File name: Pandora37s1_HamptonVA_20250621_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T233802.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20250621_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20250621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250621T103558.7Z 9303.441652 167 1 49.64 2 81.97 66.62 40.92 109.96 0.00 1 0.00 1 0 33 5.165e-01 2.870e-02 2.667e-01 7.785e-03 8.121067e-01 4.511200e-03 1.044154e-02 -6.000000e+00 3.072995e-01 232.78 -2.00 3.43 -2.00 321.86 0.00e+00 1.819954e-02 2.552722e-03 7.339766e-03 -6.000000e+00 1.589825e-02 289.42 -2.00 20.00 -2.00 321.30 0.00e+00 6.685 0.005 302.00 328.00 3 1.9959e+00 1.7613e-02 8.3293e-02 -6.0000e+00 7.7749e-01 7.5226e-01 2.3632e-02 4.9171e-02 -6.0000e+00 8.4539e-01 -1.0177e+00 2.0461e-02 2.9119e-02 -6.0000e+00 4.9620e-01 4.0858e-01 9.5342e-03 1.3463e-02 -6.0000e+00 2.0851e-01 3.7067e-05 -2.2482e-03 2.1557e-04 2.9253e-04 -6.0000e+00 1.4792e-02 -4.0422e-03 0.0000e+00 12 8 8 10 0 0 66.95 21.05 0.68 -0.00404 -0.02094 35 7 1 5 0 1418.250 25.07 20.01 21.05 29.99 35.1 1023.04 -87039 -206354 77745 31407 -117439 236908 900000 900000 -44858 900000 -64192 900000 900000 -66934 900000 8542 900000 900000 23405 -25901 900000 71449 -19650 39878 -9313 900000 -95123 900000 -48995 95672 38480 38129 -13967 21757 63461 81113 900000 123762 296201 12603 55985 28807 -1883 10260 42885 10257 99096 33957 48009 74971 58880 29325 33653 53464 33256 44273 16844 10649 -1034 21357 22697 1586 8294 20679 46529 14971 24178 7517 55874 17986 7580 15815 2872 -17296 941 1383 -5535 27014 -9363 436 1879 -1881 -4241 1061 -659 1124 -3978 -3400 1595 -2575 715 -9422 -562 3325 -7586 770 -2106 -6646 -760 8 -981 -1757 -4770 -509 -1099 3909 -5095 -4219 -743 4861 -639 -361 1007 72 -1045 231 3026 -648 953 484 561 1274 3556 -263 -921 -822 3728 4021 -2042 1544 916 -249 962 -537 -1705 -396 788 529 -418 -333 1513 -1655 -1100 -1507 -13173 589 238 -2600 1794 900000 900000 -418 900000 -711 900000 900000 -1677 900000 154 900000 900000 464 -845 900000 791 -527 581 -217 900000 -4683 900000 -1656 892 807 977 -642 773 1368 1418 900000 1731 2243 661 2218 1578 -136 677 2249 716 3175 2039 2853 3669 3773 2602 3095 4310 3382 4072 2032 1325 -139 2265 2493 242 1373 3457 6368 2770 4081 1457 7950 4005 2040 4025 806 -5493 223 291 -1185 4691 -2544 131 660 -790 -2004 503 -338 564 -2199 -1920 856 -1387 371 -5090 -271 1627 -4471 497 -1660 -6412 -766 8 -940 -1515 -3809 -386 -901 3237 -4900 -4368 -780 5542 -873 -533 1496 105 -1491 314 4064 -953 1465 778 887 1911 5000 -373 -1268 -1095 4603 5191 -3224 2572 1721 -513 2086 -1195 -4131 -1000 2014 1375 -1097 -839 3490 -3662 -2432 SS 20250621T105332.2Z 9303.453845 172 1 49.83 2 78.72 69.04 37.70 114.00 0.00 1 0.00 1 0 25 3.346e-01 9.672e-03 7.114e-02 2.068e-03 6.479681e-01 1.102595e-03 7.351979e-03 -6.000000e+00 1.935678e-01 232.78 -2.00 3.43 -2.00 320.83 0.00e+00 4.325030e-03 4.820949e-04 2.086233e-03 -6.000000e+00 8.641283e-03 289.42 -2.00 20.00 -2.00 320.14 0.00e+00 4.936 0.002 302.00 328.00 3 1.8307e+00 3.6179e-03 6.0399e-02 -6.0000e+00 4.8582e-01 7.1157e-02 4.7505e-03 3.5283e-02 -6.0000e+00 5.2496e-01 -1.5122e-01 4.4410e-03 1.8855e-02 -6.0000e+00 3.1256e-01 5.5817e-02 2.1734e-03 6.4260e-03 -6.0000e+00 1.3285e-01 3.1399e-04 -8.6508e-04 5.6064e-05 8.2573e-05 -6.0000e+00 8.9437e-03 -5.1793e-03 0.0000e+00 12 8 8 10 0 0 94.66 21.07 0.48 -0.00518 -0.01168 123 25 1 5 0 405.080 25.07 20.01 21.07 31.52 35.2 1023.23 -98815 -157945 -125209 -100813 -132851 -77615 -99113 -103742 -67114 -72702 -139205 26995 -68251 -66765 -34184 -42649 -19094 -1223 -4638 -17514 -10689 -16156 -22250 -16254 -6855 17675 -23508 -21809 -30112 -15564 -7578 -7102 -2539 -10645 -3746 -6826 -977 9517 5417 8 4559 4698 1353 3303 3912 1110 7722 2656 3126 7113 7849 5032 5275 4922 4358 5342 1582 782 876 1236 1926 2272 3484 5031 3880 1231 1411 -12850 4488 1292 1586 1926 -519 -1770 -906 -1821 -4037 -920 -3079 -1935 -1201 -1958 -2244 -845 -496 139 115 215 1181 478 704 -566 -642 4 -1258 -48 189 -48 403 -228 -598 -1220 -181 -407 -1349 -570 -946 -265 855 1411 705 607 799 291 251 212 435 -22 -120 -305 -71 423 612 -93 -331 -1211 316 801 -199 -183 -318 -479 236 58 -655 -304 323 373 -35 96 38 -322 246 -877 -2635 -1584 -1037 -1583 -595 -1039 -1297 -650 -792 -2832 136 -1051 -1309 -608 -977 -388 -23 -98 -443 -257 -412 -640 -480 -197 418 -845 -748 -1131 -568 -310 -345 -136 -644 -201 -384 -59 619 414 1 463 511 160 393 472 142 947 357 439 1037 1275 869 996 1013 952 1204 380 188 205 286 464 608 1052 1678 1362 431 489 -4954 1753 559 751 945 -257 -834 -386 -757 -1614 -365 -1315 -974 -702 -1315 -1541 -607 -381 113 98 190 1030 404 553 -421 -460 3 -1054 -44 197 -54 491 -279 -689 -1353 -182 -416 -1503 -667 -1105 -330 1152 2001 1117 964 1269 473 386 312 643 -34 -200 -503 -115 701 977 -145 -495 -1763 462 1141 -322 -318 -606 -926 476 118 -1444 -706 729 856 -81 224 84 -671 516 SS 20250621T105939.7Z 9303.458099 175 1 50.08 2 77.58 69.88 36.60 115.53 0.00 1 0.00 1 0 25 2.453e-01 7.875e-03 3.151e-02 1.363e-03 6.009121e-01 7.179746e-04 6.844517e-03 -6.000000e+00 1.418708e-01 232.78 -2.00 3.43 -2.00 320.44 0.00e+00 3.221541e-03 2.756734e-04 1.800730e-03 -6.000000e+00 6.333147e-03 289.42 -2.00 20.00 -2.00 319.71 0.00e+00 4.515 0.001 302.00 328.00 3 1.5718e+00 2.2260e-03 5.5417e-02 -6.0000e+00 3.5607e-01 4.1779e-02 2.8123e-03 3.2430e-02 -6.0000e+00 3.8475e-01 -1.1405e-01 2.4972e-03 1.6603e-02 -6.0000e+00 2.2908e-01 4.1917e-02 1.2539e-03 5.1123e-03 -6.0000e+00 9.7373e-02 6.3851e-04 -8.2173e-04 3.7101e-05 6.3721e-05 -6.0000e+00 6.5547e-03 -5.4750e-03 0.0000e+00 11 8 0 10 0 0 98.77 21.10 0.33 -0.00547 -0.01165 191 38 1 5 0 262.170 25.07 20.01 21.10 32.11 35.1 1023.34 -79260 -118624 -72230 -77378 -90143 -73265 -79265 -75679 -66091 -58332 -100084 -21310 -42221 -36656 -24742 -19404 -11642 -6047 -12335 -9832 -12810 -12608 -8455 -17107 -13252 -7571 -12022 -15617 -7990 -9686 -2401 -5761 -3398 -6951 -6506 -6196 -3590 2221 3180 832 314 3350 633 2655 2954 4362 3805 640 1906 4355 4375 3182 5113 3983 3259 3319 2066 367 983 948 1934 1570 2794 3313 1610 1622 414 -2911 2599 852 305 1479 -202 -868 -1304 -1927 -3445 -2360 -2424 -2650 -1383 -1849 -2051 -1281 -559 29 133 357 1162 659 674 -379 -452 61 -773 -134 61 183 -142 -363 -708 -822 -217 -316 -1463 -679 -595 -25 933 1185 765 524 802 455 125 317 355 156 45 -332 -228 262 521 147 -198 -813 48 585 -180 -186 -391 -351 -9 6 -219 -351 208 317 31 -59 1 -286 298 -969 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