File name: Pandora37s1_HamptonVA_20250430_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T230402.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20250430_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20250430 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250430T105752.4Z 9251.456857 59 1 50.25 2 82.02 77.29 100.41 43.86 0.00 1 0.00 1 0 25 4.527e-01 3.590e-02 2.296e-01 1.041e-02 7.975646e-01 5.849336e-03 1.008980e-02 -6.000000e+00 2.671859e-01 230.15 -2.00 3.43 -2.00 321.74 0.00e+00 1.562473e-02 2.906520e-03 7.085789e-03 -6.000000e+00 1.292266e-02 284.44 -2.00 20.00 -2.00 321.19 0.00e+00 6.728 0.005 302.00 328.00 3 2.3383e+00 2.1118e-02 8.3111e-02 -6.0000e+00 6.6864e-01 9.8161e-01 2.6258e-02 4.7799e-02 -6.0000e+00 7.2699e-01 -1.2700e+00 2.0196e-02 2.6256e-02 -6.0000e+00 4.2612e-01 5.1125e-01 9.8447e-03 1.1162e-02 -6.0000e+00 1.7897e-01 2.4071e-05 -2.1085e-03 2.8311e-04 2.7684e-04 -6.0000e+00 1.2389e-02 -6.3402e-03 0.0000e+00 12 8 8 10 0 0 82.29 21.17 0.76 -0.00634 -0.02218 22 4 1 5 0 2283.950 25.28 20.01 21.17 25.02 34.2 1019.38 -27824 -130665 -16750 28275 900000 900000 900000 -93468 900000 -16463 -75605 900000 160363 86012 49090 10144 83427 900000 -3657 65054 -23030 900000 58881 13911 21425 900000 -75503 122162 -55111 -26539 87158 24661 -27348 37679 108728 104433 -1639 188513 89975 55488 27988 73340 -12617 73894 42954 35576 112962 74012 42899 89806 37830 47019 21702 63487 58874 73766 7117 13084 2283 11644 14101 -160 14527 37492 51699 15283 20816 9276 52420 15998 3253 32400 564 -14643 10070 -851 -10665 40584 -17400 -4084 3643 -801 -5649 493 1088 -336 -7179 -5455 -302 -4683 -2255 -11250 -5134 9608 -10559 4472 -1431 -7523 1033 2029 -2008 -5804 -3958 1801 627 4583 -6230 -4591 382 4981 -1070 -915 700 1137 -2541 -885 4919 -1380 386 2053 797 1185 3035 1394 -1195 1139 4765 3723 -2532 1191 1810 -831 299 -1691 -1192 -143 1288 401 -272 1012 781 -2346 -1687 -904 -12051 -523 504 900000 900000 900000 -3790 900000 -302 -2398 900000 1625 1120 1133 392 1739 900000 -189 1732 -1336 900000 1403 499 696 900000 -5745 1345 -3345 -1393 1901 1156 -2337 1771 2371 2270 -103 2163 3082 2952 2055 3656 -1448 3826 2991 2704 4235 4155 3361 4817 3619 4510 2815 5897 5850 6408 1142 1920 354 1621 1986 -28 2569 6026 7638 3107 3995 2052 8518 4133 1022 7932 180 -4998 2458 -206 -2682 6583 -5548 -1377 1337 -348 -2800 243 564 -186 -4420 -3385 -178 -2777 -1226 -6275 -2638 4515 -6790 2934 -1155 -7387 1030 2024 -1964 -5300 -3229 1383 519 3870 -6115 -4779 419 5920 -1497 -1368 1052 1675 -3722 -1241 6625 -2055 597 3241 1257 1793 4359 1980 -1683 1530 6037 4961 -4019 2074 3449 -1733 648 -3931 -2925 -365 3295 1046 -713 2542 1858 -5393 -3699 SS 20250430T111447.1Z 9251.468600 64 1 49.92 2 78.71 79.72 98.11 46.62 0.00 1 0.00 1 0 17 2.776e-01 7.922e-03 8.080e-02 2.037e-03 6.415808e-01 1.076187e-03 7.228425e-03 -6.000000e+00 1.590081e-01 230.15 -2.00 3.43 -2.00 320.76 0.00e+00 3.449272e-03 4.514131e-04 1.804907e-03 -6.000000e+00 7.016944e-03 284.44 -2.00 20.00 -2.00 320.14 0.00e+00 4.933 0.002 302.00 328.00 3 1.8468e+00 3.4227e-03 5.9883e-02 -6.0000e+00 3.9718e-01 7.4087e-02 4.4997e-03 3.4521e-02 -6.0000e+00 4.3039e-01 -1.4029e-01 4.3168e-03 1.8562e-02 -6.0000e+00 2.5606e-01 4.9864e-02 2.1192e-03 6.2525e-03 -6.0000e+00 1.0895e-01 3.1048e-04 -9.4811e-04 5.5401e-05 7.7561e-05 -6.0000e+00 7.4114e-03 -6.7201e-03 0.0000e+00 11 8 0 10 0 0 35.46 21.20 0.40 -0.00672 -0.01384 118 24 1 5 0 423.030 25.28 20.01 21.20 25.94 34.3 1019.25 -115768 -148468 -100680 3391 -94079 -69658 -33286 -98789 -51273 -44792 -124655 1886 -22042 -80230 -25929 -35624 -12622 -4984 -21457 -20720 -10419 -19222 -25449 -12576 -15832 11415 -31263 -17439 -23851 -14287 -9126 -429 -8888 -4290 -3195 -6701 -199 8812 8885 -542 2289 2980 -2059 2071 2092 -1055 7717 -217 2663 6587 4279 4500 3366 5403 2001 4718 -177 1525 -1433 1349 2403 1427 3147 4324 4275 587 551 -1089 4041 987 1110 1563 -366 -922 -942 -1039 -3958 -1219 -2657 -2379 -1826 -1773 -2489 -778 -1008 -63 118 -177 1320 534 787 -1222 -352 159 -1055 -188 298 -233 -64 -283 -662 -665 -125 -291 -1288 -505 -682 -90 709 1560 542 532 591 209 32 608 546 -79 111 -445 -210 270 574 16 -51 -865 368 479 -490 -160 -216 -374 9 109 -268 -137 0 308 -66 -57 35 -222 300 -1212 -2466 -1200 13 -916 -540 -198 -1295 -468 -409 -2431 13 -258 -1970 -463 -830 -262 -106 -581 -587 -271 -548 -822 -391 -546 315 -1332 -627 -917 -557 -409 -21 -500 -241 -169 -372 -12 569 706 -56 257 356 -272 268 276 -136 1013 -30 370 950 708 831 689 1178 477 1140 -46 388 -365 331 610 407 1008 1426 1468 203 189 -393 1549 451 556 810 -190 -454 -423 -419 -1544 -473 -1182 -1256 -1047 -1158 -1790 -583 -812 -50 99 -153 1123 440 643 -953 -261 121 -858 -176 302 -272 -82 -359 -790 -715 -130 -307 -1393 -574 -819 -115 929 2273 837 870 969 331 48 916 827 -119 179 -751 -353 436 890 24 -79 -1286 520 699 -770 -283 -399 -738 18 226 -573 -310 0 721 -155 -130 75 -471 610 SS 20250430T112053.0Z 9251.472836 67 1 50.08 2 77.51 80.60 97.26 47.59 0.00 1 0.00 1 0 17 2.254e-01 7.605e-03 3.265e-02 1.415e-03 5.918296e-01 7.370997e-04 6.678077e-03 -6.000000e+00 1.291218e-01 230.15 -2.00 3.43 -2.00 320.36 0.00e+00 3.477113e-03 2.727114e-04 1.114692e-03 -6.000000e+00 5.697820e-03 284.44 -2.00 20.00 -2.00 319.71 0.00e+00 4.494 0.001 302.00 328.00 3 1.6806e+00 2.2389e-03 5.4510e-02 -6.0000e+00 3.2253e-01 5.1727e-02 2.8098e-03 3.0911e-02 -6.0000e+00 3.4949e-01 -1.0925e-01 2.5487e-03 1.6316e-02 -6.0000e+00 2.0793e-01 3.8024e-02 1.2853e-03 5.8607e-03 -6.0000e+00 8.8472e-02 5.8474e-04 -8.5939e-04 3.8628e-05 6.5768e-05 -6.0000e+00 6.0181e-03 -7.0406e-03 0.0000e+00 11 8 0 10 0 0 41.00 21.21 0.31 -0.00704 -0.01350 175 35 1 5 0 286.140 25.28 20.01 21.21 26.14 34.2 1019.34 -95654 -82034 -83038 -36251 -96556 -53216 -79915 -65988 -62888 -59965 -93393 -28921 -31625 -40299 -8656 -23226 1926 -9151 -4757 -9991 -2657 -11698 -6502 -10636 -7613 276 -19815 -7887 -17563 -5760 -1432 -319 -5534 -3782 -3435 -5089 -3841 3582 3763 962 2065 1580 -1 2060 3050 759 4431 1799 2222 4596 3426 3621 2741 3849 3744 2945 439 330 -818 1018 1922 2105 3116 2715 2090 1090 1024 -6089 2330 765 1251 665 105 -1202 -835 -1704 -2747 -1937 -2590 -1547 -1308 -1413 -2157 -989 -831 -142 47 333 726 628 907 -466 -223 261 -735 -71 243 152 169 -248 -813 -798 86 -187 -1220 -390 -673 120 712 964 584 547 613 344 41 427 346 115 -14 -353 -161 286 371 -112 -161 -767 308 678 -230 -320 -246 -270 -163 70 -342 -170 217 321 -42 89 -157 -119 159 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