File name: Pandora37s1_HamptonVA_20220712_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T152514.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v5d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20220712_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20220712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220712T103908.4Z 8228.443847 170 1 49.70 2 82.99 67.74 116.08 254.46 0.00 1 0.00 1 0 25 9.430e-01 5.752e-02 4.082e-01 1.849e-02 8.668772e-01 1.191492e-02 1.370148e-02 -6.000000e+00 5.784241e-01 232.60 -2.00 3.43 -2.00 322.26 0.00e+00 7.714126e-02 7.390454e-03 1.400172e-02 -6.000000e+00 3.387749e-02 291.28 -2.00 20.00 -2.00 321.76 0.00e+00 7.506 0.007 302.00 328.00 3 7.1570e-01 4.9030e-02 1.8354e-01 -6.0000e+00 1.4618e+00 1.8751e+00 6.6951e-02 2.5701e-01 -6.0000e+00 1.5935e+00 -1.6827e+00 5.9573e-02 2.5829e-02 -6.0000e+00 9.2736e-01 5.2195e-01 2.7616e-02 8.3943e-02 -6.0000e+00 3.9833e-01 3.1320e-05 -3.7163e-03 5.3058e-04 1.0250e-03 -6.0000e+00 2.9176e-02 -5.0159e-02 0.0000e+00 12 9 9 12 20 4 14.96 32.56 0.99 -0.05016 -0.07809 42 8 1 5 0 1183.140 36.22 20.06 32.56 28.69 22.6 1015.40 900000 350007 165924 900000 900000 75488 900000 900000 -91201 900000 900000 -52861 900000 9907 -42964 48945 117647 900000 58731 900000 900000 900000 900000 900000 900000 65283 900000 -47514 900000 -93393 46274 378805 900000 100804 900000 202615 900000 900000 3449 900000 306246 900000 11512 132721 4673 900000 62092 258671 123185 450287 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5815 -4435 -1504 3196 6287 2934 -641 608 -539 -2539 2499 2529 2620 3910 3058 5169 4355 -2135 -3108 -6021 -2992 -3513 -2000 -6076 1224 1811 -2734 -4654 -4138 647 -1149 -5029 819 2147 -895 3354 1357 -1991 -332 2630 -2889 4670 2207 -1378 462 3533 2843 4184 1548 -1871 -1644 -3345 -116 -1882 2344 -474 -328 SS 20220712T105225.1Z 8228.453069 173 1 49.68 2 80.53 69.60 118.51 256.05 0.00 1 0.00 1 0 25 5.117e-01 1.934e-02 1.002e-01 2.334e-03 7.266785e-01 1.307590e-03 8.360928e-03 -6.000000e+00 3.024347e-01 232.60 -2.00 3.43 -2.00 321.20 0.00e+00 2.944305e-03 6.324761e-04 2.335282e-03 -6.000000e+00 1.450199e-02 291.28 -2.00 20.00 -2.00 320.57 0.00e+00 5.779 0.003 302.00 328.00 3 1.0900e+00 4.5388e-03 7.0004e-02 -6.0000e+00 7.5719e-01 2.2329e-01 6.1638e-03 4.0516e-02 -6.0000e+00 8.1690e-01 -3.6712e-01 5.6219e-03 2.0684e-02 -6.0000e+00 4.8337e-01 1.5623e-01 2.6793e-03 6.0138e-03 -6.0000e+00 2.0686e-01 2.6550e-04 -2.0913e-03 6.3344e-05 8.5132e-05 -6.0000e+00 1.3937e-02 -5.1103e-02 0.0000e+00 12 9 8 11 4 0 0.08 32.51 0.41 -0.05110 -0.06682 150 30 1 5 0 331.130 36.11 20.11 32.51 30.03 22.6 1015.90 -217060 -258378 -155125 -121273 900000 900000 900000 -173804 -60458 -57330 -217100 900000 900000 -152443 85587 -56825 -54021 165047 -77943 19742 17607 -60032 -18203 -11045 10888 18041 -48076 -43497 57688 38338 35002 32211 7725 10018 19174 19007 97282 62718 15503 -3690 25475 13932 6686 23454 -1012 22322 20218 227 9886 12053 14328 15826 5441 21917 11074 11313 8705 2275 4290 -1599 12470 4919 7166 6546 14192 5555 8576 14746 12105 1016 2801 6555 -1196 3381 872 3481 -5738 3953 -2157 122 -815 -1079 -3225 -1184 533 -2294 -2948 -2269 -123 -1368 -392 -1186 120 3368 -2825 1422 -1547 -389 -2943 -378 -2078 -778 -925 164 -2290 -483 -2218 -1382 -890 812 -1121 -228 -26 49 983 700 2195 526 617 247 -241 557 1204 -108 971 283 1655 2950 251 584 685 421 512 -280 -151 -355 -132 300 -987 -520 214 -557 -454 -4866 -9598 -2369 -1281 900000 900000 900000 -3275 -444 -441 -7473 900000 900000 -5108 389 -1209 -1273 520 -2624 282 263 -1931 -399 -246 210 343 -1804 -1512 767 664 699 806 290 402 679 655 1787 1783 811 -283 1665 1105 564 1835 -96 1824 1729 23 961 1230 1595 1964 828 3100 1762 1880 1540 431 772 -297 2173 947 1541 1621 3534 1502 2216 3687 3393 348 1061 2535 -501 1287 312 1150 -1913 1193 -720 48 -381 -587 -1902 -732 345 -1640 -2243 -1691 -91 -1048 -280 -796 76 2091 -2065 1102 -1446 -398 -3467 -450 -2410 -810 -907 154 -2336 -494 -2428 -1606 -1071 1082 -1644 -362 -43 79 1496 1017 3108 787 976 414 -392 908 1868 -164 1408 417 2317 4088 379 968 1270 816 1050 -589 -341 -826 -316 730 -2452 -1257 484 -1232 -949 SS 20220712T110147.0Z 8228.459572 178 1 49.16 2 78.77 70.90 120.23 257.17 0.00 1 0.00 1 0 25 3.427e-01 6.795e-03 9.822e-02 2.091e-03 6.456692e-01 1.153927e-03 7.306907e-03 -6.000000e+00 1.993497e-01 232.60 -2.00 3.43 -2.00 321.21 0.00e+00 3.688700e-03 5.583558e-04 1.101513e-03 -6.000000e+00 8.929108e-03 291.28 -2.00 20.00 -2.00 320.55 0.00e+00 4.953 0.002 302.00 328.00 3 8.7181e-01 4.0194e-03 6.0991e-02 -6.0000e+00 4.9987e-01 1.0395e-01 5.4988e-03 3.7184e-02 -6.0000e+00 5.3880e-01 -1.0784e-01 5.2323e-03 1.7887e-02 -6.0000e+00 3.2125e-01 2.9655e-02 2.5070e-03 8.4184e-03 -6.0000e+00 1.3791e-01 7.6969e-04 -1.6934e-03 5.8961e-05 7.4051e-05 -6.0000e+00 9.1369e-03 -5.1431e-02 0.0000e+00 11 9 0 11 20 0 -10.84 32.43 0.33 -0.05143 -0.06416 271 54 1 5 0 181.370 36.01 19.97 32.43 31.06 22.7 1015.49 -30090 -122766 -73472 -119735 -95402 -135949 -137012 -107036 -134031 -79229 -117812 -57913 -89904 -65027 -48289 -30033 -29028 -37925 -30612 -33186 -5375 -23110 -25 -34061 -12871 -29692 -339 -25030 -13707 -20908 -3393 -4134 30 4292 -7181 6934 -14979 2955 -2755 5120 -7372 2394 -91 6249 3053 6700 1207 2113 6533 2909 6993 2646 4882 2524 2913 842 2930 -1220 2360 469 1416 3645 2301 4327 1606 2420 -150 -4014 1531 2030 658 1411 194 -28 56 -458 -645 -312 -78 -550 201 -1081 -1253 -1956 -439 -917 25 284 470 336 142 580 241 579 -261 34 277 930 -487 -822 -135 -308 54 37 -705 -1822 -862 -488 10 18 -64 -394 -26 362 421 771 932 599 -126 -136 -882 73 110 -73 -113 325 471 1509 570 -41 204 13 329 62 20 -484 -256 265 -250 -501 54 125 150 -89 -1093 -436 -1110 -637 -1336 -1473 -972 -1814 -676 -1551 -472 -1283 -940 -752 -473 -474 -754 -619 -733 -93 -479 0 -897 -297 -863 -8 -698 -335 -590 -96 -142 1 174 -316 259 -703 149 -167 347 -645 206 -9 567 291 632 123 221 685 337 862 384 764 442 504 155 548 -239 436 93 285 727 529 1107 454 669 -42 -1177 461 703 259 584 82 -11 21 -153 -198 -94 -26 -215 92 -577 -744 -1247 -294 -661 19 222 370 259 103 389 153 368 -183 28 258 991 -548 -954 -159 -331 52 35 -709 -1982 -975 -587 12 24 -97 -642 -43 583 641 1109 1318 881 -198 -225 -1493 120 173 -110 -165 455 631 2140 837 -69 380 25 692 137 45 -1157 -631 662 -635 -1251 127 295 337 SS 20220712T110757.4Z 8228.463859 181 1 49.01 2 77.60 71.75 121.37 257.91 0.00 1 0.00 1 0 25 2.254e-01 6.616e-03 5.372e-02 1.478e-03 5.968776e-01 8.024541e-04 6.799896e-03 -6.000000e+00 1.311254e-01 232.60 -2.00 3.43 -2.00 320.91 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