+00 1.6706e-02 6.6440e-04 -2.6292e-04 1.3072e-04 2.6767e-05 -6.0000e+00 1.2238e-03 -1.6852e-02 3.6247e-05 11 8 0 10 0 0 99.97 23.31 0.80 -0.01685 -0.01883 73 20 1 5 0 649.020 26.21 19.99 23.31 22.02 22.8 955.93 -599 8894 28966 10736 -13786 -15985 -1747 -14592 -7673 1404 3322 4151 -4775 1124 5686 -5698 -5045 -10838 -2750 -5424 -1362 -893 964 10750 11733 -853 -1003 -4169 580 1342 -2963 235 4081 1562 -2114 469 -3295 -3190 -2397 -882 -1101 952 -755 -1290 -1182 629 3114 -337 -2523 -249 576 -778 444 -365 1503 1930 2082 719 98 737 282 805 370 1270 1066 -173 -352 1678 2151 1229 26 369 -294 87 -1017 -713 -1457 367 -56 185 478 -636 -784 -1618 -1844 -1803 89 -360 175 739 983 180 408 362 814 471 787 499 194 83 297 -730 -763 -173 -515 -95 -1828 -529 -246 -159 171 453 410 -434 -122 -343 487 -217 -153 -432 375 -207 -18 501 355 540 409 507 -162 334 370 561 -105 -94 273 331 -205 101 -720 417 -318 -356 -179 39 -23 351 982 424 -635 -710 -74 -744 -413 75 188 239 -332 85 476 -566 -536 -1280 -334 -705 -175 -115 124 1325 1533 -133 -160 -662 83 184 -439 37 673 280 -386 80 -613 -678 -605 -260 -368 335 -281 -493 -452 236 1133 -125 -943 -91 218 -320 194 -170 721 951 1051 372 50 370 144 430 215 792 693 -110 -210 938 1221 777 18 282 -231 67 -751 -481 -894 205 -31 112 327 -492 -664 -1469 -1777 -1861 96 -407 201 834 1051 179 372 331 745 467 810 574 245 108 377 -874 -846 -197 -577 -114 -2349 -704 -343 -235 269 744 677 -696 -181 -476 682 -308 -229 -645 583 -328 -28 803 545 790 571 683 -224 493 585 934 -181 -166 506 607 -395 200 -1462 837 -627 -720 -348 75 SS 20241010T133703.7Z 9049.567404 106 1 47.04 2 63.31 123.30 145.34 86.79 0.00 1 0.00 1 0 17 2.352e-02 5.784e-03 1.996e-02 3.419e-03 2.834558e-01 1.745878e-03 3.318197e-03 -6.000000e+00 1.367826e-02 226.92 -2.00 3.43 -2.00 318.73 0.00e+00 3.996380e-04 3.782593e-04 1.825150e-04 -6.000000e+00 6.180634e-04 287.45 -2.00 20.00 -2.00 317.91 0.00e+00 2.214 0.000 302.00 328.00 3 3.8852e+00 4.7820e-03 2.6318e-02 -6.0000e+00 3.3834e-02 1.3186e-02 5.5011e-03 1.4385e-02 -6.0000e+00 3.6722e-02 1.4305e-02 3.5755e-03 7.0536e-03 -6.0000e+00 2.1971e-02 -1.3354e-02 1.8271e-03 1.9787e-03 -6.0000e+00 9.2623e-03 8.4605e-04 -2.2497e-04 1.0827e-04 2.4454e-05 -6.0000e+00 6.7815e-04 -1.7608e-02 8.7388e-05 10 0 0 10 0 0 99.91 23.28 0.75 -0.01761 -0.01930 82 22 1 5 0 573.490 26.21 20.00 23.28 22.30 22.7 957.72 3555 -11739 -9902 -14867 3634 -914 -1737 1149 -1315 -4672 2912 3613 -696 -2528 2180 4289 1346 2910 -3133 1768 -1731 1293 -2483 -1552 -155 3952 472 269 -3735 -220 -948 1931 1132 906 -648 -3024 -2467 -4136 -1680 -1111 -347 -2723 32 -816 -366 -38 12 -608 -4140 -1800 -283 1060 1437 2116 205 685 2570 1641 410 1118 406 1789 2575 1982 1872 853 821 -264 204 -393 1145 -644 879 -193 -200 -810 -163 -255 -278 -495 -616 -1082 -1099 -256 -677 -1135 -613 259 -548 -1084 62 316 -17 241 514 591 270 696 123 357 79 -526 -336 110 -154 -517 -708 -303 -64 -829 168 50 -70 -35 169 -230 213 148 -46 -22 97 -171 81 167 943 212 470 837 681 682 493 352 -126 -157 136 -82 -105 148 -62 -518 -85 -256 -81 -198 177 -765 -663 -1015 187 -46 -91 65 -85 -337 198 248 -55 -233 222 479 166 369 -441 246 -257 187 -377 -245 -25 656 82 45 -617 -34 -152 326 210 178 -127 -581 -490 -951 -449 -349 -122 -1050 13 -327 -147 -15 5 -238 -1650 -699 -112 442 638 988 102 349 1312 853 213 569 228 1041 1612 1243 1322 589 527 -163 127 -271 866 -532 733 -160 -157 -589 -106 -153 -166 -320 -450 -887 -983 -242 -677 -1222 -699 307 -668 -1312 71 331 -16 216 461 568 288 824 160 480 104 -648 -383 121 -178 -643 -930 -416 -92 -1269 272 85 -119 -57 255 -323 285 198 -65 -33 154 -276 129 256 1379 297 626 1071 888 949 736 553 -204 -262 236 -151 -202 293 -124 -1050 -168 -486 -148 -359 SS 20241010T134640.4Z 9049.574079 111 1 5.28 2 61.73 125.32 143.51 88.28 0.00 1 0.00 1 0 17 1.881e-02 6.699e-03 1.822e-02 4.640e-03 2.754686e-01 2.364541e-03 3.236225e-03 -6.000000e+00 1.093701e-02 226.92 -2.00 3.43 -2.00 317.79 0.00e+00 -6.283648e-04 3.932751e-04 6.776906e-05 -6.000000e+00 4.942759e-04 287.45 -2.00 20.00 -2.00 316.95 0.00e+00 2.101 0.000 302.00 328.00 3 3.6145e+00 6.3000e-03 2.5131e-02 -6.0000e+00 2.7053e-02 3.3158e-02 7.1448e-03 1.3921e-02 -6.0000e+00 2.9364e-02 -1.6570e-03 4.3724e-03 6.8203e-03 -6.0000e+00 1.7569e-02 -3.1832e-03 2.1728e-03 1.9656e-03 -6.0000e+00 7.4054e-03 1.2487e-03 -8.3541e-04 1.4281e-04 2.3884e-05 -6.0000e+00 5.4235e-04 -1.7814e-02 3.6757e-05 12 9 1 12 1 1 99.87 23.28 0.27 -0.01781 -0.02409 5 15 1 5 0 878.720 26.21 20.00 23.28 22.42 22.7 958.67 -2612 -183 -4027 4486 -3445 8647 -2529 -11376 -2302 3707 -3608 -3289 -3792 -174 -2377 1539 827 -1316 -1248 -326 785 2265 -2311 1291 125 2130 -749 -2513 -1315 -1775 1144 6178 2269 1317 -621 -2972 -2777 -1060 -161 490 471 -2113 -30 -465 92 -1478 -386 -1349 -785 -708 75 287 1042 551 563 829 1445 1381 56 1334 128 1416 1996 -26 875 1071 -188 162 -619 1090 267 448 546 -515 467 -265 346 837 -262 -167 -501 -1456 -1129 -1246 -1806 -1014 -717 22 -250 -187 199 -198 297 182 366 1184 709 451 181 405 106 -338 -215 -331 -565 -588 -152 -65 -76 -579 10 -652 434 -166 -1715 367 1272 121 570 -51 54 -217 -427 316 232 347 1188 1059 906 700 -29 686 229 -329 -39 -65 -23 -493 161 293 -114 -424 -220 -628 -216 -16 -392 388 -293 608 -204 -1115 -232 378 -402 -370 -466 -24 -376 261 151 -255 -251 -67 165 471 -508 287 30 524 -193 -634 -306 -398 255 1413 585 362 -170 -798 -773 -329 -59 211 229 -1066 -15 -244 48 -780 -199 -688 -413 -370 40 155 594 334 356 537 952 919 37 863 85 967 1466 -21 726 858 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