File name: Pandora37s1_HamptonVA_20220422_L2Fit_fwvt1c5d20210730p1-8.txt File generation date: 20250725T142236.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v5d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20220422_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20220422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1680 1830 Nominal wavelengths inside fitting window [nm]: 492.0891 492.2093 492.3295 492.4497 492.5698 492.6900 492.8101 492.9302 493.0503 493.1704 493.2905 493.4105 493.5306 493.6506 493.7706 493.8906 494.0105 494.1305 494.2504 494.3703 494.4902 494.6101 494.7300 494.8498 494.9697 495.0895 495.2093 495.3291 495.4488 495.5686 495.6883 495.8080 495.9277 496.0474 496.1671 496.2867 496.4064 496.5260 496.6456 496.7651 496.8847 497.0043 497.1238 497.2433 497.3628 497.4823 497.6017 497.7212 497.8406 497.9600 498.0794 498.1988 498.3181 498.4375 498.5568 498.6761 498.7954 498.9147 499.0339 499.1532 499.2724 499.3916 499.5108 499.6300 499.7491 499.8682 499.9874 500.1065 500.2256 500.3446 500.4637 500.5827 500.7017 500.8207 500.9397 501.0587 501.1776 501.2965 501.4155 501.5344 501.6532 501.7721 501.8909 502.0098 502.1286 502.2474 502.3661 502.4849 502.6036 502.7224 502.8411 502.9598 503.0784 503.1971 503.3157 503.4343 503.5529 503.6715 503.7901 503.9087 504.0272 504.1457 504.2642 504.3827 504.5011 504.6196 504.7380 504.8564 504.9748 505.0932 505.2116 505.3299 505.4482 505.5665 505.6848 505.8031 505.9213 506.0396 506.1578 506.2760 506.3942 506.5123 506.6305 506.7486 506.8667 506.9848 507.1029 507.2210 507.3390 507.4570 507.5750 507.6930 507.8110 507.9289 508.0469 508.1648 508.2827 508.4006 508.5184 508.6363 508.7541 508.8719 508.9897 509.1075 509.2252 509.3430 509.4607 509.5784 509.6961 509.8138 509.9314 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220422T110546.6Z 8147.462345 199 1 13.50 2 82.30 80.40 65.08 189.60 0.00 1 0.00 1 0 22 2.359e-03 2.363e-03 5.526e-04 5.520e-04 7.554508e+03 3.705755e+01 4.969688e+02 -6.000000e+00 1.335883e+02 283.64 -2.00 20.00 -2.00 505.29 0.00e+00 1.104715e-03 1.536187e-05 7.163416e-05 -6.000000e+00 6.662058e-05 283.64 -2.00 20.00 -2.00 500.53 0.00e+00 5.995569e-01 1.099597e-02 5.607810e-02 -6.000000e+00 4.723173e-02 229.56 -2.00 3.43 -2.00 502.11 0.00e+00 6.943 0.005 489.00 513.00 1 4.4825e+00 8.4318e-04 1.1189e-02 -6.0000e+00 3.6234e-03 -7.7353e-03 2.1479e-04 1.4057e-03 -6.0000e+00 9.3848e-04 7.6318e-03 -1.1762e-04 5.6109e-05 5.7418e-05 -6.0000e+00 2.5427e-04 8.2040e-03 -1.9091e-04 12 1 1 12 1 1 87.80 21.83 1.70 0.00820 0.00739 22 17 1 4 0 578.980 25.47 19.98 21.83 20.98 19.6 1031.10 -230 -380 -301 -88 -67 217 337 236 273 260 157 -118 -211 -134 9 137 31 118 265 112 299 418 375 430 321 410 5 94 -278 -320 -91 -228 -491 -218 -138 -328 -180 -39 51 -63 -67 -21 5 168 201 126 242 40 177 -97 -371 -123 -238 -175 -166 -151 -159 12 214 267 273 298 285 213 169 79 135 -38 -126 -305 -240 -56 -149 -278 -242 -293 -227 -271 -104 -213 -348 -204 -420 -342 -174 -194 -330 -210 -57 -29 81 105 57 13 -162 0 163 -160 -297 -192 -263 -101 -229 -395 -298 -392 -298 36 -100 143 151 24 50 344 435 630 495 464 352 168 119 215 170 334 424 158 149 323 195 65 180 -93 -163 51 -8 -126 178 133 -90 -22 219 -42 87 177 48 -140 -185 -330 -356 -205 -169 -221 -371 -298 -87 -68 223 347 243 280 268 160 -120 -212 -135 9 138 31 120 271 115 308 431 388 446 335 428 5 97 -284 -323 -90 -226 -491 -221 -141 -342 -187 -40 52 -64 -68 -22 5 174 207 131 250 41 180 -98 -371 -121 -232 -171 -163 -151 -161 12 217 271 277 304 292 218 172 80 136 -37 -126 -300 -234 -55 -146 -276 -239 -290 -225 -264 -102 -206 -337 -198 -408 -335 -172 -192 -327 -208 -56 -29 80 104 57 12 -162 0 158 -152 -280 -180 -245 -95 -217 -380 -294 -389 -297 36 -98 141 148 24 50 345 439 631 500 472 356 171 120 215 167 328 417 156 148 320 193 64 178 -91 -160 49 -8 -122 173 131 -90 -21 220 -43 88 180 48 -141 -188 -330 -353 -203 -167 SQ 20220422T111852.6Z 8147.471442 201 1 25.10 2 79.72 82.31 65.56 192.68 0.00 1 0.00 1 0 15 1.900e-03 1.906e-03 3.339e-04 3.335e-04 5.980198e+03 2.186961e+01 3.954861e+02 -6.000000e+00 1.075974e+02 283.64 -2.00 20.00 -2.00 505.28 0.00e+00 9.104287e-04 9.256071e-06 5.952245e-05 -6.000000e+00 5.365511e-05 283.64 -2.00 20.00 -2.00 500.48 0.00e+00 4.611977e-01 6.653346e-03 4.541463e-02 -6.000000e+00 3.803571e-02 229.56 -2.00 3.43 -2.00 502.06 0.00e+00 5.373 0.003 489.00 513.00 1 4.3780e+00 5.1009e-04 8.7278e-03 -6.0000e+00 2.9180e-03 -2.1664e-03 1.3058e-04 1.1215e-03 -6.0000e+00 7.5564e-04 1.0776e-02 -5.0364e-04 3.4189e-05 4.6973e-05 -6.0000e+00 2.0478e-04 9.9585e-03 -1.9110e-04 12 1 1 12 1 1 99.85 21.86 1.74 0.00996 0.00647 74 30 1 4 0 332.380 25.47 19.97 21.86 21.64 19.6 1032.21 -117 -283 -171 0 -78 141 268 134 173 155 125 85 -129 -93 119 213 3 148 227 92 229 430 312 332 340 237 -26 91 -134 -314 71 2 -434 -212 -220 -411 -221 -11 0 -121 -73 -112 -87 34 73 85 140 48 59 -22 -206 -51 -54 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-183 -80 SQ 20220422T112405.9Z 8147.475068 204 1 8.21 2 78.68 83.07 65.78 193.89 0.00 1 0.00 1 0 15 2.060e-03 2.065e-03 1.161e-04 1.160e-04 5.403973e+03 7.513466e+00 3.580729e+02 -6.000000e+00 1.166355e+02 283.64 -2.00 20.00 -2.00 505.29 0.00e+00 8.951949e-04 3.219949e-06 5.661122e-05 -6.000000e+00 5.817036e-05 283.64 -2.00 20.00 -2.00 500.54 0.00e+00 4.028820e-01 2.306158e-03 4.203632e-02 -6.000000e+00 4.125089e-02 229.56 -2.00 3.43 -2.00 502.12 0.00e+00 4.923 0.002 489.00 513.00 1 1.2045e+00 1.7678e-04 8.0163e-03 -6.0000e+00 3.1644e-03 -1.8819e-02 4.5226e-05 1.0318e-03 -6.0000e+00 8.2000e-04 2.7617e-01 3.6731e-04 1.1952e-05 4.3072e-05 -6.0000e+00 2.2202e-04 1.4592e-02 -2.5841e-04 10 0 0 10 0 0 16.33 21.88 1.86 0.01459 0.01714 538 108 1 4 0 14.640 25.47 20.00 21.88 22.05 19.7 1031.96 -216 -402 -209 -48 -68 185 272 176 217 133 137 85 -156 -128 46 120 18 113 271 131 261 431 325 360 407 263 50 57 -148 -296 -6 -47 -422 -218 -139 -329 -210 8 -52 -145 -51 -22 -30 72 145 121 139 50 46 -112 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211 311 371 67 74 291 95 65 134 -117 -124 174 134 -13 172 72 -157 -33 79 -16 58 104 -41 -206 -250 -302 -266 -88 -40 SQ 20220422T224339.5Z 8147.946985 513 7 4.04 2 78.53 277.01 168.43 346.73 0.00 1 0.00 1 0 15 1.942e-03 1.948e-03 1.141e-04 1.140e-04 4.438657e+03 7.246022e+00 2.916880e+02 -6.000000e+00 1.099585e+02 283.69 -2.00 20.00 -2.00 505.28 0.00e+00 8.229841e-04 3.162629e-06 5.068738e-05 -6.000000e+00 5.482912e-05 283.69 -2.00 20.00 -2.00 500.53 0.00e+00 4.119844e-01 2.264803e-03 3.603641e-02 -6.000000e+00 3.886407e-02 229.59 -2.00 3.43 -2.00 502.11 0.00e+00 4.860 0.002 489.00 513.00 1 4.6552e-01 1.7367e-04 7.7002e-03 -6.0000e+00 2.9816e-03 -1.4694e-02 4.4483e-05 8.9160e-04 -6.0000e+00 7.7210e-04 5.8475e-01 4.2840e-04 1.1807e-05 3.6165e-05 -6.0000e+00 2.0924e-04 2.8460e-03 -1.4791e-04 10 0 0 10 0 0 -13.37 23.25 1.85 0.00285 0.00582 607 122 1 4 0 6.340 26.51 19.98 23.25 29.60 20.3 1028.25 -111 -315 -191 -91 -142 123 171 49 146 99 86 20 -162 -87 68 200 92 137 227 112 235 427 325 365 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