File name: Pandora37s1_HamptonVA_20240707_L2Fit_fout2c3d20201125p1-8.txt File generation date: 20240708T051950.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v3d20201125.txt Level 1 file used: Pandora37s1_HamptonVA_20240707_L1_smca1c3d20201125p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20240707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session1 valid starting from 20201125 First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.0545 305.1949 305.3354 305.4758 305.6162 305.7565 305.8969 306.0373 306.1776 306.3180 306.4583 306.5986 306.7389 306.8792 307.0195 307.1597 307.3000 307.4402 307.5805 307.7207 307.8609 308.0011 308.1413 308.2814 308.4216 308.5618 308.7019 308.8420 308.9821 309.1222 309.2623 309.4024 309.5425 309.6825 309.8226 309.9626 310.1026 310.2427 310.3827 310.5226 310.6626 310.8026 310.9425 311.0825 311.2224 311.3623 311.5022 311.6421 311.7820 311.9219 312.0617 312.2016 312.3414 312.4812 312.6210 312.7608 312.9006 313.0404 313.1802 313.3199 313.4597 313.5994 313.7391 313.8788 314.0185 314.1582 314.2979 314.4375 314.5772 314.7168 314.8564 314.9960 315.1356 315.2752 315.4148 315.5544 315.6939 315.8334 315.9730 316.1125 316.2520 316.3915 316.5310 316.6704 316.8099 316.9493 317.0888 317.2282 317.3676 317.5070 317.6464 317.7858 317.9251 318.0645 318.2038 318.3431 318.4824 318.6218 318.7610 318.9003 319.0396 319.1788 319.3181 319.4573 319.5965 319.7357 319.8749 320.0141 320.1533 320.2925 320.4316 320.5707 320.7099 320.8490 320.9881 321.1272 321.2662 321.4053 321.5444 321.6834 321.8224 321.9614 322.1004 322.2394 322.3784 322.5174 322.6563 322.7953 322.9342 323.0731 323.2120 323.3509 323.4898 323.6287 323.7676 323.9064 324.0452 324.1841 324.3229 324.4617 324.6005 324.7392 324.8780 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240707T105730.7Z 8954.456605 67 1 48.72 2 79.12 69.93 93.56 57.26 0.00 1 0.00 1 0 25 5.788e-01 7.059e-02 2.839e-01 8.050e-03 6.514927e-01 4.488187e-03 8.826730e-03 -6.000000e+00 3.450852e-01 232.63 -2.00 3.43 -2.00 321.05 0.00e+00 6.069643e-02 2.044560e-03 1.790036e-03 -6.000000e+00 1.846876e-02 290.93 -2.00 20.00 -2.00 320.37 0.00e+00 5.100 0.002 302.00 328.00 3 3.3779e+00 1.4877e-02 8.3524e-02 -6.0000e+00 8.7080e-01 9.4206e-01 1.9108e-02 9.8136e-02 -6.0000e+00 9.4618e-01 -6.8794e-01 1.6964e-02 5.2510e-02 -6.0000e+00 5.5564e-01 1.8659e-01 8.3514e-03 6.9823e-02 -6.0000e+00 2.3471e-01 3.3903e-05 -2.2155e-03 2.1669e-04 6.5557e-04 -6.0000e+00 1.6278e-02 6.2758e-02 3.5078e-05 12 9 8 11 32 0 89.17 21.01 0.87 0.06276 0.04611 13 3 1 5 0 3747.480 24.65 20.00 21.01 33.80 32.9 1016.87 103506 -138776 38042 900000 96948 900000 900000 22152 900000 -8016 900000 900000 900000 900000 202114 27108 900000 900000 54635 19431 39055 201504 180348 -48604 71748 900000 -59940 -40831 -11889 84843 134186 187812 17834 81363 182896 235257 53401 30854 127910 -15672 1183 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-4984 -159 1922 -431 4006 -2724 -434 -4528 -5360 4468 2549 -1185 6634 6438 5058 971 736 665 -7092 449 -5258 -7583 -25 6841 -371 400 -1362 -1365 -5022 -2776 4351 1281 -356 551 -22 -9 586 -2714 -114 -645 6065 560 -2524 1534 -1045 474 2466 -1693 -1669 -3064 3579 633 33 -1622 2460 964 -2163 SS 20240707T112317.8Z 8954.474511 73 1 27.97 2 74.24 73.44 89.34 61.08 0.00 1 0.00 1 0 25 1.065e-01 1.184e-02 4.017e-02 2.636e-03 4.820159e-01 1.361769e-03 5.513736e-03 -6.000000e+00 6.156894e-02 232.63 -2.00 3.43 -2.00 319.57 0.00e+00 6.577399e-04 3.892658e-04 4.592037e-04 -6.000000e+00 2.767814e-03 290.93 -2.00 20.00 -2.00 318.73 0.00e+00 3.616 0.001 302.00 328.00 3 3.2472e+00 3.9345e-03 4.4159e-02 -6.0000e+00 1.5438e-01 8.2708e-03 4.6698e-03 2.5186e-02 -6.0000e+00 1.6680e-01 -5.3764e-02 3.5984e-03 1.2197e-02 -6.0000e+00 9.9419e-02 2.0776e-02 1.8830e-03 3.3211e-03 -6.0000e+00 4.2333e-02 3.2037e-04 -8.8431e-04 7.3762e-05 3.5732e-05 -6.0000e+00 2.8462e-03 6.1230e-02 4.1693e-05 12 9 9 12 1 1 83.64 21.05 0.31 0.06123 0.05459 26 10 1 5 0 1035.700 24.65 20.01 21.05 35.04 32.7 1016.95 4576 -82587 9971 -23082 -11310 -42440 9365 -14391 -542 -19151 -34062 43920 -15277 7669 3369 -3694 -5395 13898 -5637 -4793 -14935 -52 1999 -14558 4105 5904 -7147 -10183 1045 -12528 9803 -3630 -18 -9257 -6969 -1714 -955 6156 1968 -149 -4066 1778 -519 -384 -767 1055 285 441 -389 1241 1734 369 2020 -1237 3161 41 819 -253 523 1110 961 -113 317 1734 151 1179 -54 21709 2839 913 -506 1026 -1749 -42 -580 -961 -1150 257 -204 -1841 -955 -3040 -2121 -1820 -901 -805 -761 -347 1097 281 893 255 308 1768 -13 881 -110 -611 -523 -779 -807 -692 692 98 -759 -803 -749 -987 372 521 322 -331 382 325 326 858 846 648 -117 -388 -823 283 -186 250 198 28 1366 1717 -13 280 64 -357 370 120 -441 -526 346 158 -287 -271 -65 -274 -126 72 -3153 170 -497 -203 -1022 156 -338 -12 -548 -1143 813 -576 282 152 -200 -320 743 -382 -337 -1171 -4 143 -1308 332 491 -669 -935 84 -1213 877 -416 -2 -1276 -894 -212 -131 936 374 -33 -1031 451 -139 -104 -210 289 79 123 -111 367 555 130 749 -502 1286 18 359 -111 224 471 423 -54 166 967 86 641 -29 9847 1629 594 -358 739 -1277 -29 -378 -578 -651 143 -123 -1269 -728 -2574 -1891 -1685 -873 -818 -804 -373 1169 293 880 239 277 1578 -13 927 -127 -774 -695 -1032 -1025 -822 775 112 -923 -1016 -980 -1347 527 784 512 -542 617 508 488 1238 1222 965 -183 -629 -1345 453 -292 382 295 40 1911 2426 -19 454 109 -629 662 223 -853 -1053 700 324 -593 -550 -128 -524 -236 SS 20240707T113629.5Z 8954.483675 76 1 50.69 2 71.71 75.21 87.12 62.98 0.00 1 0.00 1 0 25 2.983e-01 1.864e-02 7.178e-02 3.909e-03 4.231361e-01 2.008406e-03 4.864242e-03 -6.000000e+00 1.724511e-01 232.63 -2.00 3.43 -2.00 319.36 0.00e+00 3.109375e-04 5.260437e-04 1.558814e-04 -6.000000e+00 7.752108e-03 290.93 -2.00 20.00 -2.00 318.50 0.00e+00 3.145 0.000 302.00 328.00 3 4.9222e+00 5.7547e-03 3.8499e-02 -6.0000e+00 4.3242e-01 3.0943e-02 6.7397e-03 2.2018e-02 -6.0000e+00 4.6719e-01 -5.1377e-02 4.8650e-03 1.0641e-02 -6.0000e+00 2.7846e-01 2.1166e-02 2.5518e-03 2.9208e-03 -6.0000e+00 1.1858e-01 9.9210e-05 -8.6823e-04 1.1150e-04 3.0894e-05 -6.0000e+00 7.9717e-03 6.0998e-02 4.5350e-05 12 9 8 11 32 0 97.12 21.07 0.41 0.06100 0.05447 16 3 1 5 0 3167.450 24.65 20.01 21.07 35.71 32.6 1016.58 -26878 -87148 -7131 16850 -2061 54879 23796 -8160 101623 -19014 23709 198656 14054 -1541 9478 -8992 11947 22409 -17727 -5525 -10553 7642 4792 -14618 -3072 19908 -16547 -8121 -9294 -5163 9527 6362 -7901 -3734 4991 4906 -356 11142 11962 -4746 -940 -752 1641 -434 56 -3572 3009 650 75 4743 -715 1381 2657 1718 3496 4255 433 -1710 -1002 1508 1498 -1725 -1534 639 2179 935 1886 233509 6547 1960 -706 2414 -1200 -2007 -801 -1589 227 2742 -2981 -1599 -1767 -3945 -2381 -1016 -915 -1022 -2395 -164 2013 -427 1004 -667 1073 2887 -1187 1820 1133 -1255 -196 285 -329 -909 -344 817 -421 200 -1063 -1718 661 1781 433 -141 575 578 -631 20 125 -50 -324 -644 -605 -17 403 -130 -531 1101 2177 1942 -868 223 6 -168 248 -226 -614 -429 928 670 320 -303 -597 -552 -415 -882 -5417 -218 386 -52 826 520 -270 1375 -802 687 1285 572 -85 554 -694 810 1467 -1773 -515 -1044 640 433 -1703 -342 1864 -2161 -929 -1036 -577 1036 798 -1249 -579 674 669 -57 1888 2421 -1295 -269 -226 498 -136 17 -1162 919 203 24 1498 -256 526 1066 737 1535 1910 205 -822 -469 687 706 -903 -877 385 1303 536 1031 15490 3752 1310 -520 1792 -911 -1476 -544 -993 130 1516 -1858 -1112 -1375 -3424 -2167 -953 -907 -1071 -2644 -182 2200 -461 1012 -639 961 2544 -1153 1899 1307 -1609 -263 378 -417 -1080 -387 929 -513 253 -1410 -2388 947 2692 696 -232 932 901 -942 29 179 -74 -502 -1042 -989 -28 632 -199 -788 1565 2969 2679 -1301 354 10 -290 435 -410 -1169 -848 1848 1356 652 -609 -1165 -1044 -769 SS 20240707T122125.8Z 8954.514882 94 1 49.80 2 62.95 81.24 79.26 69.15 0.00 1 0.00 1 0 25 1.842e-02 7.781e-03 6.859e-03 1.795e-03 3.015353e-01 9.163461e-04 3.530194e-03 -6.000000e+00 1.065828e-02 232.63 -2.00 3.43 -2.00 317.73 0.00e+00 1.894888e-04 1.492679e-04 1.420686e-04 -6.000000e+00 4.785690e-04 290.93 -2.00 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