File name: Pandora37s1_HamptonVA_20250614_L2Fit_fout2c3d20201125p1-8.txt File generation date: 20250615T050917.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v3d20201125.txt Level 1 file used: Pandora37s1_HamptonVA_20250614_L1_smca1c3d20201125p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20250614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session1 valid starting from 20201125 First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.0545 305.1949 305.3354 305.4758 305.6162 305.7565 305.8969 306.0373 306.1776 306.3180 306.4583 306.5986 306.7389 306.8792 307.0195 307.1597 307.3000 307.4402 307.5805 307.7207 307.8609 308.0011 308.1413 308.2814 308.4216 308.5618 308.7019 308.8420 308.9821 309.1222 309.2623 309.4024 309.5425 309.6825 309.8226 309.9626 310.1026 310.2427 310.3827 310.5226 310.6626 310.8026 310.9425 311.0825 311.2224 311.3623 311.5022 311.6421 311.7820 311.9219 312.0617 312.2016 312.3414 312.4812 312.6210 312.7608 312.9006 313.0404 313.1802 313.3199 313.4597 313.5994 313.7391 313.8788 314.0185 314.1582 314.2979 314.4375 314.5772 314.7168 314.8564 314.9960 315.1356 315.2752 315.4148 315.5544 315.6939 315.8334 315.9730 316.1125 316.2520 316.3915 316.5310 316.6704 316.8099 316.9493 317.0888 317.2282 317.3676 317.5070 317.6464 317.7858 317.9251 318.0645 318.2038 318.3431 318.4824 318.6218 318.7610 318.9003 319.0396 319.1788 319.3181 319.4573 319.5965 319.7357 319.8749 320.0141 320.1533 320.2925 320.4316 320.5707 320.7099 320.8490 320.9881 321.1272 321.2662 321.4053 321.5444 321.6834 321.8224 321.9614 322.1004 322.2394 322.3784 322.5174 322.6563 322.7953 322.9342 323.0731 323.2120 323.3509 323.4898 323.6287 323.7676 323.9064 324.0452 324.1841 324.3229 324.4617 324.6005 324.7392 324.8780 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250614T152505.0Z 9296.642419 360 1 50.82 2 25.68 115.41 122.09 262.96 0.00 1 0.00 1 0 17 1.150e-02 8.548e-03 3.425e-03 2.228e-03 1.625313e-01 1.155834e-03 1.922512e-03 -6.000000e+00 6.668034e-03 232.79 -2.00 3.43 -2.00 315.18 0.00e+00 5.850232e-04 1.029760e-04 2.979377e-05 -6.000000e+00 2.960870e-04 288.81 -2.00 20.00 -2.00 314.47 0.00e+00 1.109 0.000 302.00 328.00 3 6.3338e+00 3.0008e-03 1.3975e-02 -6.0000e+00 1.6742e-02 5.1333e-02 3.3229e-03 8.3572e-03 -6.0000e+00 1.8077e-02 -8.4204e-03 1.8969e-03 4.0279e-03 -6.0000e+00 1.0759e-02 -1.1687e-03 8.4288e-04 1.1441e-03 -6.0000e+00 4.5822e-03 2.6297e-04 3.4350e-04 6.2437e-05 1.3972e-05 -6.0000e+00 3.0710e-04 4.9111e-02 2.2009e-04 11 8 0 10 0 0 99.98 21.81 0.33 0.04911 0.05169 27 5 1 5 0 1881.930 25.68 20.01 21.81 35.09 35.3 1019.37 -714 -4876 -1191 -936 -1910 -314 1739 -605 2541 -1403 -1224 4014 -11 1455 354 -399 1545 2706 182 2066 -939 1218 744 176 -98 1435 -2068 126 -1080 288 -34 159 -773 -2454 -1452 -1780 -1759 401 217 -399 -691 -262 -1301 -314 -61 -583 128 331 -951 988 197 193 798 1273 1390 1525 364 -647 348 1173 1273 671 1085 1328 759 155 -305 -1045 2256 360 436 976 -198 -1192 -540 -692 -1716 -623 -2640 -1979 -1704 -2436 -2125 -1166 -318 -56 12 408 1354 438 957 -718 -441 730 -1036 389 257 -136 471 452 -145 -605 -986 133 -758 -125 -722 -602 984 1599 1016 541 689 507 -230 -69 382 -424 -94 -131 -572 141 109 -97 272 -480 110 1152 -870 153 150 -547 117 -572 -193 -243 474 701 64 -107 372 -779 -335 -227 -1685 -396 -284 -524 -83 475 -186 823 -479 -403 1284 -4 569 153 -182 703 1241 87 998 -467 589 366 90 -52 767 -1119 63 -509 131 -16 78 -403 -1297 -712 -865 -924 234 146 -300 -548 -212 -1079 -259 -50 -477 101 255 -718 730 152 155 659 1079 1196 1323 322 -573 302 1010 1122 625 1060 1340 757 145 -267 -893 1964 347 447 1026 -209 -1243 -534 -634 -1462 -501 -2201 -1776 -1651 -2528 -2292 -1286 -366 -67 15 520 1722 546 1129 -801 -456 723 -1068 422 298 -169 606 575 -177 -704 -1109 152 -925 -159 -942 -807 1338 2241 1469 787 974 683 -291 -84 456 -524 -122 -178 -799 196 149 -129 348 -597 131 1350 -1068 194 196 -728 156 -781 -272 -357 703 1057 98 -161 550 -1138 -479 SS 20250614T152929.1Z 9296.645476 363 1 2.65 2 24.89 116.89 122.92 263.55 0.00 1 0.00 1 0 17 7.246e-03 5.948e-03 6.959e-04 5.379e-04 1.553868e-01 2.820946e-04 1.836308e-03 -6.000000e+00 4.200276e-03 232.79 -2.00 3.43 -2.00 314.29 0.00e+00 3.035144e-04 2.127811e-05 1.187900e-05 -6.000000e+00 1.865356e-04 288.81 -2.00 20.00 -2.00 313.68 0.00e+00 1.102 0.000 302.00 328.00 3 9.7913e-01 7.2569e-04 1.3665e-02 -6.0000e+00 1.0546e-02 3.8021e-04 8.0011e-04 7.9414e-03 -6.0000e+00 1.1388e-02 -6.1012e-03 4.5864e-04 3.8354e-03 -6.0000e+00 6.7778e-03 -1.5941e-03 1.9880e-04 1.0621e-03 -6.0000e+00 2.8859e-03 5.8035e-02 1.4536e-04 1.4910e-05 1.4178e-05 -6.0000e+00 1.9349e-04 5.0596e-02 2.2712e-04 12 1 1 12 1 1 99.49 21.83 0.41 0.05060 0.05169 92 352 1 5 0 28.440 25.68 20.02 21.83 35.37 35.3 1019.81 -241 -266 -1201 -2173 -1267 -892 842 816 22 -1061 -726 158 -195 723 370 109 671 798 1143 1298 389 1113 1261 765 373 -136 -514 -510 -350 334 764 970 -190 -2181 -1762 -1905 -1136 -296 -474 -772 -623 -212 -580 -297 -68 -514 -494 -380 -377 529 695 686 896 647 750 936 497 521 724 791 1208 1308 1246 802 -363 -141 -468 392 997 -168 -151 -84 -66 121 -548 -466 -723 -717 -399 -1388 -1287 -1713 -1839 -963 -671 -460 -102 3 383 258 374 -27 366 881 372 7 331 475 -124 -257 -345 -332 438 275 -827 -625 -407 -252 533 635 564 314 479 353 398 622 312 240 155 -303 -494 -205 51 43 374 -307 43 809 52 -59 -373 -450 -71 194 -105 -232 98 252 -60 -7 -126 -375 11 -102 -118 -531 -929 -473 -342 318 345 10 -480 -315 69 -93 362 195 61 378 458 670 781 226 665 766 464 236 -89 -330 -302 -201 184 435 580 -116 -1355 -1056 -1127 -696 -200 -349 -627 -520 -182 -510 -261 -59 -445 -413 -317 -303 417 571 573 780 588 668 843 455 474 645 703 1105 1231 1215 822 -368 -134 -421 350 900 -167 -157 -88 -70 127 -541 -445 -644 -621 -354 -1277 -1268 -1787 -1965 -1065 -766 -545 -123 3 479 312 429 -30 380 895 380 7 380 578 -156 -318 -414 -381 490 308 -989 -766 -504 -325 687 860 775 434 652 458 484 724 372 288 194 -399 -657 -272 68 55 464 -377 51 942 61 -72 -478 -572 -90 254 -142 -321 139 356 -86 -10 -178 -517 16 SS 20250614T153449.3Z 9296.649181 366 1 49.94 2 23.95 118.79 123.92 264.27 0.00 1 0.00 1 0 17 7.274e-03 5.996e-03 1.352e-04 1.040e-04 1.543362e-01 5.437688e-05 1.822488e-03 -6.000000e+00 4.216352e-03 232.79 -2.00 3.43 -2.00 314.33 0.00e+00 2.869245e-04 4.138384e-06 1.240426e-05 -6.000000e+00 1.872427e-04 288.81 -2.00 20.00 -2.00 313.72 0.00e+00 1.094 0.000 302.00 328.00 3 6.4161e-01 1.3995e-04 1.3567e-02 -6.0000e+00 1.0586e-02 -4.0996e-03 1.5425e-04 7.8868e-03 -6.0000e+00 1.1431e-02 -5.6869e-03 8.8403e-05 3.8107e-03 -6.0000e+00 6.8037e-03 -1.2459e-03 3.8345e-05 1.0536e-03 -6.0000e+00 2.8971e-03 8.2282e-02 1.4107e-04 2.8781e-06 1.4058e-05 -6.0000e+00 1.9422e-04 5.0292e-02 2.2863e-04 10 0 0 10 0 0 99.86 21.86 0.42 0.05029 0.05135 2947 591 1 5 0 16.920 25.68 20.06 21.86 36.37 35.3 1020.48 -326 -179 -1140 -1993 -1320 -951 711 772 7 -963 -704 182 -152 556 384 47 719 825 1141 1305 362 1230 1202 881 420 -210 -568 -402 -381 382 624 1074 -99 -2271 -1826 -1791 -1237 -266 -443 -767 -555 -285 -571 -367 -30 -498 -481 -431 -450 503 732 619 941 634 826 1035 484 519 654 837 1238 1283 1335 815 -358 -139 -478 385 1070 -175 -167 -85 -86 47 -467 -520 -825 -734 -498 -1373 -1299 -1689 -1936 -941 -707 -446 -119 20 390 320 428 -1 306 831 245 -11 372 486 -128 -270 -328 -257 414 284 -889 -560 -442 -250 543 617 504 329 446 356 384 598 284 268 158 -253 -488 -167 -11 77 402 -330 75 827 84 -64 -333 -402 4 191 -118 -226 79 217 -90 4 -127 -403 -19 -139 -80 -509 -810 -501 -348 273 311 3 -440 -308 80 -69 280 203 27 406 474 635 746 211 698 694 533 266 -130 -364 -238 -219 211 357 643 -60 -1411 -1097 -1060 -757 -179 -324 -616 -458 -242 -497 -319 -26 -426 -415 -357 -358 411 595 533 809 570 755 919 437 466 600 764 1117 1237 1328 822 -357 -135 -442 339 991 -171 -172 -91 -92 49 -472 -490 -727 -629 -438 -1298 -1260 -1733 -2110 -1021 -792 -518 -145 25 477 390 499 -1 313 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