File name: Pandora37s1_HamptonVA_20230821_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T174528.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20230821_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20230821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230821T112858.3Z 8633.478453 59 1 49.66 2 78.75 83.24 132.70 65.43 0.00 1 0.00 1 0 25 2.774e-01 1.258e-02 1.618e-01 3.222e-03 6.054016e-01 1.698530e-03 6.864141e-03 -6.000000e+00 1.594152e-01 231.16 -2.00 3.43 -2.00 320.75 0.00e+00 2.626690e-03 7.266806e-04 1.337605e-03 -6.000000e+00 7.241308e-03 291.91 -2.00 20.00 -2.00 320.02 0.00e+00 4.947 0.002 302.00 328.00 3 2.6662e+00 5.5720e-03 5.8693e-02 -6.0000e+00 3.9811e-01 7.8514e-02 7.2134e-03 3.2020e-02 -6.0000e+00 4.3071e-01 -1.5180e-01 6.4151e-03 1.6188e-02 -6.0000e+00 2.5721e-01 5.9579e-02 3.1793e-03 4.8804e-03 -6.0000e+00 1.0982e-01 1.4224e-04 -1.1209e-03 8.8695e-05 6.1243e-05 -6.0000e+00 7.4173e-03 3.6377e-03 0.0000e+00 12 8 8 10 0 0 -66.58 20.83 0.54 0.00364 -0.00479 54 11 1 5 0 919.530 24.14 20.01 20.83 33.36 29.6 1020.83 -87873 -171441 -72220 70019 -87027 -37962 -38754 -58476 70433 -30830 -55326 68425 23056 -34389 -4720 -58799 61424 43247 -37317 -24945 -55869 -15005 -14303 -20236 2308 77107 -29538 -1748 -30272 -33842 -2196 30980 -25073 -9379 18416 -5053 -9389 17926 21669 -8518 31 2475 -1113 -4898 3200 -5183 7888 2805 2568 11269 5306 8084 4115 4346 3976 4298 434 -314 995 1836 2044 -2979 -539 1381 5486 579 4527 22434 7710 33 41 2331 -1173 -1737 -1030 531 -3450 871 -3433 -1286 -1567 -3132 -1928 -1935 -1047 -315 -1327 27 1658 -1183 1624 -670 1808 1310 -963 507 -501 -894 -1196 -346 -291 -618 96 381 -1544 55 -1699 -1102 673 1038 224 273 362 279 121 366 1708 119 152 -514 -322 43 604 -226 -279 -758 2012 2005 -461 -251 150 -222 433 -49 -504 -419 251 168 117 -799 -10 56 56 -1004 -4669 -825 220 -994 -271 -310 -652 241 -308 -743 313 211 -648 -89 -2033 772 717 -1358 -843 -2604 -468 -472 -774 76 1366 -1392 -60 -1379 -1772 -100 1193 -1782 -636 897 -318 -698 1225 1619 -1015 4 312 -152 -708 433 -781 1062 410 393 1700 949 1565 841 959 927 1040 112 -81 246 447 521 -887 -178 497 1952 209 1547 6652 2965 16 20 1154 -591 -829 -477 218 -1381 341 -1586 -643 -914 -2109 -1395 -1483 -800 -255 -1144 24 1420 -1001 1326 -522 1320 994 -785 470 -542 -1042 -1511 -430 -338 -690 98 398 -1671 62 -2057 -1420 931 1507 361 438 577 451 185 534 2479 184 251 -845 -527 71 965 -352 -416 -1096 2888 2818 -744 -430 281 -419 851 -103 -1079 -946 578 394 274 -1828 -22 119 115 SS 20230821T113452.3Z 8633.482550 62 1 50.24 2 77.58 84.11 131.68 66.73 0.00 1 0.00 1 0 25 1.495e-01 7.275e-03 6.134e-02 2.064e-03 5.609994e-01 1.074196e-03 6.332420e-03 -6.000000e+00 8.590145e-02 231.16 -2.00 3.43 -2.00 320.33 0.00e+00 2.082485e-03 4.027083e-04 2.768258e-04 -6.000000e+00 3.902066e-03 291.91 -2.00 20.00 -2.00 319.54 0.00e+00 4.516 0.001 302.00 328.00 3 2.3881e+00 3.3368e-03 5.3671e-02 -6.0000e+00 2.1452e-01 2.4074e-02 4.2150e-03 2.9212e-02 -6.0000e+00 2.3209e-01 -5.8983e-02 3.6552e-03 1.4509e-02 -6.0000e+00 1.3860e-01 1.5420e-02 1.8483e-03 4.8106e-03 -6.0000e+00 5.9175e-02 2.9708e-04 -7.8081e-04 5.6940e-05 4.8274e-05 -6.0000e+00 3.9970e-03 3.8287e-03 0.0000e+00 11 8 0 10 0 0 -34.04 20.84 0.44 0.00383 -0.00204 90 18 1 5 0 558.120 24.14 20.01 20.84 33.55 29.5 1021.02 -33944 -108578 -26386 -20861 -56432 -11486 -37373 -39182 -46398 -27448 -51354 21643 -7454 -17129 -698 -17798 3337 19696 -11640 -12588 -30297 -3258 -1867 -10636 -3351 16780 -19909 -7837 -13364 -9777 5117 11199 -7499 -9255 382 -5074 -7801 6457 5525 -3315 -963 -986 -2442 -992 -636 -1249 3548 -661 281 5449 4062 3150 3315 1288 2669 785 445 -499 -545 223 1678 17 -141 1486 1684 445 1844 1320 3632 1329 82 1558 -27 -1052 -462 -981 -1467 31 -1866 -925 -937 -2449 -1751 -712 -853 -327 -727 418 1040 -60 1112 130 1088 1542 179 281 -225 -365 -592 -438 -251 -259 707 -55 -1344 -624 -1145 -705 728 625 93 101 307 221 502 645 953 268 -154 -923 -610 -283 518 -102 -93 -751 1392 1342 84 24 2 -131 459 146 -444 -413 131 41 -220 -306 35 -185 348 -298 -2076 -251 -176 -630 -84 -397 -488 -696 -362 -902 214 -124 -395 -17 -537 90 496 -430 -494 -1443 -120 -72 -492 -155 667 -1142 -382 -686 -533 284 684 -579 -748 29 -383 -687 597 634 -490 -154 -167 -440 -179 -117 -218 647 -120 52 1033 870 755 864 370 795 248 145 -163 -173 70 545 6 -55 626 723 186 744 553 1661 716 49 948 -17 -611 -243 -467 -657 14 -958 -554 -610 -1829 -1408 -565 -727 -296 -695 406 1001 -56 953 111 881 1277 158 285 -248 -433 -758 -554 -312 -291 730 -58 -1572 -766 -1412 -924 1022 925 152 164 492 355 756 927 1376 409 -251 -1517 -997 -470 825 -158 -138 -1078 1980 1975 132 40 4 -242 878 296 -928 -910 281 89 -486 -653 73 -369 702 SS 20230821T114014.5Z 8633.486278 65 1 49.91 2 76.52 84.89 130.74 67.88 0.00 1 0.00 1 0 25 1.318e-01 7.383e-03 2.982e-02 1.552e-03 5.243360e-01 8.036028e-04 5.953740e-03 -6.000000e+00 7.574485e-02 231.16 -2.00 3.43 -2.00 320.00 0.00e+00 2.385283e-03 2.665118e-04 2.607539e-04 -6.000000e+00 3.440611e-03 291.91 -2.00 20.00 -2.00 319.18 0.00e+00 4.184 0.001 302.00 328.00 3 2.2453e+00 2.3973e-03 4.9865e-02 -6.0000e+00 1.8916e-01 2.5246e-02 2.9425e-03 2.7277e-02 -6.0000e+00 2.0465e-01 -5.7820e-02 2.4256e-03 1.3492e-02 -6.0000e+00 1.2221e-01 1.4437e-02 1.2482e-03 4.6013e-03 -6.0000e+00 5.2180e-02 4.8724e-04 -6.6630e-04 4.3002e-05 4.5992e-05 -6.0000e+00 3.5242e-03 3.4944e-03 0.0000e+00 11 8 0 10 0 0 -3.92 20.86 0.50 0.00349 -0.00151 122 24 1 5 0 409.030 24.14 20.01 20.86 33.67 29.6 1020.89 -41823 -70813 -42138 -55135 -31996 -31982 -22361 -54169 -12622 -41256 -46600 -19471 1961 -20778 -3842 -20401 6701 -290 -2182 4248 -15674 -1227 -10461 1240 -7183 9477 -15950 -8339 -9355 -6616 368 3563 -93 -5942 1386 -6443 -1375 1157 2631 -3345 -354 -1522 -1302 -489 706 951 2383 654 -839 4278 1899 3317 2373 2228 1638 1574 674 -1098 852 1425 2953 655 2198 918 1982 928 1613 -5239 2889 798 196 689 -526 -449 -799 300 -1656 880 -1422 -823 -1048 -1902 -1711 -992 -709 -572 -23 70 907 -39 1059 54 972 1089 -258 396 77 102 -499 -587 -221 -414 229 245 -1508 -596 -1203 -550 360 587 85 109 400 333 572 815 919 142 -6 -858 -671 -207 283 -34 39 -337 1059 1505 29 278 -247 144 279 189 -228 -417 62 -131 -135 -508 -1 -138 418 -639 -1471 -678 -941 -441 -450 -318 -1103 -208 -868 -1077 -396 40 -666 -126 -909 250 -13 -104 199 -908 -62 -616 71 -476 557 -1104 -559 -627 -471 26 284 -9 -603 124 -636 -146 145 397 -629 -66 -303 -270 -102 148 203 507 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