File name: Pandora37s1_HamptonVA_20231009_L2Fit_fwvt1c3d20201125p1-8.txt File generation date: 20231010T082706.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v3d20201125.txt Level 1 file used: Pandora37s1_HamptonVA_20231009_L1_smca1c3d20201125p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20231009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session1 valid starting from 20201125 First and last pixel inside fitting window: 1680 1831 Nominal wavelengths inside fitting window [nm]: 492.0113 492.1315 492.2517 492.3718 492.4920 492.6121 492.7322 492.8523 492.9724 493.0925 493.2126 493.3326 493.4526 493.5726 493.6926 493.8126 493.9325 494.0525 494.1724 494.2923 494.4122 494.5320 494.6519 494.7717 494.8916 495.0114 495.1311 495.2509 495.3707 495.4904 495.6101 495.7298 495.8495 495.9692 496.0888 496.2085 496.3281 496.4477 496.5673 496.6868 496.8064 496.9259 497.0454 497.1649 497.2844 497.4039 497.5233 497.6427 497.7621 497.8815 498.0009 498.1203 498.2396 498.3590 498.4783 498.5976 498.7168 498.8361 498.9553 499.0746 499.1938 499.3130 499.4321 499.5513 499.6704 499.7896 499.9087 500.0278 500.1468 500.2659 500.3849 500.5039 500.6229 500.7419 500.8609 500.9799 501.0988 501.2177 501.3366 501.4555 501.5744 501.6932 501.8120 501.9308 502.0496 502.1684 502.2872 502.4059 502.5247 502.6434 502.7621 502.8807 502.9994 503.1180 503.2367 503.3553 503.4738 503.5924 503.7110 503.8295 503.9480 504.0665 504.1850 504.3035 504.4219 504.5404 504.6588 504.7772 504.8956 505.0139 505.1323 505.2506 505.3689 505.4872 505.6055 505.7237 505.8420 505.9602 506.0784 506.1966 506.3147 506.4329 506.5510 506.6691 506.7872 506.9053 507.0234 507.1414 507.2595 507.3775 507.4955 507.6134 507.7314 507.8493 507.9673 508.0852 508.2031 508.3209 508.4388 508.5566 508.6744 508.7922 508.9100 509.0278 509.1455 509.2632 509.3810 509.4986 509.6163 509.7340 509.8516 509.9692 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-404: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231009T112556.6Z 8682.476350 207 1 50.81 2 87.25 99.98 30.86 115.98 0.00 1 0.00 1 0 15 4.280e-03 4.266e-03 1.141e-03 1.139e-03 8.987226e+03 7.872192e+01 5.577172e+02 -6.000000e+00 2.460476e+02 287.71 -2.00 20.00 -2.00 505.37 0.00e+00 1.957531e-03 3.215257e-05 1.153145e-04 -6.000000e+00 1.221008e-04 287.71 -2.00 20.00 -2.00 500.78 0.00e+00 1.273377e+00 2.227536e-02 7.019980e-02 -6.000000e+00 8.500587e-02 227.12 -2.00 3.43 -2.00 502.33 0.00e+00 14.078 0.046 489.00 513.00 1 5.9864e+00 1.7121e-03 2.2222e-02 -6.0000e+00 6.5371e-03 -1.8035e-02 4.2972e-04 1.9409e-03 -6.0000e+00 1.6840e-03 5.7662e-04 8.7215e-04 1.1558e-04 6.5235e-05 -6.0000e+00 4.6089e-04 1.3630e-02 4.6382e-04 11 8 0 10 0 0 99.93 20.72 2.42 0.01363 0.01968 18 4 1 4 0 2822.200 24.46 20.01 20.72 15.04 29.1 1014.96 -839 -889 -271 -379 -206 402 87 276 294 590 -77 -146 -314 -209 56 -367 102 183 374 -52 608 438 665 763 491 370 180 -104 -280 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-281 1292 -468 -474 39 139 381 540 795 1276 773 812 620 206 80 44 190 654 282 189 367 405 56 1 23 -216 -205 -304 -207 -115 182 203 -142 414 311 4 60 89 -16 -105 -227 -309 -717 -752 -451 900000 SQ 20231009T113812.3Z 8682.484864 212 1 6.51 2 84.85 101.87 28.76 119.80 0.00 1 0.00 1 0 15 2.515e-03 2.518e-03 1.195e-04 1.194e-04 6.230219e+03 7.924144e+00 3.949413e+02 -6.000000e+00 1.445432e+02 287.71 -2.00 20.00 -2.00 505.32 0.00e+00 1.403043e-03 3.356132e-06 8.451390e-05 -6.000000e+00 7.173429e-05 287.71 -2.00 20.00 -2.00 500.64 0.00e+00 8.618537e-01 2.347407e-03 4.938554e-02 -6.000000e+00 4.996170e-02 227.11 -2.00 3.43 -2.00 502.20 0.00e+00 9.591 0.015 489.00 513.00 1 2.5438e-01 1.8041e-04 1.4645e-02 -6.0000e+00 3.8418e-03 -9.9468e-03 4.5738e-05 1.3259e-03 -6.0000e+00 9.9034e-04 3.5222e-01 8.0328e-04 1.2280e-05 4.8670e-05 -6.0000e+00 2.7082e-04 3.7477e-02 2.8228e-04 10 0 0 10 0 0 0.26 20.72 1.84 0.03748 0.04305 517 104 1 4 0 12.580 24.46 19.98 20.72 15.34 28.8 1015.21 -285 -371 -238 -182 3 288 307 255 308 189 72 -16 -143 -99 -85 -26 17 180 235 165 311 422 372 496 427 229 76 93 -105 -246 -211 -346 -367 -77 -246 -333 -87 5 -97 -107 -20 -38 8 142 227 219 234 158 92 -72 -169 -160 -302 -247 -108 -112 -139 32 136 289 377 338 209 223 166 127 4 -61 -41 -179 -217 -135 -252 -177 -159 -271 -393 -322 -238 -327 -373 -360 -464 -352 -221 -317 -394 -285 -182 -156 -89 -1 33 -76 -143 -27 -106 -199 -136 -237 -350 -280 -240 -95 -191 -335 -253 -90 -38 124 167 97 232 430 516 603 635 594 420 313 336 322 264 440 401 120 208 271 92 196 167 -112 -91 -7 -166 -58 192 -35 -104 108 94 32 147 132 -13 -92 -180 -306 -402 -365 -272 900000 -273 -358 -231 -180 3 291 311 261 314 191 72 -15 -142 -97 -83 -26 17 180 238 169 320 431 380 509 441 237 78 95 -106 -244 -209 -341 -366 -78 -253 -346 -90 5 -100 -109 -20 -38 8 146 234 227 241 161 93 -72 -168 -157 -294 -242 -106 -111 -140 33 138 295 385 343 213 227 168 128 4 -60 -40 -177 -213 -132 -249 -175 -158 -270 -387 -315 -230 -315 -360 -351 -450 -344 -218 -313 -391 -283 -180 -155 -88 -1 33 -76 -142 -27 -104 -191 -129 -224 -329 -266 -229 -93 -189 -334 -252 -90 -37 122 167 97 232 434 525 610 647 609 427 319 337 322 262 439 398 120 209 272 92 196 166 -111 -90 -7 -162 -57 189 -35 -104 108 95 32 150 135 -13 -94 -184 -310 -405 -363 -271 900000 SQ 20231009T113818.9Z 8682.484941 212 2 6.61 2 84.83 101.88 28.74 119.84 0.00 1 0.00 1 0 15 2.544e-03 2.547e-03 1.189e-04 1.188e-04 6.199071e+03 7.870756e+00 3.917252e+02 -6.000000e+00 1.462338e+02 287.71 -2.00 20.00 -2.00 505.31 0.00e+00 1.394849e-03 3.339980e-06 8.437657e-05 -6.000000e+00 7.257295e-05 287.71 -2.00 20.00 -2.00 500.63 0.00e+00 8.586305e-01 2.336041e-03 4.937324e-02 -6.000000e+00 5.054462e-02 227.11 -2.00 3.43 -2.00 502.20 0.00e+00 9.561 0.014 489.00 513.00 1 2.4900e-01 1.7953e-04 1.4601e-02 -6.0000e+00 3.8866e-03 -9.8462e-03 4.5517e-05 1.3218e-03 -6.0000e+00 1.0019e-03 3.5578e-01 8.0694e-04 1.2203e-05 4.8219e-05 -6.0000e+00 2.7399e-04 3.4073e-02 3.0514e-04 10 0 0 10 0 0 9.49 20.72 1.84 0.03407 0.03967 517 104 1 4 0 12.580 24.46 19.98 20.72 15.42 28.9 1015.21 -295 -344 -219 -176 -7 309 330 270 311 201 99 -30 -142 -92 -113 -8 31 184 208 127 309 435 376 504 431 229 77 83 -115 -228 -220 -358 -342 -83 -256 -352 -109 3 -97 -123 -19 -25 21 142 213 242 237 128 76 -49 -179 -151 -292 -244 -103 -140 -121 22 165 312 349 329 215 211 185 104 7 -75 -68 -175 -196 -171 -240 -194 -145 -288 -405 -306 -221 -326 -409 -380 -466 -362 -212 -352 -390 -269 -169 -168 -110 -36 5 -98 -96 -42 -106 -191 -124 -255 -357 -282 -252 -106 -174 -360 -250 -101 -35 126 198 116 222 421 541 636 661 615 414 325 347 316 267 466 402 146 230 261 81 175 144 -115 -100 -11 -150 -38 170 -45 -96 128 96 49 126 111 -5 -112 -166 -292 -393 -338 -278 900000 -280 -329 -214 -175 -7 313 336 277 319 204 100 -30 -142 -91 -112 -8 31 186 212 129 316 446 386 519 442 235 79 84 -116 -227 -216 -355 -342 -85 -265 -363 -112 3 -98 -125 -19 -26 22 146 219 249 243 131 77 -49 -178 -147 -285 -237 -101 -140 -122 23 167 316 354 334 220 216 188 104 7 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