File name: Pandora37s1_HamptonVA_20250718_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T235931.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20250718_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20250718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250718T104640.6Z 9330.449081 215 1 49.57 2 82.31 69.52 22.99 163.53 0.00 1 0.00 1 0 25 4.718e-01 3.033e-02 2.418e-01 8.440e-03 7.740371e-01 4.806495e-03 9.513479e-03 -6.000000e+00 2.781301e-01 232.49 -2.00 3.43 -2.00 321.82 0.00e+00 1.235749e-02 2.703772e-03 7.055405e-03 -6.000000e+00 1.476168e-02 291.65 -2.00 20.00 -2.00 321.21 0.00e+00 6.942 0.005 302.00 328.00 3 1.9118e+00 1.8958e-02 8.5467e-02 -6.0000e+00 6.9837e-01 7.6956e-01 2.4931e-02 5.1921e-02 -6.0000e+00 7.5791e-01 -1.0651e+00 2.0057e-02 2.6716e-02 -6.0000e+00 4.5068e-01 4.2804e-01 9.4579e-03 8.8342e-03 -6.0000e+00 1.9378e-01 3.4028e-05 -1.5936e-03 2.3396e-04 2.2727e-04 -6.0000e+00 1.3448e-02 6.0152e-03 0.0000e+00 12 8 8 10 0 0 29.38 20.78 0.72 0.00602 -0.00596 33 7 1 5 0 1501.970 24.35 20.01 20.78 33.63 35.8 1019.08 900000 -159000 900000 900000 -6989 900000 -41494 217083 -38263 900000 -46803 900000 -93688 84566 50802 10316 900000 900000 -4956 13953 -64766 32157 177999 -59097 84315 900000 -35476 -52998 -13898 -71152 88309 50943 -30310 41770 12631 54479 24256 900000 193639 37060 20910 61993 -12758 40156 47532 4370 156138 67881 55833 71637 74621 17906 75204 35785 52481 41807 30043 3292 17266 17104 11267 -2107 -5912 34603 33151 23799 17172 96 36949 17488 6837 24091 -1403 -13822 884 -6343 648 6519 -14421 -8657 8881 -10454 463 3251 -1204 265 -8408 1156 3273 -2402 913 -3660 -3502 4628 -10547 2329 -3471 -6172 -921 302 92 -4113 -3918 -741 1833 1677 -2480 -4875 2122 4699 849 736 113 1189 -3041 -27 2502 -729 -387 698 820 2752 1720 364 -2940 -1979 5211 1901 -1985 282 1677 -61 864 -1335 -720 -973 1587 1033 293 -1041 586 -135 -2054 900000 -10042 900000 900000 -77 900000 -591 1783 -545 900000 -718 900000 -3540 744 723 254 900000 900000 -171 397 -3866 687 1462 -3140 1138 900000 -1418 -2409 -434 -4520 1503 1395 -2108 1418 526 1566 956 900000 2045 1989 1420 2920 -1232 2463 2733 395 3390 3457 3364 3963 4455 1949 5313 3748 5116 4315 3486 483 2110 2064 1510 -361 -1211 5330 5396 4155 3201 22 6602 4346 1926 6209 -424 -4375 230 -1586 144 1433 -4546 -2933 2974 -4865 211 1524 -629 145 -5253 672 1855 -1382 474 -1873 -1751 2263 -6916 1590 -2795 -5927 -919 298 85 -3540 -3063 -567 1473 1431 -2348 -5133 2326 5739 1150 1071 167 1705 -4348 -37 3340 -1062 -598 1108 1280 4036 2454 510 -4117 -2660 6695 2668 -3158 504 3127 -125 1860 -3140 -1723 -2464 4003 2662 758 -2618 1423 -308 -4583 SS 20250718T110540.8Z 9330.462277 220 1 50.12 2 78.74 72.18 22.22 175.08 0.00 1 0.00 1 0 25 2.706e-01 1.040e-02 4.215e-02 1.815e-03 6.048513e-01 9.586436e-04 7.038953e-03 -6.000000e+00 1.561924e-01 232.49 -2.00 3.43 -2.00 320.63 0.00e+00 3.120961e-03 3.887643e-04 3.071628e-03 -6.000000e+00 7.054290e-03 291.65 -2.00 20.00 -2.00 319.88 0.00e+00 4.940 0.002 302.00 328.00 3 1.6762e+00 3.0625e-03 5.9984e-02 -6.0000e+00 3.9139e-01 7.1110e-02 3.9197e-03 3.5852e-02 -6.0000e+00 4.2307e-01 -1.6649e-01 3.4430e-03 1.7324e-02 -6.0000e+00 2.5232e-01 6.5520e-02 1.7128e-03 4.5470e-03 -6.0000e+00 1.0736e-01 3.8804e-04 -3.0759e-04 4.9807e-05 7.0007e-05 -6.0000e+00 7.2375e-03 5.6761e-03 0.0000e+00 12 8 8 10 0 0 25.94 20.81 0.42 0.00568 0.00336 136 27 1 5 0 368.450 24.46 20.01 20.81 34.56 35.9 1019.27 -104372 -133784 -86263 -82371 -92598 -61831 -71518 -93674 -61128 -75931 -92403 -49823 -26696 -54102 -16373 -32480 -6380 -10705 -16968 -9247 -30675 -8539 -15116 -10084 -13855 4352 -24690 -14133 -20346 -20565 -7304 -4166 -4890 -10414 -2991 -9168 -377 4706 8859 2640 1524 4072 2477 4240 3192 2762 5894 4067 1903 7497 6392 6400 5407 6363 4544 5680 2695 310 -168 1645 2355 1693 3124 3721 4260 749 1618 -9629 2758 2222 1612 2061 -136 -990 -2315 -2640 -4842 -3421 -4213 -2560 -1736 -2088 -2184 -884 -599 310 165 960 1605 604 625 -1015 -923 -944 -1500 -512 -224 -56 143 -569 -838 -1078 -702 -535 -1310 -367 -331 266 1373 1694 1345 907 902 405 -103 31 211 -120 54 -266 93 562 681 40 -331 -1414 -88 380 -613 -462 -395 -343 -64 -178 -245 -214 546 478 102 -33 -35 -357 156 -1607 -2820 -1283 -1094 -1262 -635 -899 -1675 -877 -1331 -1829 -838 -454 -1393 -356 -962 -161 -310 -560 -296 -1229 -276 -557 -385 -586 160 -1212 -600 -923 -1046 -389 -253 -312 -717 -198 -607 -26 374 827 308 198 550 355 609 471 419 883 641 320 1286 1145 1273 1185 1494 1142 1467 734 86 -45 435 651 525 1086 1425 1661 291 617 -3974 1131 1054 839 1104 -73 -504 -1088 -1120 -1981 -1417 -1999 -1416 -1107 -1413 -1606 -680 -493 271 142 841 1391 507 520 -802 -702 -746 -1341 -491 -248 -66 182 -719 -990 -1151 -736 -576 -1448 -424 -405 347 1828 2509 2082 1478 1461 631 -151 46 319 -181 87 -449 154 902 1057 60 -507 -2109 -126 561 -974 -822 -728 -670 -123 -367 -517 -475 1233 1102 237 -74 -74 -747 316 SS 20250718T111148.1Z 9330.466529 223 1 49.99 2 77.57 73.03 22.13 178.91 0.00 1 0.00 1 0 17 1.967e-01 9.103e-03 2.412e-02 1.288e-03 5.588003e-01 6.726977e-04 6.501381e-03 -6.000000e+00 1.135561e-01 232.49 -2.00 3.43 -2.00 320.27 0.00e+00 2.756237e-03 2.417756e-04 2.439606e-03 -6.000000e+00 5.128611e-03 291.65 -2.00 20.00 -2.00 319.47 0.00e+00 4.511 0.001 302.00 328.00 3 1.5339e+00 2.0615e-03 5.4567e-02 -6.0000e+00 2.8455e-01 3.1693e-02 2.5640e-03 3.1893e-02 -6.0000e+00 3.0758e-01 -1.1894e-01 2.1549e-03 1.5599e-02 -6.0000e+00 1.8344e-01 4.6676e-02 1.0934e-03 4.1972e-03 -6.0000e+00 7.8054e-02 7.0895e-04 -2.0211e-04 3.5589e-05 5.9111e-05 -6.0000e+00 5.2618e-03 5.5472e-03 0.0000e+00 11 8 0 10 0 0 59.39 20.82 0.38 0.00555 0.00403 197 39 1 5 0 253.720 24.46 20.01 20.82 34.81 35.8 1019.42 -72912 -85507 -52198 -60581 -72094 -67372 -50342 -63791 -44025 -60216 -72192 -38896 -30714 -42261 -12177 -18019 3614 -1490 -8015 -8029 -11999 -855 -6659 -8056 -7872 -1045 -16680 -14299 -15751 -8605 -3590 -3163 -3474 -7059 -4291 -6661 -2944 4086 5027 1639 2745 4052 2496 2750 2935 2090 4147 1947 831 3852 3681 3652 3537 3460 3118 3036 1817 402 309 589 2195 1829 3039 2986 2335 1001 -24 -4793 2359 1017 650 1107 -71 -948 -1743 -2465 -4234 -3556 -3211 -2370 -1768 -2080 -1809 -1056 -59 359 337 697 1483 815 719 -651 -995 -575 -1062 -441 95 300 -111 -605 -915 -958 -677 -425 -1278 -600 -446 501 1360 1699 1196 927 899 432 44 68 135 -141 57 -230 19 568 510 72 -302 -1298 -142 148 -574 -266 -552 -498 -105 21 -389 -195 413 500 222 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