File name: Pandora37s1_HamptonVA_20250716_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T235754.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20250716_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20250716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250716T111112.5Z 9328.466117 219 1 49.98 2 77.45 72.68 41.01 216.96 0.00 1 0.00 1 0 17 2.629e-01 1.204e-02 1.095e-01 3.607e-03 5.613109e-01 1.894168e-03 6.558691e-03 -6.000000e+00 1.517810e-01 232.55 -2.00 3.43 -2.00 320.54 0.00e+00 2.178767e-03 7.388961e-04 2.924296e-03 -6.000000e+00 6.852713e-03 291.61 -2.00 20.00 -2.00 319.77 0.00e+00 4.473 0.001 302.00 328.00 3 3.2365e+00 6.0064e-03 5.5026e-02 -6.0000e+00 3.8040e-01 7.5291e-02 7.5468e-03 3.4021e-02 -6.0000e+00 4.1119e-01 -1.4120e-01 6.3338e-03 1.5515e-02 -6.0000e+00 2.4522e-01 6.0105e-02 3.1810e-03 3.8993e-03 -6.0000e+00 1.0430e-01 1.2999e-04 -4.4413e-04 1.0112e-04 5.9722e-05 -6.0000e+00 7.0327e-03 6.6682e-03 0.0000e+00 12 8 8 10 0 0 99.92 20.77 0.27 0.00667 0.00333 66 13 1 5 0 757.170 24.46 20.01 20.77 33.52 35.7 1020.89 371 -143936 -59944 -50692 -121142 -20762 -69099 -56329 -57955 -23465 -78693 155974 -17144 -32158 29659 4670 28563 25514 -3437 -16558 -18054 -20445 -326 -22070 12915 34621 -10962 -10924 -16322 -21208 -2972 2704 -11553 -13255 934 -1692 -382 29422 13241 5009 -2995 3831 -3563 -2549 538 -1131 11321 -104 -61 11049 7705 2772 5276 3827 7001 6203 1746 411 -326 1276 3133 471 828 4298 4876 1376 1089 741 5371 2354 697 3028 -1414 -5115 -2015 -1588 -3526 -1033 -4546 -2117 -1551 -3461 -1598 -1415 -711 287 -882 534 1606 615 891 -1431 -790 509 -2567 251 -646 -1118 47 -546 -647 -1563 -848 -99 -365 188 -709 -401 1785 1730 894 990 887 854 -392 -11 446 -592 157 -240 415 922 733 -44 -667 -1683 966 -119 -898 -159 -251 -484 6 -385 -373 -152 808 604 202 -383 15 -291 -74 3 -4992 -1039 -758 -3105 -228 -1272 -1043 -1191 -375 -2094 589 -373 -962 619 136 735 726 -132 -741 -826 -962 -14 -1196 550 1271 -591 -567 -883 -1301 -180 177 -955 -1132 67 -127 -32 2228 1384 649 -454 577 -595 -428 89 -193 1750 -18 -11 1927 1525 628 1261 992 1844 1704 510 120 -94 362 913 155 303 1661 1903 533 416 293 2260 1151 373 1638 -783 -2780 -982 -702 -1500 -437 -2209 -1163 -964 -2431 -1182 -1098 -583 247 -800 489 1455 542 736 -1136 -601 393 -2235 240 -696 -1342 60 -683 -768 -1720 -876 -104 -411 220 -874 -520 2428 2553 1422 1622 1444 1343 -593 -16 655 -911 252 -400 688 1487 1155 -69 -1001 -2470 1350 -173 -1428 -273 -459 -921 12 -786 -799 -337 1811 1376 462 -857 31 -603 -149 SS 20250716T111656.1Z 9328.470093 222 1 49.91 2 76.36 73.47 41.67 218.83 0.00 1 0.00 1 0 17 1.413e-01 8.069e-03 1.398e-02 9.136e-04 5.256899e-01 4.731828e-04 5.999571e-03 -6.000000e+00 8.154893e-02 232.55 -2.00 3.43 -2.00 319.83 0.00e+00 1.985717e-03 1.481611e-04 1.444211e-03 -6.000000e+00 3.681829e-03 291.61 -2.00 20.00 -2.00 319.00 0.00e+00 4.139 0.001 302.00 328.00 3 1.3111e+00 1.3928e-03 4.9893e-02 -6.0000e+00 2.0438e-01 2.5936e-02 1.6794e-03 2.8083e-02 -6.0000e+00 2.2093e-01 -8.2438e-02 1.3412e-03 1.3766e-02 -6.0000e+00 1.3175e-01 3.0475e-02 6.9534e-04 3.8314e-03 -6.0000e+00 5.6039e-02 1.2917e-03 -1.7702e-04 2.5163e-05 4.6024e-05 -6.0000e+00 3.7785e-03 6.6648e-03 0.0000e+00 11 8 0 10 0 0 97.47 20.78 0.31 0.00666 0.00533 272 55 1 5 0 183.480 24.46 20.02 20.78 34.01 35.7 1020.96 -39953 -55353 -46377 -42741 -57706 -42661 -53248 -42315 -46772 -35296 -53661 -24037 -19854 -21785 -9321 -6102 -1191 -2182 -3869 -3459 -3668 -6401 -3483 -5828 -3576 -2485 -8540 -10453 -11724 -6842 -4008 -926 -2851 -5635 -5782 -5411 -3146 2343 2180 1649 1629 1823 2334 1964 2796 1820 2201 846 1086 2367 2761 2747 2569 2546 2345 1816 1042 499 236 770 1738 2355 2631 2843 1219 360 -303 -2541 1142 400 551 588 -57 -824 -1356 -2216 -3650 -2994 -2679 -2381 -1624 -1827 -1971 -909 -564 420 419 763 1192 878 590 -402 -734 -282 -784 -402 234 339 71 -422 -809 -830 -254 -368 -1203 -500 -419 389 1289 1351 1015 870 786 371 58 153 93 -27 -60 -276 -75 305 474 36 -226 -1237 -79 242 -418 -334 -452 -385 -111 -56 -168 -224 340 398 237 76 -107 -230 91 -733 -1197 -939 -849 -1122 -806 -1134 -925 -1190 -840 -1599 -617 -608 -843 -385 -279 -57 -114 -201 -188 -202 -365 -205 -383 -245 -176 -638 -760 -855 -520 -346 -90 -316 -653 -635 -609 -394 310 353 314 340 403 534 458 656 438 534 212 280 643 769 843 857 913 882 712 421 201 93 301 707 985 1234 1458 642 182 -151 -1334 646 245 368 405 -39 -534 -807 -1276 -1995 -1647 -1647 -1605 -1178 -1495 -1743 -794 -528 416 414 770 1192 889 556 -355 -657 -257 -756 -419 263 431 92 -542 -1020 -947 -284 -425 -1442 -629 -529 518 1845 2038 1598 1424 1267 572 87 221 136 -42 -94 -455 -124 485 729 55 -337 -1792 -114 344 -664 -563 -791 -707 -203 -109 -334 -453 699 833 498 155 -214 -438 175 SS 20250716T113015.2Z 9328.479342 225 1 49.98 2 73.81 75.29 43.33 222.99 0.00 1 0.00 1 0 17 6.697e-02 7.296e-03 5.360e-03 5.590e-04 4.545469e-01 2.867336e-04 5.189672e-03 -6.000000e+00 3.866224e-02 232.55 -2.00 3.43 -2.00 319.15 0.00e+00 1.660153e-03 7.181410e-05 8.004558e-04 -6.000000e+00 1.745463e-03 291.61 -2.00 20.00 -2.00 318.27 0.00e+00 3.524 0.001 302.00 328.00 3 1.0695e+00 8.0722e-04 4.2514e-02 -6.0000e+00 9.6897e-02 1.0050e-02 9.4259e-04 2.3660e-02 -6.0000e+00 1.0474e-01 -5.5261e-02 6.7894e-04 1.1568e-02 -6.0000e+00 6.2460e-02 1.9234e-02 3.5566e-04 3.3012e-03 -6.0000e+00 2.6570e-02 3.2029e-03 -1.4942e-04 1.5558e-05 3.4940e-05 -6.0000e+00 1.7912e-03 5.9751e-03 0.0000e+00 11 8 0 10 0 0 74.70 20.82 0.31 0.00598 0.00485 517 104 1 5 0 96.650 24.46 20.01 20.82 35.38 35.6 1020.83 -22676 -16911 -21274 -18415 -31204 -22837 -26175 -20018 -18702 -17196 -24583 -15826 -9066 -7386 -916 -3002 1042 162 773 65 -472 -275 -646 -868 -1901 -817 -4301 -5231 -6832 -2859 -2589 104 -1570 -3547 -4113 -4417 -2499 -76 1276 954 1366 1178 1394 1087 1800 926 1226 344 366 1302 1562 1619 1899 1643 1502 1472 275 265 59 736 1423 2153 2467 1938 759 129 -502 -756 1015 59 522 46 -134 -518 -1239 -1733 -2754 -2622 -2260 -2068 -1550 -1929 -2028 -920 -612 148 343 710 1019 845 667 -192 -314 -245 -549 -272 449 460 50 -442 -765 -755 -45 -305 -1125 -508 -325 366 1164 1254 976 755 736 402 121 326 29 -45 5 -317 -165 228 416 -1 -99 -992 -173 229 -424 -289 -513 -403 -112 78 -203 -140 359 435 99 43 -128 -263 120 -690 -534 -713 -551 -977 -671 -883 -725 -741 -699 -1104 -738 -481 -429 -59 -223 80 14 68 6 -44 -26 -65 -94 -222 -98 -529 -616 -799 -345 -328 15 -250 -581 -638 -704 -443 -16 319 258 402 366 449 355 590 310 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