File name: Pandora37s1_HamptonVA_20230226_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T154251.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20230226_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20230226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230226T145405.2Z 8457.620893 154 1 49.95 2 56.89 135.95 94.84 58.39 0.00 1 0.00 1 0 25 9.006e-03 6.432e-03 4.705e-04 2.332e-04 2.542142e-01 1.170828e-04 3.041303e-03 -6.000000e+00 5.076169e-03 225.73 -2.00 3.43 -2.00 316.19 0.00e+00 2.499838e-04 1.279453e-05 4.525511e-05 -6.000000e+00 2.226124e-04 279.12 -2.00 20.00 -2.00 315.57 0.00e+00 1.825 0.000 302.00 328.00 3 1.3971e+00 3.0260e-04 2.2203e-02 -6.0000e+00 1.2572e-02 2.1323e-02 3.3853e-04 1.2675e-02 -6.0000e+00 1.3677e-02 -1.5197e-02 1.9660e-04 6.2721e-03 -6.0000e+00 8.1401e-03 2.2228e-03 9.2483e-05 1.7885e-03 -6.0000e+00 3.4815e-03 1.5644e-02 -2.7134e-04 6.5088e-06 2.1624e-05 -6.0000e+00 2.4012e-04 -1.0506e-02 0.0000e+00 11 8 0 10 0 0 99.99 25.36 0.30 -0.01051 -0.01254 1141 229 1 5 0 43.770 29.58 20.02 25.36 15.06 25.2 1022.32 -1878 -2180 -2944 -3347 -2584 -1571 267 302 -814 -1690 -1399 6 -133 494 -61 -233 178 558 910 931 284 1060 1250 993 411 -520 -478 -213 98 1078 1749 2005 177 -1401 -987 -856 72 524 -342 -774 -854 -658 -951 -531 -469 -707 -510 -491 -275 768 927 826 784 483 853 929 455 503 683 964 1358 1253 1141 391 -546 -256 -269 1261 1314 -73 -301 -414 -300 -206 -238 24 103 639 515 -529 -832 -1642 -1946 -1261 -1086 -739 -648 -587 -155 97 279 171 961 1569 778 349 349 162 -306 -545 -567 -11 939 371 -831 -597 -768 -417 218 79 -147 -248 -31 184 549 1021 773 663 207 -409 -622 -340 -98 331 543 66 897 1476 724 369 -245 -133 289 308 -190 -342 -82 -105 -296 -218 -483 -410 49 -370 -460 -623 -645 -476 -282 48 61 -182 -390 -316 1 -35 140 -20 -76 60 194 326 345 107 391 475 401 175 -217 -196 -86 37 401 690 854 78 -628 -434 -375 33 263 -197 -491 -584 -445 -661 -369 -325 -488 -360 -338 -185 517 661 601 602 373 674 748 374 409 543 762 1108 1056 1001 366 -509 -227 -222 1049 1124 -69 -298 -425 -306 -202 -225 21 86 505 429 -481 -816 -1719 -2091 -1356 -1250 -876 -782 -729 -192 119 328 190 1007 1584 807 386 414 206 -400 -702 -708 -13 1076 442 -1015 -770 -1002 -567 299 113 -213 -366 -45 258 728 1304 983 880 286 -588 -892 -481 -139 450 722 87 1148 1871 952 505 -345 -193 422 452 -288 -531 -131 -171 -473 -352 -753 -633 73 SS 20230226T145925.9Z 8457.624605 157 1 46.54 2 56.16 137.27 93.95 59.19 0.00 1 0.00 1 0 25 1.108e-02 6.587e-03 1.916e-03 9.399e-04 2.502552e-01 4.711344e-04 3.002604e-03 -6.000000e+00 6.247248e-03 225.73 -2.00 3.43 -2.00 316.20 0.00e+00 4.107599e-04 5.170126e-05 5.503131e-05 -6.000000e+00 2.739110e-04 279.12 -2.00 20.00 -2.00 315.57 0.00e+00 1.790 0.000 302.00 328.00 3 4.0732e+00 1.2184e-03 2.1823e-02 -6.0000e+00 1.5472e-02 4.1129e-02 1.3636e-03 1.2510e-02 -6.0000e+00 1.6832e-02 -1.4074e-02 7.9148e-04 6.1889e-03 -6.0000e+00 1.0017e-02 1.5358e-03 3.7283e-04 1.7849e-03 -6.0000e+00 4.2853e-03 1.1091e-03 -3.4188e-04 2.6208e-05 2.1093e-05 -6.0000e+00 2.9544e-04 -1.1731e-02 0.0000e+00 12 9 1 12 1 1 99.96 25.45 0.28 -0.01173 -0.01430 63 14 1 5 0 724.550 29.69 19.82 25.45 15.69 25.0 1021.50 -3103 -6496 -2976 -2598 -2175 -572 1042 -206 -816 -1606 -2904 3626 -28 -13 573 -855 -416 590 952 1083 773 861 1021 1415 169 365 -1117 -113 251 1068 2018 1386 603 -757 -848 -42 839 1302 -553 -675 -1030 -638 -987 -499 -494 -913 -133 -607 -106 1040 719 591 574 553 790 1231 162 386 90 1009 1321 1213 1262 486 -380 -224 -248 -520 1621 -178 -121 -217 -241 8 -143 23 -247 607 437 -408 -996 -1438 -1977 -1196 -951 -759 -683 -637 -217 197 193 -17 984 1736 554 612 518 153 -292 -383 -496 -21 705 367 -841 -486 -838 -525 52 266 -273 -158 22 282 458 990 935 523 115 -368 -667 -379 -117 492 636 142 1016 1530 738 365 -210 -192 188 303 -175 -385 -47 -120 -384 -137 -382 -463 -16 -619 -1373 -630 -497 -386 -98 182 -41 -180 -367 -658 807 -7 -4 178 -292 -140 204 341 400 288 317 387 564 69 153 -467 -45 93 393 785 565 267 -341 -354 -17 380 666 -324 -428 -708 -440 -700 -353 -349 -644 -91 -418 -71 696 496 437 435 428 625 989 133 314 72 796 1075 1036 1139 456 -354 -196 -207 -437 1393 -168 -120 -220 -242 8 -135 20 -204 487 359 -371 -970 -1474 -2116 -1328 -1077 -899 -834 -801 -272 242 224 -18 1033 1749 582 692 623 195 -381 -502 -623 -26 809 427 -1053 -627 -1110 -710 72 383 -401 -235 32 397 614 1261 1181 677 157 -518 -966 -542 -166 679 850 186 1273 1897 960 500 -292 -275 272 445 -263 -600 -75 -192 -624 -217 -596 -710 -24 SS 20230226T150329.6Z 8457.627426 160 1 10.76 2 55.61 138.29 93.27 59.80 0.00 1 0.00 1 0 17 2.118e-02 9.418e-03 1.012e-02 4.694e-03 2.447295e-01 2.354997e-03 2.950414e-03 -6.000000e+00 1.194082e-02 225.73 -2.00 3.43 -2.00 316.33 0.00e+00 -8.003116e-05 2.661077e-04 4.774119e-05 -6.000000e+00 5.235735e-04 279.12 -2.00 20.00 -2.00 315.71 0.00e+00 1.765 0.000 302.00 328.00 3 5.3639e+00 6.1042e-03 2.1483e-02 -6.0000e+00 2.9573e-02 4.0024e-02 6.8368e-03 1.2273e-02 -6.0000e+00 3.2172e-02 -5.0099e-03 3.9811e-03 6.0770e-03 -6.0000e+00 1.9147e-02 1.3045e-04 1.8867e-03 1.7231e-03 -6.0000e+00 8.1906e-03 3.1504e-04 -5.0189e-04 1.3189e-04 2.0731e-05 -6.0000e+00 5.6473e-04 -1.1432e-02 0.0000e+00 12 9 9 12 33 1 999.00 25.53 0.65 -0.01143 -0.01520 2 3 1 5 0 3530.200 29.80 20.00 25.53 15.85 24.9 1020.27 -5909 3147 -6506 -8526 -7717 -230 3392 2563 -2625 -4442 -3491 11039 -2438 3147 -3154 -3046 3898 3478 -262 1627 -1770 -33 2164 1056 982 522 -1361 -65 -989 1946 3380 -1435 3860 -934 -1393 1787 1287 2907 -2306 -266 -1797 -792 -25 316 -2211 620 -409 -970 68 1540 -839 1167 468 1018 1397 889 241 19 -293 713 256 1043 1798 28 -331 -546 -8 953 2492 -63 408 1073 -741 -458 -557 -415 388 62 233 -1117 -1239 -2198 -2204 -903 -381 -804 -844 -329 372 680 275 -911 -634 2187 241 999 627 184 -755 490 -1627 -553 606 -26 -808 -68 -563 407 427 160 -99 -282 119 198 1595 472 759 89 -683 -314 -942 -122 -686 1137 1078 310 1232 2020 21 -101 -294 -513 1245 -120 -307 -381 -179 -324 -87 819 -242 -811 -616 -1114 580 -1304 -1599 -1300 -36 550 468 -547 -965 -738 2142 -591 816 -957 -985 1222 1127 -90 567 -639 -12 771 398 386 211 -552 -25 -356 683 1233 -579 1586 -400 -564 703 552 1398 -1326 -168 -1208 -544 -17 220 -1559 428 -279 -652 44 1008 -582 838 350 786 1096 709 195 16 -234 564 208 886 1605 26 -308 -481 -7 778 2112 -60 403 1084 -754 -454 -527 -365 317 49 190 -998 -1196 -2272 -2371 -991 -435 -961 -1045 -414 466 831 321 -1011 -662 2197 253 1113 748 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