File name: Pandora37s1_HamptonVA_20240912_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T212531.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20240912_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20240912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240912T112053.9Z 9021.472846 48 1 49.39 2 83.83 89.79 168.51 313.70 0.00 1 0.00 1 0 33 8.609e-01 8.830e-02 2.744e-01 1.958e-02 9.499361e-01 1.113181e-02 1.062989e-02 -6.000000e+00 5.018177e-01 229.53 -2.00 3.43 -2.00 321.81 0.00e+00 2.614780e-02 4.526853e-03 1.455108e-02 -6.000000e+00 2.629979e-02 290.45 -2.00 20.00 -2.00 321.13 0.00e+00 8.336 0.010 302.00 328.00 3 9.3899e-01 3.8132e-02 1.5172e-01 -6.0000e+00 1.2567e+00 2.2327e+00 4.6511e-02 1.7993e-01 -6.0000e+00 1.3654e+00 -1.9439e+00 3.0253e-02 3.3284e-02 -6.0000e+00 8.0597e-01 5.8301e-01 1.5577e-02 3.7479e-02 -6.0000e+00 3.4479e-01 1.0909e-05 -1.9893e-03 4.9424e-04 2.7555e-04 -6.0000e+00 2.4831e-02 -4.7716e-03 0.0000e+00 12 9 8 11 32 0 99.21 20.90 0.91 -0.00477 -0.01972 16 3 1 5 0 3086.690 24.65 20.02 20.90 26.02 32.9 1024.64 58193 153823 58711 88212 118344 73794 900000 -56743 900000 -36691 900000 900000 532861 28942 115912 24072 249536 900000 10355 44129 6370 83284 79806 17264 18210 900000 -87083 15497 -40897 -16525 64757 113716 -2978 55974 408317 42503 95358 900000 900000 1605 3513 72518 -14209 -12546 94875 -3154 147354 210296 67428 250791 99862 97157 85517 99248 144254 118202 27510 1852 40274 35274 17148 -6856 -7498 44993 138570 54055 79511 -94361 900000 84411 37116 100178 14369 5124 17321 15191 13931 -12675 -12918 23469 51515 -1154 22076 20151 13382 12451 -9210 12524 38306 -15505 22146 -9999 5107 43970 -4994 24002 2582 -10973 11496 10447 9213 -4004 602 13657 12350 17906 -8247 -5942 3702 16841 -195 -1673 -2379 -2079 -6223 -4026 11633 -2634 1283 -3177 -1499 -907 -167 -6232 -6737 -2008 8571 1142 -8071 539 2344 -1135 1581 -2153 -1773 -349 4114 2534 793 -2978 2454 629 -1490 3782 4247 3887 3742 3015 2421 900000 -5076 900000 -2238 900000 900000 10156 1930 4235 2441 4756 900000 1341 3951 734 4083 3672 1314 1250 900000 -14008 906 -4203 -1589 3655 4813 -421 4485 7783 3162 4366 900000 900000 228 508 5580 -2515 -2191 6022 -510 5862 4733 6215 4780 7778 8356 8617 9089 8597 8772 4598 369 5223 4633 2745 -1519 -1910 7920 10622 8990 10372 -64624 900000 13115 9489 14167 4274 1497 3955 3114 2742 -3378 -4023 6277 12397 -515 8562 8257 6077 5910 -5505 6162 14559 -9285 8642 -4957 2156 13719 -2845 12379 1919 -10743 10039 9261 7713 -3346 427 8349 8073 11667 -7229 -5526 3520 16317 -251 -2364 -3474 -2997 -9001 -5559 14119 -3822 1890 -4999 -2259 -1288 -225 -8631 -9095 -2528 9572 1449 -12920 927 4455 -2420 3509 -5272 -4623 -943 10894 6890 2186 -8173 6015 1462 -3370 SS 20240912T114416.8Z 9021.489083 54 1 40.18 2 79.17 93.35 171.04 337.36 0.00 1 0.00 1 0 25 3.309e-01 8.925e-03 5.787e-02 1.845e-03 6.590642e-01 9.745783e-04 7.484021e-03 -6.000000e+00 1.891869e-01 229.53 -2.00 3.43 -2.00 320.74 0.00e+00 2.203962e-03 4.208939e-04 1.828722e-03 -6.000000e+00 8.582730e-03 290.45 -2.00 20.00 -2.00 320.04 0.00e+00 5.123 0.002 302.00 328.00 3 1.3008e+00 3.1559e-03 6.1779e-02 -6.0000e+00 4.7086e-01 7.2669e-02 4.1638e-03 3.5414e-02 -6.0000e+00 5.0994e-01 -1.3363e-01 3.8645e-03 1.7945e-02 -6.0000e+00 3.0466e-01 5.0985e-02 1.9019e-03 5.1889e-03 -6.0000e+00 1.3055e-01 4.4448e-04 -1.0399e-03 4.9089e-05 6.5798e-05 -6.0000e+00 8.8378e-03 -5.8217e-03 0.0000e+00 12 9 1 12 1 1 89.57 20.99 0.32 -0.00582 -0.01364 120 30 1 5 0 332.050 24.75 20.02 20.99 28.66 33.2 1025.00 -96344 -165132 -98791 -106176 -121843 -107973 -102037 -89471 -68745 -73376 -132634 -5054 -53873 -64317 -49735 -39523 -18019 -10009 -31733 -22811 -26826 -13362 -21235 -21413 -10940 302 -27216 -28570 -23212 -23047 -5439 -2108 -6623 -16152 -8319 -7269 -5348 9419 4326 -461 1246 3444 -3274 -416 1439 2148 6403 3136 1418 5880 4512 3386 4921 3321 5094 3459 2288 1186 2092 1196 1835 951 1810 3279 2925 809 765 13795 2808 1324 473 1567 -528 -90 -1031 -1425 -3385 -2141 -2672 -2242 -1653 -2605 -1866 -1101 -1177 -301 -207 423 1055 -132 422 -177 -563 239 -1058 -95 -196 -183 -349 -422 -608 -935 -322 -52 -1196 -222 -1020 -283 845 1019 550 487 584 643 246 428 557 107 2 -545 -326 260 478 131 -52 -676 576 879 -74 -52 -153 -265 10 -139 -389 -231 207 247 25 -194 7 -265 174 -815 -2891 -1031 -1127 -1403 -1108 -1102 -982 -693 -832 -2625 -36 -814 -1263 -1058 -899 -371 -211 -898 -623 -777 -341 -629 -701 -349 9 -1086 -1117 -862 -954 -229 -94 -357 -1000 -454 -399 -326 599 358 -48 131 379 -405 -51 176 268 785 414 200 860 753 641 1007 753 1203 868 556 289 528 301 479 259 559 1121 1047 288 271 4460 1134 586 232 791 -268 -43 -482 -601 -1369 -876 -1245 -1157 -994 -1694 -1318 -819 -940 -254 -184 361 893 -116 342 -135 -416 181 -916 -89 -213 -215 -448 -541 -731 -1015 -337 -55 -1299 -253 -1236 -365 1120 1513 866 774 931 1040 377 627 820 165 3 -897 -533 427 754 200 -76 -1019 826 1301 -118 -90 -277 -514 20 -286 -826 -518 474 574 58 -437 15 -552 347 SS 20240912T115759.5Z 9021.498605 57 1 26.00 2 76.45 95.46 171.64 355.92 0.00 1 0.00 1 0 25 1.421e-01 6.430e-03 3.339e-02 1.659e-03 5.490238e-01 8.551865e-04 6.250207e-03 -6.000000e+00 8.122730e-02 229.53 -2.00 3.43 -2.00 319.92 0.00e+00 1.854424e-03 2.799371e-04 6.297912e-04 -6.000000e+00 3.684095e-03 290.44 -2.00 20.00 -2.00 319.13 0.00e+00 4.164 0.001 302.00 328.00 3 1.7789e+00 2.5272e-03 5.0288e-02 -6.0000e+00 2.0216e-01 3.1294e-02 3.0890e-03 2.8306e-02 -6.0000e+00 2.1893e-01 -5.9143e-02 2.5842e-03 1.4146e-02 -6.0000e+00 1.3080e-01 1.7836e-02 1.3371e-03 4.3001e-03 -6.0000e+00 5.6062e-02 7.6298e-04 -7.7190e-04 4.5337e-05 4.6300e-05 -6.0000e+00 3.7934e-03 -7.4366e-03 0.0000e+00 12 9 1 12 1 1 99.56 21.09 0.37 -0.00744 -0.01324 84 33 1 5 0 305.770 24.75 20.01 21.09 29.98 33.0 1024.33 -44688 -60249 -42783 -43234 -68068 -6095 -66366 -43568 -39906 -33730 -51146 -12468 -5669 -21413 -8397 -14331 -2749 -5009 -4659 -4214 -6637 -6886 -3168 -5132 -3143 -2558 -9629 -9325 -14264 -5652 -5484 1226 -1664 -4062 -2469 -5861 -4747 3468 2268 61 334 176 157 209 1763 1483 2860 -243 164 2630 2547 1373 2979 2186 1623 2620 55 409 535 731 1504 1472 2136 2041 958 653 550 -1155 2385 -270 431 528 -68 -429 -765 -1715 -2324 -1437 -1826 -1355 -1531 -1634 -1996 -770 -995 -331 -471 517 1058 501 883 -159 42 506 -122 -57 366 -119 2 -347 -499 -514 276 -99 -1070 -654 -607 -169 829 995 548 495 554 410 305 558 423 48 -171 -614 -409 -18 373 -84 -144 -849 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