File name: Pandora37s1_HamptonVA_20211012_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T124849.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v4d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20211012_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20211012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211012T173315.9Z 7955.731434 293 1 11.60 2 45.81 194.35 97.31 118.08 0.00 1 0.00 1 0 17 1.236e-02 7.990e-03 4.776e-03 3.221e-03 1.744818e-01 1.641438e-03 2.120829e-03 -6.000000e+00 7.003970e-03 226.81 -2.00 3.43 -2.00 315.00 0.00e+00 3.034361e-04 1.437656e-04 2.557268e-05 -6.000000e+00 3.162324e-04 287.35 -2.00 20.00 -2.00 314.34 0.00e+00 1.433 0.000 302.00 328.00 3 5.3193e+00 4.1973e-03 1.6790e-02 -6.0000e+00 1.7340e-02 3.3649e-02 4.6668e-03 8.8299e-03 -6.0000e+00 1.8818e-02 -2.9006e-03 2.6763e-03 4.3384e-03 -6.0000e+00 1.1246e-02 -6.9506e-04 1.1995e-03 1.2404e-03 -6.0000e+00 4.8409e-03 5.2284e-04 -2.9192e-04 8.9826e-05 1.6188e-05 -6.0000e+00 3.2966e-04 -1.6629e-02 0.0000e+00 12 9 1 12 41 1 99.95 22.02 0.28 -0.01663 -0.01882 3 3 1 5 0 2856.240 25.39 20.00 22.02 28.88 51.90 16.9 1019.34 -4213 -4539 -1538 -2204 -2203 6032 1466 787 1346 -647 1083 1181 1628 1379 454 -493 2620 1751 600 662 -708 946 2424 154 -40 1127 -1629 213 -1307 1298 422 2992 291 -1447 -2138 -598 -2184 530 -272 -1307 -1283 -1813 -723 -1650 38 -1570 -38 -158 -502 360 323 1050 425 588 961 1015 1259 478 136 916 1325 1684 1072 78 -174 149 741 -437 1903 -50 -583 -106 -585 35 -214 467 -69 1303 325 -138 -1347 -1666 -1880 -1193 -232 -555 -898 -538 143 -308 -239 340 908 1261 654 464 1041 8 -704 -788 646 14 86 1104 -1187 -205 -788 -566 457 442 -76 -129 -40 326 52 422 1289 322 261 -719 -889 -365 479 -105 190 142 568 1701 -143 -257 325 -20 564 -86 37 -90 -88 505 -753 -268 -140 -273 -133 -1438 -1620 -532 -708 -642 1607 430 255 465 -231 371 413 613 569 204 -234 1233 844 298 335 -364 477 1227 82 -22 626 -909 111 -652 625 211 1532 159 -799 -1120 -308 -1219 323 -189 -998 -1026 -1487 -597 -1373 31 -1296 -30 -123 -386 274 254 852 356 507 837 892 1116 424 119 800 1179 1561 1044 79 -174 139 656 -382 1701 -49 -602 -112 -619 37 -212 432 -60 1076 276 -126 -1324 -1734 -2030 -1316 -265 -663 -1109 -676 179 -380 -281 377 945 1272 679 509 1205 10 -901 -999 784 16 97 1261 -1446 -257 -1015 -746 612 611 -109 -185 -56 434 66 512 1545 397 335 -972 -1226 -500 646 -139 244 176 682 2015 -176 -328 425 -27 750 -117 52 -130 -129 750 -1135 -399 -205 -393 -189 SS 20211012T181351.7Z 7955.759626 312 1 26.34 2 48.72 207.48 90.64 123.74 0.00 1 0.00 1 0 25 8.616e-03 6.757e-03 1.760e-03 1.180e-03 1.833042e-01 6.014176e-04 2.228502e-03 -6.000000e+00 4.882216e-03 226.80 -2.00 3.43 -2.00 315.04 0.00e+00 1.587188e-04 5.307596e-05 2.639193e-05 -6.000000e+00 2.204113e-04 287.35 -2.00 20.00 -2.00 314.38 0.00e+00 1.513 0.000 302.00 328.00 3 4.3585e+00 1.5380e-03 1.7704e-02 -6.0000e+00 1.2087e-02 2.3048e-02 1.7105e-03 9.2686e-03 -6.0000e+00 1.3117e-02 -3.2539e-03 9.8138e-04 4.5576e-03 -6.0000e+00 7.8387e-03 -1.2039e-03 4.4050e-04 1.2885e-03 -6.0000e+00 3.3747e-03 1.2476e-03 -3.8130e-04 3.2878e-05 1.6937e-05 -6.0000e+00 2.2976e-04 -1.7309e-02 0.0000e+00 12 9 1 12 1 1 99.91 22.14 0.27 -0.01731 -0.02017 24 10 1 5 0 1046.310 25.47 19.99 22.14 28.51 51.90 17.0 1018.30 -1011 -1972 -1997 -2455 -1056 1833 1140 948 446 -753 -691 1029 86 456 458 -1263 1071 380 349 359 -409 1017 2035 528 -26 478 -781 -580 -261 2166 1518 2343 299 -1747 -840 320 -361 8 62 -868 -1394 -913 -813 -923 -473 -1478 -416 -749 -505 530 911 402 705 871 732 764 549 341 985 1039 1440 1256 774 516 -960 -164 721 497 1275 -212 -251 -130 -193 -516 -521 277 652 981 620 -573 -836 -1256 -1952 -765 -799 -765 -866 -328 -110 -417 16 425 800 1440 561 476 671 192 -596 -732 146 115 257 610 -810 -686 -600 -374 30 205 -64 -239 -106 357 225 800 688 400 325 -433 -893 -322 92 -9 461 424 1163 1776 385 -126 90 274 376 242 -110 -253 -251 183 -373 -564 -284 -260 -192 -330 -677 -682 -780 -302 502 333 303 154 -267 -239 358 33 188 204 -596 504 183 172 180 -208 507 1024 278 -14 264 -430 -303 -129 1038 753 1206 163 -967 -438 164 -199 5 42 -654 -1103 -736 -663 -755 -384 -1205 -331 -584 -385 401 709 326 587 744 635 669 485 301 857 902 1272 1159 748 515 -956 -153 638 431 1144 -207 -257 -136 -203 -532 -516 256 565 817 528 -525 -820 -1302 -2104 -840 -912 -910 -1063 -410 -138 -511 18 470 835 1457 585 523 778 236 -761 -927 178 134 290 701 -985 -861 -771 -491 40 283 -91 -341 -148 477 286 974 833 497 420 -585 -1233 -443 124 -12 592 529 1403 2119 477 -162 119 366 505 330 -155 -369 -370 273 -564 -845 -417 -376 -273 SS 20211012T181921.8Z 7955.763447 315 1 5.19 2 49.24 209.15 89.77 124.54 0.00 1 0.00 1 0 25 1.086e-02 7.996e-03 6.438e-03 4.185e-03 1.856551e-01 2.129231e-03 2.280430e-03 -6.000000e+00 6.152667e-03 226.80 -2.00 3.43 -2.00 315.18 0.00e+00 6.467398e-04 1.932201e-04 7.239085e-05 -6.000000e+00 2.777874e-04 287.35 -2.00 20.00 -2.00 314.51 0.00e+00 1.529 0.000 302.00 328.00 3 4.8116e+00 5.4534e-03 1.7935e-02 -6.0000e+00 1.5233e-02 3.3276e-02 6.0692e-03 9.4945e-03 -6.0000e+00 1.6530e-02 -3.0929e-03 3.4810e-03 4.6548e-03 -6.0000e+00 9.8787e-03 -3.1843e-03 1.5700e-03 1.4145e-03 -6.0000e+00 4.2526e-03 7.7263e-04 -5.8971e-04 1.1678e-04 1.7909e-05 -6.0000e+00 2.8958e-04 -1.6809e-02 0.0000e+00 12 9 1 12 1 1 999.00 22.13 0.52 -0.01681 -0.02124 2 6 1 5 0 1670.560 25.47 20.00 22.13 28.66 50.40 17.0 1019.68 -1277 -3630 -1891 -3095 -634 2510 -678 -405 1085 -430 1018 187 1876 -481 3268 -2218 1308 1948 1379 -1054 -765 1388 1804 156 -223 1705 -1083 317 -1148 1665 1874 1817 -218 -2246 -53 895 403 -748 104 -1241 -1258 -749 -1402 -1480 -249 -1759 -233 -475 -626 361 -19 1540 402 1402 793 775 294 316 -578 1509 2050 1385 1171 620 -414 -746 1007 -630 1299 -393 76 300 -175 -668 -299 228 -121 979 298 -17 -1070 -969 -2080 -828 -1094 -635 -545 -486 219 -516 178 378 968 1907 1341 413 896 -87 -76 -895 356 -274 -245 511 -840 -853 -1044 113 -7 318 -325 -285 -194 529 -223 1191 1274 -23 -633 -589 -1068 -2 270 54 805 -87 1436 1012 214 395 1089 245 132 202 -292 -160 -190 162 28 -867 50 -201 -669 -396 -1201 -614 -940 -171 646 -190 -124 353 -144 329 62 667 -191 1372 -1019 595 899 653 -519 -378 670 881 80 -118 907 -580 160 -553 776 901 914 -116 -1219 -27 446 216 -449 70 -923 -981 -596 -1136 -1203 -200 -1424 -184 -366 -474 271 -15 1229 333 1185 683 674 259 277 -504 1297 1793 1270 1126 617 -410 -700 886 -548 1159 -383 78 314 -183 -688 -295 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