File name: Pandora37s1_HamptonVA_20230622_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T165833.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20230622_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20230622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230622T212230.5Z 8573.890631 466 1 7.01 2 55.68 275.01 20.42 201.33 0.00 1 0.00 1 0 25 9.229e-03 6.306e-03 4.406e-03 2.231e-03 2.488560e-01 1.146886e-03 2.918096e-03 -6.000000e+00 5.328454e-03 232.77 -2.00 3.43 -2.00 316.14 0.00e+00 1.894438e-04 1.255036e-04 4.252160e-05 -6.000000e+00 2.383441e-04 289.55 -2.00 20.00 -2.00 315.33 0.00e+00 1.768 0.000 302.00 328.00 3 3.8031e+00 3.0045e-03 2.1929e-02 -6.0000e+00 1.3371e-02 2.2509e-02 3.3496e-03 1.2763e-02 -6.0000e+00 1.4459e-02 -1.1531e-02 1.9245e-03 6.1601e-03 -6.0000e+00 8.6101e-03 1.9162e-03 8.8727e-04 1.6818e-03 -6.0000e+00 3.6508e-03 1.4889e-03 5.0485e-05 6.2330e-05 1.9947e-05 -6.0000e+00 2.4685e-04 1.0294e-02 0.0000e+00 12 1 1 12 1 1 99.14 21.53 0.19 0.01029 0.01067 8 13 1 5 0 760.660 25.28 20.00 21.53 28.15 28.1 1017.26 -2057 -2695 -3411 -1484 -2105 215 1624 791 97 -1521 -3467 -1449 407 119 651 -1146 592 790 628 174 250 693 1259 1070 433 -687 -310 -1388 -915 1466 1368 1691 -482 -1307 -740 -542 -1006 196 89 -925 -1033 -66 -482 -36 119 -541 -38 -662 -199 605 691 625 933 972 704 1577 377 818 374 1203 1781 1158 611 192 -342 251 190 336 1226 -199 -511 -604 -363 -432 -319 -345 -95 592 128 -1161 -903 -1540 -1994 -824 -861 -458 -683 -342 91 -29 102 345 1152 1405 469 229 134 98 -487 -392 -129 -151 693 486 -946 -708 -781 -386 290 -33 -219 37 140 -108 496 634 739 332 226 -230 -644 -278 134 340 699 172 1257 1467 620 79 193 161 484 174 34 -283 -226 -289 -336 -330 -340 -490 -203 -426 -586 -737 -288 -378 38 308 168 22 -357 -816 -354 109 35 211 -397 208 285 233 66 96 264 491 436 184 -299 -132 -562 -354 562 553 722 -220 -593 -317 -236 -478 104 53 -609 -710 -46 -343 -26 85 -384 -26 -455 -135 413 491 463 714 765 564 1273 310 665 301 967 1464 1003 557 181 -317 220 159 281 1076 -190 -511 -616 -368 -427 -300 -304 -78 478 109 -1066 -885 -1600 -2147 -906 -988 -544 -838 -425 112 -35 117 375 1187 1433 500 260 161 125 -638 -505 -160 -179 796 574 -1182 -909 -1029 -520 401 -48 -322 55 202 -149 651 806 940 435 309 -327 -926 -397 188 465 926 223 1571 1842 812 107 270 229 693 255 51 -441 -357 -463 -540 -524 -529 -748 -306 SS 20230622T212717.4Z 8573.893952 469 1 8.23 2 56.63 275.67 20.80 204.32 0.00 1 0.00 1 0 25 9.457e-03 6.495e-03 4.046e-03 1.976e-03 2.559355e-01 1.015554e-03 3.005168e-03 -6.000000e+00 5.460334e-03 232.77 -2.00 3.43 -2.00 316.23 0.00e+00 2.375679e-04 1.137525e-04 5.033503e-05 -6.000000e+00 2.442474e-04 289.55 -2.00 20.00 -2.00 315.41 0.00e+00 1.812 0.000 302.00 328.00 3 3.6943e+00 2.6638e-03 2.2512e-02 -6.0000e+00 1.3702e-02 2.3905e-02 2.9724e-03 1.3149e-02 -6.0000e+00 1.4817e-02 -1.1729e-02 1.7098e-03 6.3445e-03 -6.0000e+00 8.8233e-03 1.6435e-03 7.9119e-04 1.7360e-03 -6.0000e+00 3.7411e-03 1.5696e-03 -3.4243e-05 5.5200e-05 2.0699e-05 -6.0000e+00 2.5297e-04 1.0527e-02 0.0000e+00 12 9 1 12 1 1 95.99 21.53 0.30 0.01053 0.01027 10 14 1 5 0 732.930 25.28 20.01 21.53 28.38 28.1 1017.62 -2424 -3608 -3276 -1558 -1369 -1648 794 -89 322 -1014 -761 2803 577 67 -536 -1080 689 600 1707 914 -300 1542 844 575 575 -275 -955 -722 1130 626 1871 2013 92 -683 -1332 -1011 -629 419 -530 -1304 -1003 -490 -1203 -454 -698 -775 -725 -28 -409 1044 730 406 784 565 1070 1061 54 765 734 663 1285 731 1212 321 -591 246 -474 1560 1090 -84 69 -352 -484 -302 -283 -30 397 938 195 -1110 -1019 -1490 -1747 -769 -975 -861 -595 -417 19 77 671 456 1008 1525 741 446 590 -184 -676 -542 -391 19 722 110 -1032 -353 -799 -322 295 182 -203 -249 102 133 484 877 520 574 230 -420 -657 -538 90 126 282 -104 1384 1364 476 334 276 -216 441 275 -192 -585 46 -176 -304 -19 -223 -541 -13 -481 -765 -681 -285 -227 -275 142 -18 71 -231 -170 645 144 19 -175 -356 230 209 609 340 -113 567 325 236 233 -115 -390 -289 419 236 750 820 41 -302 -552 -425 -296 219 -318 -853 -666 -336 -849 -318 -489 -540 -492 -20 -278 713 509 303 587 444 858 869 43 629 591 536 1031 638 1093 294 -553 218 -394 1262 969 -79 70 -354 -482 -299 -269 -26 332 753 161 -1011 -996 -1544 -1849 -846 -1115 -1016 -736 -511 24 93 761 489 1024 1576 794 511 698 -234 -877 -706 -491 23 845 131 -1305 -451 -1039 -435 404 257 -303 -373 146 182 645 1137 656 760 318 -602 -934 -777 125 173 380 -133 1726 1716 625 455 383 -309 637 401 -290 -933 73 -285 -495 -30 -350 -823 -21 SS 20230622T213131.6Z 8573.896893 472 1 49.70 2 57.47 276.25 21.17 206.89 0.00 1 0.00 1 0 17 1.955e-02 7.585e-03 6.901e-03 2.323e-03 2.607537e-01 1.184471e-03 3.037672e-03 -6.000000e+00 1.129084e-02 232.77 -2.00 3.43 -2.00 317.22 0.00e+00 3.796486e-04 1.677442e-04 6.474366e-05 -6.000000e+00 5.049914e-04 289.55 -2.00 20.00 -2.00 316.36 0.00e+00 1.853 0.000 302.00 328.00 3 5.4540e+00 3.1566e-03 2.3005e-02 -6.0000e+00 2.8334e-02 3.7122e-02 3.5461e-03 1.3431e-02 -6.0000e+00 3.0636e-02 -2.3538e-03 2.0980e-03 6.4764e-03 -6.0000e+00 1.8243e-02 -3.4952e-03 1.0214e-03 1.7769e-03 -6.0000e+00 7.7373e-03 2.5474e-04 1.6006e-04 6.6110e-05 1.9534e-05 -6.0000e+00 5.2294e-04 8.6988e-03 0.0000e+00 11 8 0 10 0 0 99.99 21.55 0.15 0.00870 0.00990 50 10 1 5 0 993.810 25.28 20.00 21.55 28.68 28.1 1017.43 -1582 -14178 -2246 2639 -577 7238 6451 2409 5287 -1120 -982 4013 5228 -1497 503 -3261 1276 2212 425 -987 -919 2307 1680 337 793 447 -1600 -297 -2127 639 1076 1281 -1060 -1343 -1721 84 -2099 1817 462 -1603 -1721 -230 -1803 -1145 -951 -1644 599 -1180 -682 1417 1127 572 1411 950 845 1695 43 385 239 1107 1554 303 661 852 481 -120 160 1044 2463 141 -174 476 -302 -430 -50 -227 -1008 1179 -1203 -859 -586 -1894 -1859 -991 -700 -429 -833 -224 397 106 843 278 1093 1769 52 691 649 41 -239 -550 -253 -704 312 235 -1087 -167 -1308 -812 46 949 -127 13 240 161 106 333 1067 179 -19 -489 -223 -295 287 202 428 -833 1876 1771 95 140 -314 -308 360 96 -301 -305 -248 321 -95 -203 48 -334 -186 -197 -2089 -294 300 -62 727 712 309 715 -163 -141 588 855 -295 109 -779 302 539 109 -264 -247 601 456 98 239 138 -492 -84 -585 174 312 399 -360 -451 -545 27 -754 732 220 -869 -989 -135 -1090 -690 -572 -991 348 -682 -387 804 677 365 934 656 596 1208 32 278 170 785 1137 238 554 741 410 -96 121 781 1957 126 -165 460 -291 -401 -44 -182 -757 848 -931 -731 -543 -1902 -1947 -1069 -794 -510 -1032 -282 496 128 956 295 1084 1726 54 771 782 54 -322 -729 -318 -837 357 279 -1379 -219 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