File name: Pandora37s1_HamptonVA_20230517_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T163840.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20230517_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20230517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230517T112802.5Z 8537.477806 114 1 5.72 2 73.44 77.99 58.12 101.82 0.00 1 0.00 1 0 17 3.656e-01 2.505e-02 2.222e-01 1.324e-02 4.750479e-01 7.021233e-03 5.509091e-03 -6.000000e+00 2.144762e-01 231.38 -2.00 3.43 -2.00 319.56 0.00e+00 7.263330e-03 1.961227e-03 7.693141e-04 -6.000000e+00 1.058354e-02 286.14 -2.00 20.00 -2.00 318.85 0.00e+00 3.452 0.001 302.00 328.00 3 4.1780e+00 1.9914e-02 4.3227e-02 -6.0000e+00 5.4001e-01 1.3252e-01 2.3506e-02 2.7676e-02 -6.0000e+00 5.8475e-01 -9.5693e-02 1.8820e-02 1.3312e-02 -6.0000e+00 3.4321e-01 2.8498e-02 9.9159e-03 8.9219e-03 -6.0000e+00 1.4943e-01 1.3525e-04 -1.7562e-03 3.7636e-04 6.7844e-05 -6.0000e+00 9.9594e-03 -6.8693e-02 0.0000e+00 12 9 9 12 21 5 999.00 35.46 0.73 -0.06869 -0.08189 1 4 1 5 0 2774.830 39.80 20.00 35.46 26.80 26.9 1007.65 900000 900000 -70332 -61888 21483 900000 -80615 28938 900000 900000 900000 -98162 65399 196127 206856 136164 17483 -32850 -44474 611 97100 15496 29321 128338 18992 9704 -18843 55592 -28183 -23670 25744 -33727 -6392 35504 3360 21840 -12381 14528 37572 -5251 15245 -16274 2556 -1301 11469 14932 7964 9436 12640 15547 -314 6489 3211 8728 -442 2287 7834 4251 -9616 1883 4450 2188 -3216 -527 521 -1829 -71 -17547 6284 -1209 -3516 1593 7104 59 3567 -2640 6730 3023 -8363 2149 -20 -1134 -5201 1647 -806 -1132 -1801 -1793 -2361 26 343 4827 -676 74 2504 3249 2611 200 -80 -266 994 -1408 1995 -1864 -1247 -330 -1466 -1029 -1024 493 -2192 1863 -1812 -599 811 -1149 1324 2460 -937 697 1843 1256 -1151 -1388 1240 675 239 62 665 1513 2030 -717 861 -427 -813 565 -2128 710 -767 802 -1093 -173 450 900000 900000 -2830 -2260 325 900000 -3101 433 900000 900000 900000 -6047 1036 2529 2667 1990 864 -2814 -4558 43 2842 969 1619 2918 1261 729 -1886 2702 -2927 -2429 1869 -4946 -821 3323 412 2155 -1786 1859 4603 -1128 3022 -4587 635 -346 2760 3555 2050 2422 3201 3938 -98 2076 1137 3129 -180 930 3094 1739 -4359 762 1797 964 -1636 -288 297 -1037 -38 -10700 3260 -744 -2432 1110 4771 41 2260 -1619 3504 1563 -4946 1306 -14 -890 -4556 1430 -747 -1110 -1859 -1910 -2556 28 342 4375 -602 64 2203 3115 2784 239 -103 -353 1269 -1717 2207 -2071 -1444 -400 -1857 -1354 -1409 713 -3439 2967 -2977 -952 1220 -1673 1858 3491 -1418 1093 2927 1987 -1811 -2140 1819 965 331 84 947 2307 3277 -1231 1499 -770 -1527 1096 -4306 1430 -1577 1620 -2173 -332 831 SS 20230517T113640.7Z 8537.483804 121 1 7.37 2 71.75 79.19 56.46 103.28 0.00 1 0.00 1 0 17 3.430e-01 3.929e-02 1.001e-01 8.332e-03 4.300903e-01 4.381667e-03 5.007177e-03 -6.000000e+00 2.014210e-01 231.39 -2.00 3.43 -2.00 319.17 0.00e+00 9.895119e-03 1.095257e-03 5.967760e-04 -6.000000e+00 9.789905e-03 286.14 -2.00 20.00 -2.00 318.44 0.00e+00 3.151 0.000 302.00 328.00 3 4.2995e+00 1.2258e-02 3.9428e-02 -6.0000e+00 5.0615e-01 9.2084e-02 1.4255e-02 2.6231e-02 -6.0000e+00 5.4721e-01 -1.3719e-01 1.0392e-02 1.2816e-02 -6.0000e+00 3.2200e-01 7.2817e-02 5.4183e-03 1.0470e-02 -6.0000e+00 1.3835e-01 1.7148e-04 -1.1344e-03 2.3601e-04 8.5909e-05 -6.0000e+00 9.5022e-03 -6.9793e-02 0.0000e+00 12 9 9 12 37 5 999.00 35.48 0.93 -0.06979 -0.07832 2 4 1 5 0 2401.820 39.80 19.97 35.48 27.13 26.9 1007.38 -30164 -151776 -5123 900000 900000 900000 88348 -32583 900000 900000 84043 -60497 900000 31757 121517 -14856 -22477 108583 34979 105338 125204 65597 28225 49301 3624 -11114 11418 25165 58329 83476 41994 21457 72968 78557 73261 96959 14566 45100 -3725 -9748 11498 4863 -9 2268 -2150 3104 26918 8020 22211 14568 -4017 9861 5560 7346 2275 6394 -758 -502 -6826 -1513 10194 171 4497 -3840 13149 -1738 2687 -24308 10627 -1580 -5540 2476 -2818 -3957 4774 -2090 -2545 9037 -396 -1013 1493 -17 -2297 -2651 -1763 371 -1105 -5211 -2257 1867 1214 -1245 2575 1239 -207 -451 2699 459 -2988 3795 -2800 404 444 1222 -2438 572 -4007 -1680 -1447 2984 -1762 -1895 149 -2435 511 1270 4110 -422 2175 3965 -1408 -2225 1908 -400 2109 3011 3778 1256 1074 1125 1361 -362 2047 -136 -979 -995 154 729 -1568 -321 136 -1582 -1920 -1222 -22071 -201 900000 900000 900000 1177 -1453 900000 900000 1380 -4094 900000 1336 2675 -1376 -2451 3709 2540 4122 4157 3756 2279 3345 387 -1391 1172 2219 3672 4283 3564 2525 5952 6513 6131 6200 2123 5606 -851 -2718 2920 1385 -3 714 -715 1008 7178 2545 6280 4493 -1540 3622 2257 3100 1040 2867 -366 -242 -3407 -717 4489 87 2433 -2418 7539 -1093 1551 -17108 5859 -1063 -4199 1845 -2203 -3040 3250 -1388 -1568 4879 -239 -684 1109 -14 -2068 -2491 -1718 375 -1180 -5901 -2532 2010 1258 -1238 2348 1107 -194 -460 2953 559 -3990 4937 -3701 492 507 1363 -2920 706 -5268 -2258 -2023 4275 -2753 -3074 240 -3872 762 1801 5616 -606 3193 6017 -2261 -3572 2926 -610 3068 4227 5111 1702 1517 1697 2161 -603 3428 -237 -1769 -1871 295 1404 -3093 -623 256 -2928 -3460 SS 20230517T114123.8Z 8537.487081 124 1 4.24 2 70.82 79.84 55.55 104.10 0.00 1 0.00 1 0 17 2.316e-01 3.753e-02 1.399e-01 1.096e-02 4.546339e-01 5.664926e-03 5.298662e-03 -6.000000e+00 1.344065e-01 231.39 -2.00 3.43 -2.00 318.88 0.00e+00 4.820401e-03 1.272525e-03 8.207765e-04 -6.000000e+00 5.902321e-03 286.14 -2.00 20.00 -2.00 318.12 0.00e+00 3.008 0.000 302.00 328.00 3 4.0159e+00 1.5520e-02 3.8676e-02 -6.0000e+00 3.3667e-01 2.0069e-01 1.7886e-02 2.4990e-02 -6.0000e+00 3.6323e-01 -8.7494e-02 1.2861e-02 1.1576e-02 -6.0000e+00 2.1611e-01 7.3201e-03 6.7807e-03 5.1726e-03 -6.0000e+00 9.2816e-02 2.4079e-04 -2.9394e-03 3.0058e-04 4.5002e-05 -6.0000e+00 6.1668e-03 -6.9464e-02 0.0000e+00 12 9 9 12 21 5 999.00 35.50 0.44 -0.06946 -0.09155 1 5 1 5 0 2035.680 39.80 20.01 35.50 27.29 26.9 1007.73 -41504 2888 44321 -66257 39196 -90061 -54830 -68008 44914 27979 168374 2621 75589 -32243 -8636 -49 -7493 -11689 15199 42451 23973 10342 -11389 -2281 -11841 -3218 -24221 -12768 -24126 7387 2580 8609 33030 13520 3602 -7565 21116 6748 13474 -4359 2777 -4718 1380 7343 -4275 13602 7332 11662 4443 8867 -636 6182 8674 4085 3821 75 -1963 1456 -4152 -1874 5397 7347 6233 4449 1283 2933 4158 -42059 10077 242 -90 390 4430 -1232 1262 1688 -532 1115 2282 -218 5096 1997 -185 -2080 1430 363 -1623 735 168 539 735 -72 2190 1807 -143 -1476 956 -721 -188 295 -311 493 265 169 -2101 -1599 -1975 -1399 -1584 350 -4 563 -317 789 1253 1525 2331 66 978 -1670 -1515 644 2265 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