File name: Pandora37s1_HamptonVA_20230904_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T175448.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20230904_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20230904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230904T112231.0Z 8647.473970 226 1 49.28 2 82.14 86.93 40.31 249.68 0.00 1 0.00 1 0 25 7.487e-01 4.776e-02 3.088e-01 9.578e-03 7.844737e-01 5.496751e-03 9.820582e-03 -6.000000e+00 4.407751e-01 230.17 -2.00 3.43 -2.00 321.78 0.00e+00 3.789341e-02 3.090012e-03 4.564722e-03 -6.000000e+00 2.447569e-02 291.02 -2.00 20.00 -2.00 321.19 0.00e+00 6.810 0.005 302.00 328.00 3 2.0134e+00 2.1234e-02 1.0247e-01 -6.0000e+00 1.1050e+00 1.0895e+00 2.8257e-02 1.1042e-01 -6.0000e+00 1.2059e+00 -1.1575e+00 2.3978e-02 2.4987e-02 -6.0000e+00 7.1089e-01 4.1258e-01 1.1263e-02 4.5151e-02 -6.0000e+00 3.0406e-01 2.7216e-05 -3.0806e-03 2.6018e-04 4.6044e-04 -6.0000e+00 2.0929e-02 4.2271e-03 0.0000e+00 12 8 8 10 0 0 5.33 20.71 0.98 0.00423 -0.01892 26 5 1 5 0 1895.140 24.14 20.01 20.71 30.73 29.7 1016.82 900000 -117132 81249 157726 70088 900000 198250 -48815 900000 900000 -167253 900000 900000 -39926 153308 28999 900000 900000 24979 63670 -15493 149544 4793 23050 900000 900000 -16547 44486 36994 -36661 900000 900000 -6958 79067 74180 250396 96478 900000 452299 -19444 35705 71962 -5345 30887 23715 26685 338383 55232 89939 164173 113488 57910 84684 67432 74059 41766 50447 6188 8359 24714 34761 472 3405 45735 57216 31968 43542 -72564 59956 28384 10351 33595 6827 -7656 8359 3571 7996 26931 -283 7249 11089 -1956 7391 -508 1463 3125 -9131 4001 7500 -6179 7156 -2416 -4138 10848 -9416 4103 -5440 -2530 1436 2388 5551 -3094 1894 1609 -333 3637 -5442 -6107 329 3654 -1808 -823 -1161 -464 -4008 271 3055 -407 1171 399 751 1755 1501 -1378 -2484 -3406 7029 3192 -2225 213 2147 649 2042 -643 -905 -112 650 -325 153 -1569 531 323 -960 900000 -7135 757 1469 653 900000 1847 -796 900000 900000 -6593 900000 900000 -1173 1428 765 900000 900000 823 1532 -711 1393 156 555 900000 900000 -488 725 718 -1708 900000 900000 -454 2394 2131 2333 2172 900000 4214 -1700 2051 3017 -479 2036 1768 2046 3153 3562 4678 4334 5463 4897 5826 5751 5891 4460 4772 869 1108 2816 3861 85 693 6981 8242 5819 6990 -35396 9152 6733 3160 8234 2094 -2308 2061 822 1673 4922 -80 2327 3764 -863 3226 -251 748 1655 -5706 2247 4058 -3689 3476 -1206 -2032 4815 -5903 2689 -4677 -2313 1397 2318 5224 -2815 1463 1231 -278 3088 -5378 -6167 348 4290 -2534 -1229 -1765 -684 -5842 367 4083 -596 1796 641 1183 2611 2145 -1962 -3443 -4614 8322 4126 -3500 379 3930 1306 4298 -1483 -2112 -273 1610 -824 388 -3887 1278 727 -2087 SS 20230904T113929.4Z 8647.485757 231 1 49.84 2 78.76 89.47 43.42 253.41 0.00 1 0.00 1 0 25 2.684e-01 8.100e-03 7.992e-02 1.984e-03 6.244762e-01 1.045614e-03 7.005433e-03 -6.000000e+00 1.536440e-01 230.17 -2.00 3.43 -2.00 320.71 0.00e+00 2.007454e-03 4.445380e-04 7.366232e-04 -6.000000e+00 6.977886e-03 291.02 -2.00 20.00 -2.00 319.98 0.00e+00 4.949 0.002 302.00 328.00 3 1.8069e+00 3.3966e-03 5.9016e-02 -6.0000e+00 3.8289e-01 4.4716e-02 4.4558e-03 3.2506e-02 -6.0000e+00 4.1462e-01 -9.4123e-02 4.0773e-03 1.6518e-02 -6.0000e+00 2.4767e-01 3.0844e-02 2.0083e-03 5.1734e-03 -6.0000e+00 1.0588e-01 3.3038e-04 -7.7716e-04 5.3947e-05 5.9232e-05 -6.0000e+00 7.1730e-03 3.5534e-03 0.0000e+00 11 8 0 10 0 0 -27.86 20.73 0.46 0.00355 -0.00229 127 25 1 5 0 392.400 24.14 20.01 20.73 32.21 29.9 1017.24 -54418 -162181 -54242 -100282 -50847 -107414 -38933 -82977 -38384 -38323 -107765 56323 -44811 -66212 -32112 -24726 6016 25401 -29246 -14737 -39893 -22711 -23112 -15518 -6735 -5665 -17303 -29135 -10182 -21207 3416 61 -2776 -15214 -3822 -9710 -4982 14949 8241 -33 -1602 4137 -4269 137 -1714 -8 6777 229 -499 4280 3810 3271 4261 2043 5079 2174 3548 -569 2466 103 2732 -1087 787 3691 2709 2444 848 4253 3079 1761 162 1963 -661 -1135 -1036 -1464 -2064 641 -1941 -1470 -567 -2554 -1688 -1511 -641 -718 -809 -127 1063 -204 944 544 145 1104 -599 587 -596 -34 -444 -39 -437 -221 -68 -448 -1276 -772 -811 -539 726 496 185 -121 530 447 368 740 765 120 -123 -643 -557 409 260 107 -251 -755 1310 1541 -11 13 -55 -21 289 47 -298 -512 200 -70 -162 -479 120 -143 439 -347 -3138 -409 -1023 -325 -1134 -256 -890 -327 -348 -1895 251 -638 -1491 -638 -535 107 411 -880 -404 -1431 -695 -764 -524 -225 -197 -679 -1240 -360 -936 142 3 -153 -979 -209 -578 -322 962 700 -4 -198 515 -559 18 -227 -1 864 32 -75 659 661 637 901 479 1222 562 929 -154 629 27 725 -334 251 1276 975 853 298 1507 1240 829 85 1045 -354 -576 -478 -610 -815 253 -892 -798 -332 -1734 -1237 -1172 -496 -593 -703 -113 927 -173 735 424 109 856 -499 559 -624 -41 -540 -49 -521 -236 -71 -481 -1406 -895 -994 -666 970 743 291 -201 869 705 548 1110 1158 182 -199 -1090 -937 658 405 161 -385 -1120 1835 2242 -17 23 -101 -41 563 98 -633 -1150 458 -163 -378 -1082 254 -300 887 SS 20230904T114520.7Z 8647.489823 234 1 50.04 2 77.59 90.36 44.50 254.62 0.00 1 0.00 1 0 25 1.974e-01 7.533e-03 3.570e-02 1.455e-03 5.774788e-01 7.572890e-04 6.525412e-03 -6.000000e+00 1.130320e-01 230.17 -2.00 3.43 -2.00 320.33 0.00e+00 3.308185e-03 2.848529e-04 3.897826e-04 -6.000000e+00 5.133464e-03 291.02 -2.00 20.00 -2.00 319.56 0.00e+00 4.518 0.001 302.00 328.00 3 1.7109e+00 2.3441e-03 5.4085e-02 -6.0000e+00 2.8168e-01 3.9106e-02 2.9504e-03 2.9966e-02 -6.0000e+00 3.0503e-01 -7.1334e-02 2.5674e-03 1.5226e-02 -6.0000e+00 1.8221e-01 1.9291e-02 1.3000e-03 5.7887e-03 -6.0000e+00 7.7890e-02 5.6802e-04 -6.6683e-04 3.9840e-05 5.7179e-05 -6.0000e+00 5.2771e-03 3.5838e-03 0.0000e+00 11 8 0 10 0 0 88.55 20.75 0.36 0.00358 -0.00143 182 36 1 5 0 274.910 24.14 20.02 20.75 32.87 29.7 1017.24 -85576 -97752 -63577 -61824 -64744 -48835 -53963 -63466 -29435 -61599 -70123 -23479 -12126 -40688 -11285 -24992 6382 521 -11344 -5174 -19742 965 -16224 -5691 -9363 6223 -16857 -6104 -15167 -10249 -2033 2746 -4590 -9876 -1318 -5411 931 1693 3494 -2428 -1117 -1004 -75 294 132 1727 3034 1341 1213 4446 2983 3568 3077 2753 3405 1482 968 -545 136 1141 2027 751 2317 2731 2511 1285 1997 -7922 3093 697 582 1010 -414 -233 -723 -149 -1508 515 -1634 -943 -678 -1666 -1560 -1137 -768 -321 -334 -29 652 210 941 198 970 864 -273 12 209 44 -450 -483 -301 -58 345 40 -1500 -825 -1154 -474 419 478 189 128 540 332 322 705 838 120 -5 -619 -577 -101 77 -9 -59 -457 1240 1371 100 37 -72 52 110 324 -318 -364 -7 -44 -160 -331 -149 -139 507 -1159 -1690 -812 -726 -727 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