File name: Pandora37s1_HamptonVA_20201221_L2Fit_fout2c6d20201125p1-8.txt File generation date: 20250726T001909.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: David Flittner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v2d20200313.txt Instrument calibration file used: Pandora37s1_CF_v6d20201125.txt Level 1 file used: Pandora37s1_HamptonVA_20201221_L1_smca1c6d20201125p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20201221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.0413 305.1818 305.3222 305.4626 305.6030 305.7434 305.8838 306.0242 306.1645 306.3049 306.4452 306.5855 306.7258 306.8661 307.0064 307.1467 307.2870 307.4272 307.5675 307.7077 307.8479 307.9881 308.1283 308.2685 308.4087 308.5488 308.6890 308.8291 308.9692 309.1094 309.2495 309.3896 309.5296 309.6697 309.8098 309.9498 310.0898 310.2298 310.3699 310.5099 310.6498 310.7898 310.9298 311.0697 311.2097 311.3496 311.4895 311.6294 311.7693 311.9092 312.0490 312.1889 312.3287 312.4686 312.6084 312.7482 312.8880 313.0278 313.1676 313.3073 313.4471 313.5868 313.7265 313.8663 314.0060 314.1457 314.2853 314.4250 314.5647 314.7043 314.8439 314.9836 315.1232 315.2628 315.4023 315.5419 315.6815 315.8210 315.9606 316.1001 316.2396 316.3791 316.5186 316.6581 316.7976 316.9370 317.0765 317.2159 317.3553 317.4947 317.6341 317.7735 317.9129 318.0522 318.1916 318.3309 318.4702 318.6096 318.7489 318.8881 319.0274 319.1667 319.3059 319.4452 319.5844 319.7236 319.8628 320.0020 320.1412 320.2804 320.4196 320.5587 320.6978 320.8370 320.9761 321.1152 321.2543 321.3933 321.5324 321.6715 321.8105 321.9495 322.0885 322.2275 322.3665 322.5055 322.6445 322.7834 322.9224 323.0613 323.2002 323.3391 323.4780 323.6169 323.7558 323.8947 324.0335 324.1723 324.3112 324.4500 324.5888 324.7276 324.8663 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201221T191919.5Z 7660.805087 300 1 6.95 2 68.41 213.32 68.33 116.24 0.00 1 0.00 1 0 25 4.088e-02 1.001e-02 3.965e-02 8.360e-03 3.417669e-01 4.183723e-03 4.038688e-03 -6.000000e+00 2.310283e-02 223.65 -2.00 3.43 -2.00 317.86 0.00e+00 5.561735e-04 7.097410e-04 1.059813e-04 -6.000000e+00 1.016663e-03 280.01 -2.00 20.00 -2.00 317.22 0.00e+00 2.693 0.000 302.00 328.00 3 4.5258e+00 1.1068e-02 3.1741e-02 -6.0000e+00 5.6951e-02 6.6735e-02 1.2513e-02 1.7046e-02 -6.0000e+00 6.1792e-02 -1.7582e-02 8.0704e-03 8.4877e-03 -6.0000e+00 3.6857e-02 2.7978e-03 4.2205e-03 2.5859e-03 -6.0000e+00 1.6054e-02 2.5061e-04 1.2302e-03 2.3499e-04 2.7289e-05 -6.0000e+00 1.0848e-03 -1.3377e-02 0.0000e+00 12 9 9 12 1 1 999.00 22.80 0.16 -0.01338 -0.00413 1 9 1 5 0 3390.910 26.11 22.00 22.80 14.44 4.4 1013.33 -2950 -27784 -4863 7442 -9055 -14812 8302 18314 2185 -9994 -6194 8491 5799 -795 5629 -627 -4741 4415 4491 -4255 -3119 -1077 367 3400 2940 -1427 -1815 1662 -1957 -7180 2765 4657 867 203 -7402 -4063 4040 -860 2010 1750 -994 561 147 -1788 -1276 -2034 1119 1929 -1665 -1427 441 -50 2885 216 3037 433 751 -956 1944 70 -305 -605 2467 1588 1291 648 -656 381 2867 908 1284 -810 -619 -1269 -457 1562 1484 -1818 661 100 -903 -2842 -931 -1612 -1654 -900 -1518 -1337 -212 155 361 747 990 679 491 321 1494 1623 -708 -185 818 -586 -192 1057 -548 -1144 -1810 -215 144 504 495 -535 -368 -60 1055 509 -89 -43 -126 -56 -1222 -82 466 889 446 18 -598 1228 1816 861 388 -164 -180 123 -227 -689 -368 630 204 296 -530 -78 -972 -190 -2536 -375 494 -631 -1031 489 1098 171 -937 -564 693 546 -93 719 -95 -800 718 766 -816 -607 -205 70 667 615 -324 -420 359 -411 -1556 582 1059 223 56 -2086 -1066 1044 -263 705 714 -456 267 72 -910 -646 -1041 557 943 -833 -716 227 -27 1646 132 1885 280 494 -640 1254 45 -200 -416 1778 1230 1032 503 -486 273 2072 728 1114 -745 -574 -1159 -397 1247 1096 -1311 474 79 -785 -2714 -933 -1683 -1796 -1020 -1801 -1628 -258 187 416 812 1013 671 497 347 1732 2028 -953 -253 1078 -737 -227 1227 -673 -1479 -2419 -294 203 740 761 -850 -584 -92 1537 709 -121 -60 -181 -84 -1899 -127 705 1315 642 26 -815 1624 2466 1243 588 -257 -286 199 -380 -1200 -655 1129 371 535 -940 -134 -1644 SS 20201221T193749.0Z 7660.817928 313 1 30.04 2 70.54 217.23 65.09 119.65 0.00 1 0.00 1 0 25 3.103e-02 6.113e-03 1.815e-02 2.498e-03 3.748623e-01 1.251205e-03 4.421378e-03 -6.000000e+00 1.753326e-02 223.65 -2.00 3.43 -2.00 318.61 0.00e+00 6.383192e-04 2.627575e-04 1.861930e-04 -6.000000e+00 7.716220e-04 280.01 -2.00 20.00 -2.00 317.97 0.00e+00 2.968 0.000 302.00 328.00 3 3.7851e+00 3.3743e-03 3.4990e-02 -6.0000e+00 4.3221e-02 5.8818e-02 3.8647e-03 1.8868e-02 -6.0000e+00 4.6899e-02 -1.2554e-02 2.7266e-03 9.4135e-03 -6.0000e+00 2.7974e-02 -7.2517e-04 1.4537e-03 2.8982e-03 -6.0000e+00 1.2181e-02 3.8612e-04 4.7783e-04 7.0615e-05 3.0042e-05 -6.0000e+00 8.2352e-04 -1.1614e-02 0.0000e+00 10 0 0 10 0 0 99.98 22.85 0.31 -0.01161 -0.00802 22 22 1 5 0 1365.120 26.21 21.98 22.85 14.70 4.4 1012.29 6524 -21999 545 -16030 -7781 -10933 -5650 -7663 967 864 -1546 -1845 -5721 -763 -6015 -2848 -4794 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515 671 -111 -329 -737 -393 -253 283 -313 -1548 -753 -931 -111 109 232 -48 158 149 391 583 556 598 404 -154 -1482 -585 -621 -132 350 1309 65 1916 1422 644 88 -66 684 200 1066 -705 -348 19 316 -1069 -318 -851 -308 SS 20201221T194746.8Z 7660.824847 316 1 29.55 2 71.77 219.27 63.40 121.58 0.00 1 0.00 1 0 25 3.376e-02 5.856e-03 1.708e-02 2.006e-03 3.995957e-01 1.008660e-03 4.701814e-03 -6.000000e+00 1.907311e-02 223.65 -2.00 3.43 -2.00 318.77 0.00e+00 3.982491e-04 2.240548e-04 2.147192e-04 -6.000000e+00 8.393974e-04 280.01 -2.00 20.00 -2.00 318.14 0.00e+00 3.155 0.000 302.00 328.00 3 3.1878e+00 2.7318e-03 3.7237e-02 -6.0000e+00 4.7017e-02 5.7642e-02 3.1420e-03 2.0121e-02 -6.0000e+00 5.1018e-02 -1.7779e-02 2.2825e-03 1.0054e-02 -6.0000e+00 3.0431e-02 1.3810e-03 1.2202e-03 3.0254e-03 -6.0000e+00 1.3251e-02 5.6865e-04 2.9137e-04 5.6439e-05 3.1832e-05 -6.0000e+00 8.9589e-04 -1.1337e-02 0.0000e+00 10 0 0 10 0 0 99.79 22.86 0.33 -0.01134 -0.00915 32 32 1 5 0 922.980 26.21 22.00 22.86 14.74 4.4 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