File name: Pandora37s1_HamptonVA_20250501_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T230457.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20250501_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20250501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250501T111336.0Z 9252.467777 64 1 50.11 2 78.74 79.32 105.76 34.93 0.00 1 0.00 1 0 25 5.833e-01 7.441e-02 2.453e-01 1.797e-02 5.959426e-01 9.551473e-03 6.806969e-03 -6.000000e+00 3.401197e-01 230.23 -2.00 3.43 -2.00 320.60 0.00e+00 1.351550e-02 3.131890e-03 2.868874e-04 -6.000000e+00 1.614120e-02 284.54 -2.00 20.00 -2.00 319.91 0.00e+00 4.946 0.002 302.00 328.00 3 4.7920e+00 2.9012e-02 5.8681e-02 -6.0000e+00 8.5308e-01 7.6852e-01 3.4149e-02 3.5114e-02 -6.0000e+00 9.2724e-01 -8.4374e-01 2.2644e-02 1.5853e-02 -6.0000e+00 5.4667e-01 3.4771e-01 1.1583e-02 1.2288e-02 -6.0000e+00 2.3073e-01 1.3134e-05 -2.8771e-03 5.0797e-04 1.4446e-04 -6.0000e+00 1.6272e-02 -4.5214e-03 0.0000e+00 12 9 8 11 32 0 99.97 21.32 0.72 -0.00452 -0.02614 14 3 1 5 0 3578.580 25.39 20.01 21.32 28.44 34.5 1019.75 42453 -108122 143015 123435 407 7183 900000 -66536 900000 58501 266052 900000 281909 32070 132703 -2330 52053 900000 47827 22959 36100 149298 59311 32190 24097 900000 -64919 150181 29792 21358 103101 32082 30555 66609 70813 79213 24836 900000 262183 12724 29852 46549 -23786 18235 53284 13469 66894 47676 57015 98954 38071 25738 18095 68697 46512 38056 2145 4430 -11359 21324 21113 -1414 16054 26658 51197 12100 30834 -62048 60467 15966 5730 24366 -3643 -18477 4249 3543 -7520 41956 -15805 -4709 12211 -6749 -4388 -363 2383 -717 -5703 -6944 8770 405 6657 -18053 3516 1523 -13597 10074 2041 -8930 2403 7263 -2298 -5077 -6116 2307 7368 6964 -7544 -4729 1963 11619 -228 1721 2370 2390 -3806 -4122 9458 -6007 375 1025 1130 642 2887 656 -5149 5840 10585 -3507 -5281 1410 2070 -1055 -25 1313 -2666 -1516 3442 1277 -499 2953 958 -3725 -3462 1902 -19559 2828 2618 22 336 900000 -5819 900000 1679 4656 900000 4934 1858 3788 -242 3580 900000 3662 2187 2964 4317 3653 2480 1962 900000 -11154 3731 2096 1741 4761 3123 3311 5322 5037 5051 2695 900000 4588 2193 4688 6517 -6479 3433 7366 2698 8356 7158 8009 9933 7055 5744 4578 11502 9699 8589 670 1320 -3771 5179 5315 -478 5158 8544 13466 4376 9068 -43614 14748 6606 2819 10344 -1962 -10740 1822 1374 -3006 10669 -7566 -2374 6043 -4463 -3060 -255 1726 -566 -4928 -6225 6792 327 4738 -15052 2279 1018 -11513 7833 1956 -10734 2825 8190 -2670 -5489 -6126 2136 6969 6980 -9052 -5879 2477 14809 -354 2756 3774 3677 -5856 -6086 12356 -9409 586 1667 1837 1019 4340 974 -7749 7675 12824 -4925 -8298 2319 3668 -2029 -50 2680 -5957 -3515 7790 2985 -1187 6622 2074 -7954 -7075 SS 20250501T114126.8Z 9252.487116 76 1 33.07 2 73.25 83.31 102.55 39.95 0.00 1 0.00 1 0 25 1.091e-01 8.171e-03 4.223e-02 3.231e-03 4.500718e-01 1.649748e-03 5.138390e-03 -6.000000e+00 6.252651e-02 230.23 -2.00 3.43 -2.00 319.47 0.00e+00 1.373893e-03 4.485295e-04 5.715723e-04 -6.000000e+00 2.758551e-03 284.54 -2.00 20.00 -2.00 318.74 0.00e+00 3.416 0.001 302.00 328.00 3 3.9918e+00 4.6812e-03 4.1349e-02 -6.0000e+00 1.5621e-01 1.8983e-02 5.4972e-03 2.3201e-02 -6.0000e+00 1.6924e-01 -4.9424e-02 4.2425e-03 1.1499e-02 -6.0000e+00 1.0068e-01 1.4441e-02 2.2261e-03 3.3761e-03 -6.0000e+00 4.2854e-02 1.9040e-04 -6.4990e-04 9.1500e-05 3.6304e-05 -6.0000e+00 2.9123e-03 -9.3495e-03 0.0000e+00 12 9 1 12 1 1 99.97 21.37 0.28 -0.00935 -0.01423 24 8 1 5 0 1322.460 25.39 20.01 21.37 28.92 34.3 1019.82 -11129 -56630 -19607 -23656 -26911 -20537 -114 -15381 16866 8229 -34638 88883 1390 13197 -3973 -8143 -1092 15988 -10218 1164 -1846 4516 -1279 -5765 -3285 3186 -5744 -2910 -2171 -9394 3175 -716 -3160 -374 -552 -2715 -4681 5827 22 -488 -1446 2664 -4196 1383 -908 58 2337 -838 -571 1268 2451 -399 1734 781 3648 1569 -480 -732 283 309 2174 205 1728 2891 1664 8 -262 851 2716 1169 139 2491 -1046 -1133 330 -1186 -2396 -163 -2090 -1996 -805 -2729 -1866 -1564 -1047 -737 115 150 1021 954 519 -891 -718 1516 -1402 702 453 7 -329 -23 -676 -1040 354 305 -660 -56 -874 -502 1002 1293 735 280 407 754 -95 267 462 -367 6 -327 -324 126 394 247 -739 -740 979 746 -674 -277 -18 -523 -61 -55 -390 -228 453 495 248 62 31 -458 -154 -256 -2144 -549 -644 -696 -504 -3 -445 404 223 -1398 1325 53 543 -224 -535 -72 968 -829 89 -147 340 -106 -537 -318 303 -591 -279 -201 -975 331 -87 -436 -52 -72 -365 -713 949 4 -117 -381 711 -1232 392 -264 17 670 -249 -172 391 809 -147 667 322 1524 687 -218 -332 125 136 972 101 919 1641 965 5 -142 463 1571 767 99 1798 -771 -805 217 -722 -1377 -91 -1276 -1375 -614 -2311 -1667 -1451 -1022 -755 122 162 1101 1000 517 -844 -647 1345 -1359 735 522 9 -438 -30 -859 -1236 396 347 -801 -70 -1146 -684 1419 1943 1170 458 658 1176 -142 384 662 -546 9 -528 -527 202 617 378 -1103 -1074 1361 1050 -1020 -447 -31 -916 -109 -101 -749 -455 914 1011 509 126 61 -875 -287 SS 20250501T115258.0Z 9252.495115 79 1 7.10 2 70.97 84.97 101.12 41.93 0.00 1 0.00 1 0 17 3.512e-02 6.459e-03 1.550e-02 2.337e-03 4.030812e-01 1.185242e-03 4.647284e-03 -6.000000e+00 2.013262e-02 230.23 -2.00 3.43 -2.00 318.57 0.00e+00 6.808735e-04 2.448081e-04 3.361055e-04 -6.000000e+00 8.882642e-04 284.54 -2.00 20.00 -2.00 317.81 0.00e+00 3.030 0.000 302.00 328.00 3 2.5089e+00 3.2346e-03 3.6744e-02 -6.0000e+00 5.0297e-02 -4.9436e-03 3.6915e-03 2.0634e-02 -6.0000e+00 5.4493e-02 -4.2857e-02 2.5107e-03 1.0072e-02 -6.0000e+00 3.2419e-02 1.3930e-02 1.3161e-03 2.8103e-03 -6.0000e+00 1.3798e-02 1.3065e-03 -6.8067e-04 6.5498e-05 2.9243e-05 -6.0000e+00 9.3777e-04 -9.0010e-03 0.0000e+00 12 9 1 12 1 1 85.05 21.40 0.26 -0.00900 -0.01412 20 30 1 5 0 337.950 25.39 20.01 21.40 29.49 34.5 1020.44 -632 -13687 -5429 -7484 -8695 -18926 -5306 -8386 -12531 -10386 -18354 -1827 -7261 -43 -3972 -500 2088 5678 328 2324 -438 1667 578 -1292 1350 228 -936 -3799 -3346 -1390 114 164 -2221 -3422 -4019 -2740 -2929 771 509 -467 -44 1125 -517 -118 -251 230 806 -119 -103 753 1823 1398 1991 1442 2182 844 466 212 417 348 1249 1802 2451 1509 26 676 -775 -988 1033 190 10 552 20 -684 -1318 -780 -1896 -1344 -1596 -1784 -1165 -1938 -1923 -995 -406 -64 399 285 881 816 354 -458 -165 414 -357 244 -57 480 6 -265 -581 -589 121 -231 -926 -517 -423 -278 844 781 693 294 367 594 290 551 366 218 93 -472 -343 187 247 -48 211 -710 138 856 -9 -224 -374 -165 -58 86 -409 -359 208 241 42 56 -65 -416 217 -27 -669 -270 -351 -375 -906 -244 -454 -727 -617 -1194 -111 -551 -4 -411 -56 243 680 41 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