File name: Pandora37s1_HamptonVA_20220419_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T142628.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v5d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20220419_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20220419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220419T105820.5Z 8144.457182 219 1 51.17 2 84.49 80.05 78.34 228.85 0.00 1 0.00 1 0 17 7.558e-01 8.514e-02 2.922e-01 2.377e-02 1.024994e+00 1.350274e-02 1.098233e-02 -6.000000e+00 4.420074e-01 229.33 -2.00 3.43 -2.00 321.64 0.00e+00 -2.003053e-06 4.485906e-03 4.753727e-03 -6.000000e+00 2.032521e-02 283.34 -2.00 20.00 -2.00 321.01 0.00e+00 9.131 0.013 302.00 328.00 3 3.8474e-01 4.3596e-02 1.0950e-01 -6.0000e+00 1.1132e+00 2.4452e+00 5.0331e-02 6.4755e-02 -6.0000e+00 1.2161e+00 -2.1885e+00 2.8636e-02 2.4746e-02 -6.0000e+00 7.0965e-01 6.8573e-01 1.5765e-02 1.0496e-02 -6.0000e+00 2.9886e-01 8.4232e-06 2.0521e-03 5.9273e-04 8.9735e-05 -6.0000e+00 2.2422e-02 1.7812e-02 0.0000e+00 12 9 8 11 32 0 78.69 20.57 0.64 0.01781 0.03323 16 3 1 5 0 3197.800 24.46 20.01 20.57 12.65 19.0 1016.47 66678 307287 -40081 165183 37353 282784 900000 33838 900000 -19138 148748 900000 146178 -3925 112006 17145 11669 900000 -8544 75905 900000 900000 84420 9202 66125 119157 -63089 317276 96355 -217 58879 31589 23561 137856 900000 900000 900000 900000 900000 65836 91362 332940 24413 9040 29619 -31582 190775 13092 133292 68536 50542 16252 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-1789 -3795 3357 6561 8460 -9569 1031 10333 -3389 17921 8972 -2503 7090 10432 -4172 -8659 -4226 5891 2040 7603 -14290 -5765 -145 12163 -6818 27 663 -1808 3943 -552 15540 -15394 -1248 2874 -5764 -5280 5770 2775 -4215 -8952 4738 11442 1248 -8000 4286 2992 5988 -8771 -4927 -9479 5048 10102 -8846 17257 2235 -3845 -4876 SS 20220419T111125.2Z 8144.466263 222 1 49.70 2 81.92 81.97 80.29 231.06 0.00 1 0.00 1 0 25 6.027e-01 1.848e-02 2.100e-01 4.064e-03 8.761306e-01 2.257905e-03 9.577082e-03 -6.000000e+00 3.466460e-01 229.33 -2.00 3.43 -2.00 321.76 0.00e+00 5.232740e-03 1.263569e-03 3.515798e-03 -6.000000e+00 1.609493e-02 283.34 -2.00 20.00 -2.00 321.24 0.00e+00 6.656 0.005 302.00 328.00 3 9.6695e-01 8.4451e-03 8.2204e-02 -6.0000e+00 8.6640e-01 4.7973e-01 1.2339e-02 4.9720e-02 -6.0000e+00 9.4222e-01 -5.9139e-01 1.2543e-02 2.7606e-02 -6.0000e+00 5.5665e-01 2.3355e-01 5.7068e-03 9.6021e-03 -6.0000e+00 2.3557e-01 1.0515e-04 -1.9225e-04 1.0378e-04 1.5004e-04 -6.0000e+00 1.6233e-02 1.6637e-02 0.0000e+00 12 8 8 10 0 0 20.41 20.61 0.49 0.01664 0.01519 86 17 1 5 0 577.850 24.56 20.00 20.61 13.26 19.0 1016.49 -238076 -290119 -186640 34395 -230370 900000 -93522 -126574 900000 -196247 -247122 900000 -50267 -175350 900000 -142157 -33884 118008 -29267 -62433 900000 -381 2765 10645 -36386 -15524 -88497 -6545 -88847 31645 -41382 9591 -8818 23462 5446 28888 85904 70140 54459 15663 10034 22662 15190 3861 17652 -3010 10379 -2931 27128 34609 12966 17753 10867 36231 15828 19170 -2050 13778 -8236 9869 6462 13147 11745 9349 21463 8476 13482 53441 22191 3106 5890 9392 2043 3007 -416 338 -8436 6331 -1896 -473 -2718 145 -4085 1289 -1181 -1219 -2454 -2000 -291 1195 2055 -2156 -418 -313 -2367 -814 -557 -1761 -1191 -369 -1148 -1734 -1228 -1021 -2255 -106 -3017 -269 -636 46 -1146 -153 -359 32 940 1025 1724 -534 45 309 248 510 795 731 1189 -224 2323 2195 382 -176 393 465 292 -54 -373 -425 39 390 -703 -73 -45 -117 -797 -3456 -7945 -2015 136 -3234 900000 -370 -775 900000 -2755 -5789 900000 -308 -4571 900000 -4034 -402 467 -390 -1191 900000 -4 29 111 -642 -229 -2453 -85 -2521 353 -1221 207 -263 515 135 582 1113 1288 1431 651 487 1032 777 224 909 -197 620 -214 1584 2090 1112 1634 1092 3335 1740 2119 -284 1586 -1131 1115 799 1730 1832 1700 3615 1619 2521 7211 4691 848 1689 2651 596 797 -109 80 -2117 1485 -535 -160 -1115 66 -2135 678 -634 -692 -1471 -1213 -171 706 1123 -1172 -224 -183 -1544 -622 -501 -1743 -1268 -384 -1114 -1595 -1023 -864 -2075 -101 -2942 -278 -748 62 -1662 -236 -561 48 1357 1442 2460 -820 73 506 393 762 1139 1078 1687 -312 3098 3176 618 -313 774 989 630 -125 -934 -1059 99 988 -1782 -184 -105 -266 -1762 SS 20220419T112646.6Z 8144.476929 227 1 49.09 2 78.87 84.22 82.66 233.55 0.00 1 0.00 1 0 25 3.741e-01 7.469e-03 4.078e-02 1.259e-03 7.014855e-01 6.627973e-04 7.678427e-03 -6.000000e+00 2.130532e-01 229.33 -2.00 3.43 -2.00 320.73 0.00e+00 2.212684e-03 2.800660e-04 6.461872e-04 -6.000000e+00 9.406234e-03 283.34 -2.00 20.00 -2.00 320.13 0.00e+00 5.000 0.002 302.00 328.00 3 7.8593e-01 2.0916e-03 6.1806e-02 -6.0000e+00 5.3128e-01 1.3203e-01 2.7617e-03 3.6463e-02 -6.0000e+00 5.7680e-01 -1.1935e-01 2.7182e-03 1.8852e-02 -6.0000e+00 3.4318e-01 3.5989e-02 1.3318e-03 6.5252e-03 -6.0000e+00 1.4558e-01 7.5121e-04 6.1018e-05 3.2904e-05 7.0145e-05 -6.0000e+00 9.9970e-03 1.6258e-02 0.0000e+00 11 8 0 10 0 0 30.42 20.69 0.31 0.01626 0.01672 260 52 1 5 0 188.770 24.56 20.00 20.69 14.00 19.0 1016.47 -135811 -165468 -106832 -116431 -116341 -119508 -121534 -132891 -105063 -101350 -131278 -25598 -67828 -61861 -45503 -41157 -38466 -23344 -30803 -21201 -6192 -26477 -19589 -25424 -10635 -23014 -24865 -23635 -13205 -18021 -8214 -3423 -6018 -3832 -3897 -134 -408 4537 2300 2917 -284 2029 -248 1862 564 61 1888 840 1953 5255 4352 3035 3380 4014 2846 2188 6 991 530 1956 2129 3201 3183 2180 2094 2308 1975 273 2907 569 811 697 76 140 -161 -639 -1355 -84 -990 -1225 -977 -1238 -2175 -1106 -765 -770 -818 -260 202 467 837 309 520 639 -148 159 459 -97 -558 -674 -144 149 158 -383 -1239 -913 -604 54 -49 18 -264 -15 33 283 630 985 762 358 -250 -568 -398 357 320 -304 191 -170 1129 1381 171 -132 127 271 183 1 -351 -366 -7 141 -487 -309 40 161 59 -1367 -2309 -944 -1058 -1000 -1115 -1313 -1860 -1251 -1244 -2154 -198 -954 -1063 -833 -850 -872 -506 -774 -509 -129 -692 -520 -792 -309 -794 -871 -794 -411 -682 -347 -151 -312 -198 -193 -7 -23 304 195 267 -30 222 -29 217 68 8 238 113 275 787 746 590 669 858 650 526 1 242 126 456 525 880 1005 776 766 822 712 106 1168 269 414 365 39 67 -69 -267 -547 -35 -454 -672 -585 -845 -1624 -867 -602 -643 -715 -231 176 386 681 238 391 510 -128 151 504 -116 -716 -850 -166 162 159 -399 -1401 -1083 -716 68 -65 27 -419 -25 55 449 943 1490 1175 554 -412 -967 -663 564 488 -472 284 -244 1556 2018 274 -229 231 523 372 3 -754 -823 -15 326 -1127 -679 87 323 120 SS 20220419T113302.7Z 8144.481281 230 1 48.84 2 77.63 85.14 83.64 234.55 0.00 1 0.00 1 0 25 2.701e-01 6.813e-03 2.290e-02 9.279e-04 6.433433e-01 4.817180e-04 7.106681e-03 -6.000000e+00 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