File name: Pandora37s1_HamptonVA_20220118_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T133645.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v5d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20220118_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20220118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220118T125105.9Z 8053.535485 277 1 50.68 2 84.83 120.59 88.82 298.30 0.00 1 0.00 1 0 25 6.886e-01 5.385e-02 3.206e-01 2.014e-02 1.083085e+00 1.290915e-02 1.252499e-02 -6.000000e+00 4.234127e-01 224.22 -2.00 3.43 -2.00 322.40 0.00e+00 1.761711e-02 6.290051e-03 3.167654e-03 -6.000000e+00 2.487261e-02 278.69 -2.00 20.00 -2.00 322.00 0.00e+00 9.583 0.015 302.00 328.00 3 4.0499e-05 4.8323e-02 1.1062e-01 -6.0000e+00 1.0692e+00 2.4200e+00 5.5067e-02 5.8088e-02 -6.0000e+00 1.1883e+00 -2.6269e+00 3.0545e-02 2.5928e-02 -6.0000e+00 6.6777e-01 9.3560e-01 1.7765e-02 1.4719e-02 -6.0000e+00 2.8649e-01 8.9200e-06 7.0072e-04 5.5793e-04 2.9917e-04 -6.0000e+00 2.3223e-02 8.3252e-03 0.0000e+00 12 8 8 10 0 0 13.68 19.63 1.51 0.00833 0.01359 27 5 1 5 0 1876.680 23.72 20.00 19.63 6.78 17.6 1020.38 900000 -16240 900000 900000 900000 900000 900000 900000 900000 900000 -46582 900000 900000 900000 900000 900000 64917 900000 161599 289399 900000 900000 900000 90041 47083 900000 169772 900000 900000 900000 900000 27250 900000 900000 900000 900000 900000 900000 900000 900000 165034 900000 -30849 8701 -17328 96741 178165 38247 900000 234622 109364 74522 32470 900000 84738 157381 -14726 126445 -41696 59734 -12688 164214 19747 153611 147329 89655 22548 63570 900000 32575 28027 76460 45118 58532 69484 -1277 -21986 900000 24481 -23608 28011 1312 -1670 17016 31085 7015 1843 -14109 -7329 56780 -1502 -27978 8055 75655 -19149 21147 2732 -7123 -9156 7526 -4698 -10415 -4515 -6064 17934 -2327 -13985 -6055 1852 13293 -10426 -5453 1628 2136 1534 1133 6897 -550 1041 2109 -2539 -275 1644 4926 72 -4896 8140 7463 4759 797 2054 -1350 1359 -1868 -2221 -1040 634 529 -1957 5015 3699 -3812 -3338 900000 -3575 900000 900000 900000 900000 900000 900000 900000 900000 -3779 900000 900000 900000 900000 900000 4740 900000 4195 5634 900000 900000 900000 2630 1910 900000 3305 900000 900000 900000 900000 1813 900000 900000 900000 900000 900000 900000 900000 900000 3213 900000 -3854 770 -1771 3425 3469 2572 900000 4568 4452 4617 3218 900000 5099 4457 -2031 4252 -6291 3383 -1527 3778 2237 5166 5476 5871 2953 5851 900000 5074 4762 7849 5829 5802 5288 -174 -3619 900000 3423 -6013 5503 353 -501 4417 7978 2174 616 -5540 -2616 10954 -441 -10259 2295 12319 -8885 7994 1494 -5051 -7235 4982 -3216 -6539 -2366 -3217 7973 -1333 -9643 -4283 1406 10698 -12348 -6733 1939 2520 1772 1295 7677 -697 1364 2755 -3299 -326 1833 5179 78 -5418 7884 8124 6447 1234 3589 -2694 2863 -4409 -5669 -2739 1661 1399 -5217 11694 7972 -8089 -6759 SS 20220118T130336.2Z 8053.544169 280 1 49.43 2 82.70 122.62 90.94 300.08 0.00 1 0.00 1 0 25 7.616e-01 1.640e-02 3.046e-01 4.321e-03 9.670823e-01 2.499768e-03 1.029009e-02 -6.000000e+00 4.388738e-01 224.22 -2.00 3.43 -2.00 322.03 0.00e+00 1.296641e-02 1.447180e-03 1.951962e-03 -6.000000e+00 2.303637e-02 278.69 -2.00 20.00 -2.00 321.59 0.00e+00 7.272 0.006 302.00 328.00 3 4.1704e-01 9.5380e-03 9.1819e-02 -6.0000e+00 1.0816e+00 5.7125e-01 1.5491e-02 6.5810e-02 -6.0000e+00 1.1826e+00 -6.8184e-01 1.7491e-02 3.0636e-02 -6.0000e+00 6.9632e-01 2.6325e-01 7.8221e-03 1.7783e-02 -6.0000e+00 2.9686e-01 9.3870e-05 -5.3326e-04 1.1162e-04 2.0102e-04 -6.0000e+00 2.1629e-02 8.1726e-03 0.0000e+00 12 8 8 10 0 0 5.64 19.67 0.50 0.00817 0.00417 109 22 1 5 0 453.360 23.83 20.01 19.67 7.69 17.6 1020.44 -273594 -358660 -109866 900000 900000 900000 900000 -189043 -175957 900000 -315351 900000 900000 -175586 900000 900000 -35980 13936 -52568 140853 900000 900000 -76962 88668 -114556 900000 -15877 900000 -29007 -2145 11849 -47418 44242 32283 47838 316093 188439 124646 271681 27650 23838 70288 -23058 -17178 -7954 2603 29028 25338 5514 35328 12980 28338 20803 40605 16834 23063 -2359 16654 -6636 6350 9060 15965 4891 17525 18864 5978 9012 4544 22168 9966 4315 8443 3213 6753 2198 -4218 -4691 13382 1157 -2556 211 595 -1989 -272 2588 -184 214 -437 721 3965 127 -3763 503 2034 -3360 -561 -458 -931 -2324 -194 -467 -934 -720 -1712 -1835 -1567 -2635 -2203 -1318 -50 -1576 -679 437 -342 412 625 1030 327 394 -136 -390 575 1284 1425 632 -501 2054 2638 302 387 655 198 446 -45 -452 -435 62 -60 -545 250 613 -803 -764 -2875 -9393 -462 900000 900000 900000 900000 -927 -801 900000 -6628 900000 900000 -2460 900000 900000 -239 63 -497 592 900000 900000 -944 373 -2207 900000 -127 900000 -264 -20 120 -1096 480 407 530 1329 792 857 1142 649 643 1280 -1131 -818 -357 110 1007 994 290 1547 818 1737 1406 2455 1355 1797 -239 1352 -650 540 797 1507 614 2255 2562 934 1419 750 3508 2050 1016 1942 745 1377 416 -765 -839 2367 260 -738 71 216 -815 -116 1140 -88 106 -222 357 1812 56 -1660 215 943 -1952 -383 -350 -839 -2329 -190 -423 -746 -547 -1311 -1410 -1266 -2293 -2097 -1420 -59 -2150 -998 652 -507 585 864 1448 487 617 -217 -600 822 1745 1876 813 -633 2646 3458 481 682 1299 409 984 -108 -1108 -1117 162 -156 -1416 609 1441 -1762 -1606 SS 20220118T131536.6Z 8053.552507 283 1 49.06 2 80.71 124.62 92.94 301.84 0.00 1 0.00 1 0 25 5.871e-01 1.017e-02 7.467e-02 1.722e-03 8.138030e-01 9.181053e-04 8.825353e-03 -6.000000e+00 3.283882e-01 224.22 -2.00 3.43 -2.00 321.32 0.00e+00 5.535967e-03 4.488690e-04 1.036537e-03 -6.000000e+00 1.484690e-02 278.69 -2.00 20.00 -2.00 320.83 0.00e+00 5.889 0.003 302.00 328.00 3 3.7959e-01 3.0817e-03 7.1976e-02 -6.0000e+00 8.1058e-01 2.3806e-01 4.4569e-03 4.3034e-02 -6.0000e+00 8.8371e-01 -2.6805e-01 4.8473e-03 2.4484e-02 -6.0000e+00 5.2644e-01 9.9224e-02 2.2894e-03 1.0822e-02 -6.0000e+00 2.2548e-01 4.4157e-04 -2.6229e-04 4.3590e-05 1.1580e-04 -6.0000e+00 1.5670e-02 7.3887e-03 0.0000e+00 12 8 8 10 0 0 -5.87 19.71 0.42 0.00739 0.00542 254 51 1 5 0 193.120 23.83 20.01 19.71 8.71 17.6 1020.35 -191153 -270715 -167874 -199728 -178888 -184816 -161378 -141551 -185103 -124150 -240299 900000 -137571 -105222 -99991 -38820 -79864 -37049 -45689 -44136 6938 -36009 -35703 -36796 -42344 -36093 -40200 -51199 -19114 -26708 -11149 -23614 -5847 -5200 -14937 6932 2003 6985 2080 8863 -1845 6523 -4660 1523 1893 5153 10522 1527 8141 7020 8316 6055 6986 6681 7112 5486 1386 4777 -715 4416 3614 5777 4840 6822 4452 3680 2635 2966 3917 2427 1534 1273 1725 443 938 -1338 -2343 203 422 -1583 -652 -1499 -1646 -443 -1045 -669 -824 -583 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