File name: Pandora37s1_HamptonVA_20240612_L2Fit_fout2c3d20201125p1-8.txt File generation date: 20240613T051446.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v3d20201125.txt Level 1 file used: Pandora37s1_HamptonVA_20240612_L1_smca1c3d20201125p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20240612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session1 valid starting from 20201125 First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.0545 305.1949 305.3354 305.4758 305.6162 305.7565 305.8969 306.0373 306.1776 306.3180 306.4583 306.5986 306.7389 306.8792 307.0195 307.1597 307.3000 307.4402 307.5805 307.7207 307.8609 308.0011 308.1413 308.2814 308.4216 308.5618 308.7019 308.8420 308.9821 309.1222 309.2623 309.4024 309.5425 309.6825 309.8226 309.9626 310.1026 310.2427 310.3827 310.5226 310.6626 310.8026 310.9425 311.0825 311.2224 311.3623 311.5022 311.6421 311.7820 311.9219 312.0617 312.2016 312.3414 312.4812 312.6210 312.7608 312.9006 313.0404 313.1802 313.3199 313.4597 313.5994 313.7391 313.8788 314.0185 314.1582 314.2979 314.4375 314.5772 314.7168 314.8564 314.9960 315.1356 315.2752 315.4148 315.5544 315.6939 315.8334 315.9730 316.1125 316.2520 316.3915 316.5310 316.6704 316.8099 316.9493 317.0888 317.2282 317.3676 317.5070 317.6464 317.7858 317.9251 318.0645 318.2038 318.3431 318.4824 318.6218 318.7610 318.9003 319.0396 319.1788 319.3181 319.4573 319.5965 319.7357 319.8749 320.0141 320.1533 320.2925 320.4316 320.5707 320.7099 320.8490 320.9881 321.1272 321.2662 321.4053 321.5444 321.6834 321.8224 321.9614 322.1004 322.2394 322.3784 322.5174 322.6563 322.7953 322.9342 323.0731 323.2120 323.3509 323.4898 323.6287 323.7676 323.9064 324.0452 324.1841 324.3229 324.4617 324.6005 324.7392 324.8780 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240612T103417.7Z 8929.440483 63 1 50.01 2 82.07 66.84 129.44 9.70 0.00 1 0.00 1 0 17 5.628e-01 2.504e-02 3.086e-01 6.520e-03 9.329022e-01 3.745709e-03 1.104283e-02 -6.000000e+00 3.301349e-01 232.73 -2.00 3.43 -2.00 322.01 0.00e+00 1.980784e-02 2.253766e-03 2.803920e-03 -6.000000e+00 1.588365e-02 288.70 -2.00 20.00 -2.00 321.51 0.00e+00 6.765 0.005 302.00 328.00 3 1.3523e+00 1.5101e-02 8.4721e-02 -6.0000e+00 8.2790e-01 9.3026e-01 2.1068e-02 5.5084e-02 -6.0000e+00 8.9674e-01 -1.1837e+00 1.9193e-02 2.8662e-02 -6.0000e+00 5.3215e-01 4.6692e-01 8.7410e-03 2.0490e-02 -6.0000e+00 2.2514e-01 5.3990e-05 -2.1373e-03 1.6477e-04 3.0838e-04 -6.0000e+00 1.5774e-02 6.5768e-02 -8.6415e-06 12 8 8 10 0 0 15.51 21.13 0.52 0.06577 0.04971 56 11 1 5 0 892.870 25.17 20.01 21.13 25.84 31.7 1019.78 -123967 -229797 -26640 900000 216990 900000 63771 -136056 20147 -80738 -190522 900000 115494 -68759 -4178 -33816 -13455 900000 -5674 -10985 -32383 105597 94075 18704 -51472 900000 -82619 5554 359 34672 135029 110519 45538 30163 69328 126086 98509 900000 181069 46568 37741 121025 59556 30318 9394 26657 130343 55804 40800 105209 61626 43527 36762 63260 50519 40666 19062 21712 -6067 15291 14271 4252 23461 28396 44573 14795 26161 -26409 45985 20756 10816 22625 1275 387 7701 -218 -797 17105 -4616 -1860 6093 1312 2127 2221 1340 87 -5053 -3662 1899 -204 642 -5314 -2052 2657 -7380 2334 -3089 -4791 -374 -15 -1045 -2456 -1453 -2668 -2078 -736 -3498 -3932 -1440 1902 -1135 -899 -277 -373 -805 -321 2655 135 481 446 1004 1009 2850 652 -188 76 3852 2405 -161 981 996 320 874 -724 -962 -42 443 236 -220 -419 605 -663 -1764 -2296 -12686 -211 900000 1378 900000 405 -2088 128 -684 -4941 900000 734 -1274 -53 -698 -256 900000 -114 -233 -806 671 652 247 -1335 900000 -2799 76 6 500 936 1212 1012 798 1137 1238 1365 900000 1464 1503 1438 2306 2017 1412 552 1369 2709 2392 2181 3230 3294 3110 2820 4319 3727 3338 1928 2058 -723 1449 1436 536 2865 3815 5444 2429 3898 -6529 6650 4115 2566 4865 326 91 1495 -44 -155 2983 -1106 -535 1935 506 896 987 637 41 -2632 -1923 937 -105 307 -2555 -946 1259 -4231 1465 -2449 -4550 -354 -16 -1001 -2109 -1099 -2014 -1667 -617 -3205 -3954 -1496 2224 -1571 -1355 -427 -569 -1189 -460 3750 206 775 696 1612 1528 4044 917 -257 100 4799 3234 -259 1729 1985 701 1929 -1746 -2502 -108 1155 622 -580 -1113 1471 -1503 -3839 SS 20240612T105212.4Z 8929.452921 68 1 49.82 2 78.76 69.32 128.77 15.03 0.00 1 0.00 1 0 37 4.233e-01 1.476e-02 1.997e-01 4.355e-03 7.315550e-01 2.397443e-03 8.259048e-03 -6.000000e+00 2.454609e-01 232.73 -2.00 3.43 -2.00 321.28 0.00e+00 4.539671e-03 1.184696e-03 2.501751e-03 -6.000000e+00 1.158371e-02 288.70 -2.00 20.00 -2.00 320.66 0.00e+00 4.951 0.002 302.00 328.00 3 2.7267e+00 8.4197e-03 6.3597e-02 -6.0000e+00 6.1549e-01 1.6489e-01 1.1542e-02 4.0557e-02 -6.0000e+00 6.6551e-01 -2.3899e-01 1.0957e-02 2.1644e-02 -6.0000e+00 3.9570e-01 9.7893e-02 5.1810e-03 7.0718e-03 -6.0000e+00 1.6876e-01 1.0962e-04 -1.3724e-03 1.1786e-04 1.0016e-04 -6.0000e+00 1.1419e-02 6.4729e-02 -1.0554e-05 12 8 8 10 0 0 99.98 21.21 0.32 0.06473 0.05442 93 19 1 5 0 535.610 25.17 20.02 21.21 28.52 31.7 1019.85 -106593 -270037 900000 -3944 900000 -99885 -37809 -183583 -83655 -60274 -200287 900000 -6889 -84505 -81545 -70785 -11637 97379 -59235 8857 -41105 53130 -47211 -31852 -37054 37001 -38403 -13630 -18096 -45121 -874 -22885 -6477 -21981 17291 -5204 47513 51813 41839 3312 9388 22496 10624 14627 5841 9121 18239 15990 6164 23916 7761 7841 9753 12284 16379 4119 4383 -709 635 -1040 8910 -912 428 5605 9947 717 2878 8479 12125 3294 1950 5481 -3239 -678 -1749 995 -3411 6155 -1999 -328 620 -4030 -2843 -1411 -641 -2285 -1203 -2221 533 -457 232 -2402 -794 2304 -2365 1457 -1144 -1470 -379 31 -1389 -644 54 -151 -1425 -40 -1622 -741 433 1118 115 -368 900 615 595 235 1335 -92 -232 305 -277 748 962 -19 -454 -411 1541 1750 -407 79 416 -400 288 -146 -587 -488 269 42 -23 -185 166 -430 18 -719 -8679 900000 -17 900000 -673 -160 -3199 -668 -406 -5235 900000 -46 -1534 -1731 -1613 -176 620 -1641 138 -1010 570 -1318 -833 -1093 576 -1149 -326 -461 -1638 -27 -996 -278 -1093 580 -222 1422 1704 1874 235 699 1576 843 1194 508 791 1491 1405 635 2251 931 1057 1420 1901 2575 733 798 -134 115 -189 1535 -194 99 1400 2493 193 761 2225 3450 1140 750 2108 -1330 -254 -622 309 -1047 1783 -721 -135 297 -2233 -1706 -885 -427 -1648 -870 -1664 400 -332 156 -1560 -493 1452 -1777 1191 -1119 -1607 -447 36 -1542 -635 50 -141 -1446 -40 -1780 -867 535 1550 174 -597 1453 967 887 349 1975 -140 -375 509 -459 1174 1448 -29 -664 -579 2058 2434 -638 140 788 -796 600 -316 -1367 -1164 651 104 -57 -449 377 -942 38 SS 20240612T105815.8Z 8929.457128 71 1 25.26 2 77.63 70.15 128.47 16.80 0.00 1 0.00 1 0 25 3.365e-01 2.158e-02 2.389e-01 8.797e-03 6.822146e-01 4.703989e-03 7.652462e-03 -6.000000e+00 1.956542e-01 232.73 -2.00 3.43 -2.00 320.78 0.00e+00 -7.877743e-04 1.903994e-03 1.639320e-03 -6.000000e+00 8.687507e-03 288.70 -2.00 20.00 -2.00 320.08 0.00e+00 4.532 0.001 302.00 328.00 3 3.8263e+00 1.5099e-02 5.8444e-02 -6.0000e+00 4.9191e-01 3.6888e-01 1.9070e-02 3.7497e-02 -6.0000e+00 5.3248e-01 -4.3533e-01 1.6082e-02 1.7536e-02 -6.0000e+00 3.1656e-01 1.7209e-01 7.9772e-03 5.1679e-03 -6.0000e+00 1.3369e-01 5.4000e-05 -1.1065e-03 2.3606e-04 5.6474e-05 -6.0000e+00 8.9953e-03 6.2789e-02 3.6374e-05 12 9 9 12 33 1 98.65 21.23 0.28 0.06279 0.05447 6 3 1 5 0 3608.460 25.28 20.01 21.23 29.00 31.5 1019.21 -111179 49748 -160225 117370 -155254 16590 -5243 -106382 -42409 2885 -69032 -1754 -1155 94557 -54388 -33730 -59914 900000 -59565 -33127 -25904 36497 -23851 -38658 -22136 98541 -63774 54092 -26398 -3298 -11704 -1019 -6384 18557 6620 42340 52026 48190 19412 8158 9736 13072 21596 6155 8905 -4994 36057 9944 3242 24127 8394 -2101 7395 23201 13340 9490 3640 1091 -6641 -2110 12011 -4055 3799 3430 15917 4102 4924 -11288 17880 2690 1961 6424 1962 -39 -3009 -4150 -2700 11146 -6406 -2846 -691 -3668 -1875 -2511 -2527 319 -3837 -1053 542 249 473 -4706 201 -4115 -3862 1091 218 -581 -262 2047 -2089 -2551 -1531 72 -363 -242 -1407 2478 -441 2047 -131 -347 1185 -12 838 -313 2211 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