File name: Pandora37s1_HamptonVA_20240417_L2Fit_fout2c3d20201125p1-8.txt File generation date: 20240418T050906.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v3d20201125.txt Level 1 file used: Pandora37s1_HamptonVA_20240417_L1_smca1c3d20201125p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20240417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session1 valid starting from 20201125 First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.0545 305.1949 305.3354 305.4758 305.6162 305.7565 305.8969 306.0373 306.1776 306.3180 306.4583 306.5986 306.7389 306.8792 307.0195 307.1597 307.3000 307.4402 307.5805 307.7207 307.8609 308.0011 308.1413 308.2814 308.4216 308.5618 308.7019 308.8420 308.9821 309.1222 309.2623 309.4024 309.5425 309.6825 309.8226 309.9626 310.1026 310.2427 310.3827 310.5226 310.6626 310.8026 310.9425 311.0825 311.2224 311.3623 311.5022 311.6421 311.7820 311.9219 312.0617 312.2016 312.3414 312.4812 312.6210 312.7608 312.9006 313.0404 313.1802 313.3199 313.4597 313.5994 313.7391 313.8788 314.0185 314.1582 314.2979 314.4375 314.5772 314.7168 314.8564 314.9960 315.1356 315.2752 315.4148 315.5544 315.6939 315.8334 315.9730 316.1125 316.2520 316.3915 316.5310 316.6704 316.8099 316.9493 317.0888 317.2282 317.3676 317.5070 317.6464 317.7858 317.9251 318.0645 318.2038 318.3431 318.4824 318.6218 318.7610 318.9003 319.0396 319.1788 319.3181 319.4573 319.5965 319.7357 319.8749 320.0141 320.1533 320.2925 320.4316 320.5707 320.7099 320.8490 320.9881 321.1272 321.2662 321.4053 321.5444 321.6834 321.8224 321.9614 322.1004 322.2394 322.3784 322.5174 322.6563 322.7953 322.9342 323.0731 323.2120 323.3509 323.4898 323.6287 323.7676 323.9064 324.0452 324.1841 324.3229 324.4617 324.6005 324.7392 324.8780 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240417T113259.3Z 8873.481242 156 1 49.98 2 78.01 85.51 121.18 340.62 0.00 1 0.00 1 0 27 4.558e-01 1.501e-02 2.024e-01 3.615e-03 7.202742e-01 1.934155e-03 8.120366e-03 -6.000000e+00 2.600664e-01 229.26 -2.00 3.43 -2.00 321.09 0.00e+00 5.471253e-03 8.879098e-04 1.885245e-03 -6.000000e+00 1.176535e-02 283.24 -2.00 20.00 -2.00 320.51 0.00e+00 4.666 0.002 302.00 328.00 3 2.9351e+00 6.4029e-03 6.0208e-02 -6.0000e+00 6.4849e-01 1.6980e-01 8.6242e-03 3.8204e-02 -6.0000e+00 7.0363e-01 -2.8802e-01 8.4564e-03 2.1214e-02 -6.0000e+00 4.1859e-01 1.1489e-01 4.0688e-03 8.1439e-03 -6.0000e+00 1.7833e-01 1.1931e-04 -1.4015e-03 9.5498e-05 1.0314e-04 -6.0000e+00 1.2177e-02 6.4972e-02 -1.0916e-05 12 8 8 10 0 0 94.08 21.23 0.42 0.06497 0.05444 48 10 1 5 0 1041.140 25.28 19.99 21.23 24.46 30.7 1022.14 -197922 -257120 -76585 -48119 -142922 -1479 -36504 -102785 -45398 204376 -178827 900000 131522 -74429 -62450 -59793 -18191 38693 -51166 -31867 -27261 -17799 3888 -16411 -9319 91267 -34946 -28243 -56018 -35538 20542 15624 -5438 -3149 14018 13809 16222 54462 13625 2057 6580 17533 6584 3620 76 -3129 17082 666 8876 16476 5278 8417 5257 16622 9201 8253 53 -648 -1642 3372 4875 2756 3556 4550 8225 2535 2236 19189 10439 1741 2468 4501 -2348 -2227 -867 -3080 -3753 2596 -3625 -2621 192 -2069 -2528 -981 -923 -298 -1706 -1430 643 -507 198 -1487 -714 1726 -2110 202 -490 -1097 -414 203 -1053 -1033 6 -593 -1314 -408 -1778 -846 304 776 -519 -234 -36 609 524 743 1374 287 287 -242 -18 572 716 415 -179 -141 2317 1999 171 111 88 155 252 -439 -672 -393 92 165 -273 -78 49 -344 -212 -3787 -9486 -561 -248 -1619 -5 -168 -1031 -283 720 -4413 900000 464 -1349 -1274 -1415 -321 462 -1494 -802 -659 -390 72 -405 -228 916 -1153 -846 -2257 -1333 543 523 -243 -143 544 542 698 1920 826 165 561 1434 631 343 8 -333 1634 74 960 1797 726 1257 890 2728 1715 1613 11 -139 -345 666 993 642 890 1274 2325 743 657 4981 3318 697 1073 1982 -1082 -957 -332 -1082 -1257 847 -1444 -1241 98 -1239 -1663 -674 -641 -219 -1333 -1142 501 -383 146 -1046 -484 1195 -1636 179 -485 -1256 -489 249 -1225 -1075 6 -591 -1351 -439 -2051 -1040 389 1116 -806 -385 -60 972 794 1079 1999 442 469 -413 -30 913 1099 617 -269 -205 3175 2867 272 192 168 303 521 -933 -1533 -942 216 392 -651 -186 110 -748 -442 SS 20240417T113805.6Z 8873.484787 159 1 50.03 2 76.99 86.26 121.51 341.92 0.00 1 0.00 1 0 25 3.791e-01 1.711e-02 2.058e-01 3.912e-03 6.737075e-01 2.081236e-03 7.576821e-03 -6.000000e+00 2.162059e-01 229.26 -2.00 3.43 -2.00 320.97 0.00e+00 4.063707e-03 9.104749e-04 1.194624e-03 -6.000000e+00 9.773219e-03 283.24 -2.00 20.00 -2.00 320.37 0.00e+00 4.327 0.001 302.00 328.00 3 3.3525e+00 6.7823e-03 5.5897e-02 -6.0000e+00 5.3911e-01 1.1533e-01 8.9750e-03 3.5448e-02 -6.0000e+00 5.8507e-01 -2.0796e-01 8.5799e-03 1.8824e-02 -6.0000e+00 3.4806e-01 8.3536e-02 4.1695e-03 6.4769e-03 -6.0000e+00 1.4820e-01 1.1425e-04 -1.9923e-03 1.0646e-04 7.8502e-05 -6.0000e+00 1.0133e-02 6.5942e-02 -1.2622e-04 12 8 8 10 0 0 99.99 21.23 0.43 0.06594 0.05097 62 12 1 5 0 806.920 25.28 20.01 21.23 24.66 30.7 1022.19 -153166 -208094 -69572 -70343 14616 -10917 51648 -186830 21622 -86244 -142016 900000 83025 -75502 -21721 -37132 -14262 64038 -55448 3223 -24904 101246 -17258 2080 -38201 53306 -56825 -22470 -30162 -15747 18223 2935 -4142 -14878 6227 -5682 30665 25927 19192 1825 3802 6434 2984 3649 -2320 -149 16004 7167 -2147 16202 2933 9628 2786 7229 4515 7061 1606 -2902 -606 -918 5680 -4182 5154 2604 7006 -248 1470 73621 7462 3204 224 4803 -1362 225 -940 -112 -4722 3191 -3746 -1297 -549 -3940 -3305 -1459 -613 -1410 -970 -1963 839 -815 1484 -1258 339 1652 -1089 681 -256 -804 -1396 397 -1196 -750 -572 -286 -1859 343 -1525 -900 483 1263 -360 -422 993 406 865 642 1348 -602 70 113 -641 768 616 86 -349 -83 1695 1913 -370 336 260 -166 73 -116 -541 -455 259 207 -230 -290 81 -554 141 -2483 -6257 -619 -590 56 -47 197 -5157 93 -1090 -3123 900000 338 -1711 -383 -903 -309 749 -2028 73 -710 927 -484 56 -1534 953 -2722 -782 -1144 -583 585 131 -216 -895 288 -300 1342 1352 1314 166 377 664 334 415 -285 -18 1722 878 -289 2066 455 1563 530 1428 966 1531 377 -703 -139 -209 1265 -1092 1402 817 2186 -81 469 12483 2614 1350 102 2154 -636 97 -389 -41 -1716 1103 -1579 -608 -299 -2530 -2202 -1010 -450 -1111 -799 -1675 693 -657 1087 -886 237 1185 -867 620 -261 -908 -1724 480 -1371 -799 -556 -280 -1991 379 -1743 -1096 637 1785 -574 -688 1599 659 1320 941 1973 -941 116 187 -1055 1244 962 130 -510 -122 2346 2741 -589 580 493 -326 150 -244 -1226 -1049 605 494 -550 -666 181 -1164 292 SS 20240417T114412.8Z 8873.489037 162 1 49.61 2 75.77 87.17 121.87 343.48 0.00 1 0.00 1 0 17 2.745e-01 3.179e-02 1.112e-01 3.038e-03 6.292231e-01 1.593173e-03 6.959703e-03 -6.000000e+00 1.568273e-01 229.26 -2.00 3.43 -2.00 320.51 0.00e+00 1.344238e-02 6.136598e-04 2.549752e-03 -6.000000e+00 7.103649e-03 283.24 -2.00 20.00 -2.00 319.88 0.00e+00 3.980 0.001 302.00 328.00 3 3.3258e+00 4.8495e-03 5.6337e-02 -6.0000e+00 3.9110e-01 2.2021e-01 6.1639e-03 4.6997e-02 -6.0000e+00 4.2412e-01 -1.9860e-01 5.7808e-03 2.0099e-02 -6.0000e+00 2.5230e-01 5.2337e-02 2.8982e-03 2.0058e-02 -6.0000e+00 1.0768e-01 1.5637e-04 4.2802e-04 8.1420e-05 1.3478e-04 -6.0000e+00 7.3245e-03 6.0767e-02 2.6475e-04 12 8 8 10 0 0 99.88 21.23 0.33 0.06077 0.06398 47 9 1 5 0 1055.280 25.28 20.01 21.23 24.96 30.7 1021.85 -109968 -129649 -89938 -27683 -61067 98726 -87530 -69397 -71627 -45143 -125632 900000 16856 -45919 21526 -26158 -3504 9953 -2577 -12062 25008 -12482 22460 -14207 -12873 26113 -39661 -8507 -28670 471 6759 18312 2060 3748 7686 12743 9627 27554 12288 -4543 142 2190 5736 -3342 8193 1603 15574 9859 13071 18737 9590 11162 9889 12413 7156 6321 -427 -87 -1709 1632 6497 3219 6650 6918 10331 5786 6025 -52041 11356 4117 3883 3165 755 -895 1038 -924 -2629 4241 -191 878 1503 915 -96 1189 -614 1075 -618 75 1739 793 1746 -547 232 1207 -930 958 928 562 696 1404 609 106 663 -936 -1885 -437 -1453 -777 -153 1039 -204 -392 57 197 -68 372 1021 156 166 -852 -862 -199 -22 -557 -706 -541 939 1407 -403 291 534 -113 751 2 -565 -429 -29 239 -289 112 397 -375 246 -1973 -3093 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