File name: Pandora37s1_HamptonVA_20250804_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250819T225428.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20250804_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20250804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250804T124047.5Z 9347.528328 108 1 44.43 2 62.21 88.99 169.40 328.20 0.00 1 0.00 1 0 17 2.274e-02 1.143e-02 7.212e-03 2.258e-03 2.819565e-01 1.149828e-03 3.243999e-03 -6.000000e+00 1.311335e-02 231.93 -2.00 3.43 -2.00 317.38 0.00e+00 1.508681e-03 1.719934e-04 1.467484e-04 -6.000000e+00 5.936784e-04 292.02 -2.00 20.00 -2.00 316.47 0.00e+00 2.134 0.000 302.00 328.00 3 5.1363e+00 3.0649e-03 2.5823e-02 -6.0000e+00 3.2811e-02 1.5775e-02 3.4487e-03 1.4423e-02 -6.0000e+00 3.5461e-02 -1.6169e-02 2.0626e-03 6.9634e-03 -6.0000e+00 2.1163e-02 9.3463e-04 1.0214e-03 2.1299e-03 -6.0000e+00 9.0365e-03 2.6117e-04 -2.3929e-04 6.3998e-05 2.1248e-05 -6.0000e+00 6.0758e-04 -5.8077e-03 0.0000e+00 12 9 9 12 1 1 99.96 20.66 0.37 -0.00581 -0.00761 17 4 1 5 0 2467.900 24.25 20.01 20.66 32.10 35.5 1022.80 2452 -5902 -1728 -898 -12462 -1150 -3580 -5478 -1705 -3619 -4272 3959 -1852 2100 -108 -1532 6004 5522 1371 -388 -176 1180 883 -587 897 2970 -3283 -2470 -3700 -4143 -87 1935 -4405 -2482 -2391 -3337 -4053 1222 1808 -766 -889 212 -383 418 1210 -738 2834 654 -574 1334 1196 1593 1855 1172 1799 1856 800 -3 -144 901 1647 943 1287 2770 1301 -168 -1063 -8674 2772 564 305 1399 400 -1038 -753 -2020 -2921 -1924 -2941 -2406 -1570 -2502 -1679 -911 -347 204 315 1179 1390 532 975 -313 -959 341 -1475 143 487 212 506 190 -287 -1089 -586 -288 -528 108 -116 -132 1078 1909 1076 1310 897 398 -193 41 269 -689 -334 -368 106 168 196 -130 -551 -1029 158 -311 -1042 -708 -259 -789 18 -165 -125 -87 824 680 340 198 130 -464 -257 256 -712 -201 -95 -1334 -110 -379 -660 -216 -478 -561 513 -288 362 -22 -333 1268 1220 326 -97 -44 291 225 -159 251 839 -965 -680 -982 -1120 -24 575 -1484 -825 -746 -1055 -1417 470 806 -391 -483 118 -219 239 688 -427 1572 364 -319 741 700 982 1193 788 1230 1290 567 -2 -101 626 1174 717 1040 2316 1089 -133 -811 -6941 2165 491 282 1319 378 -963 -661 -1655 -2248 -1430 -2305 -2059 -1453 -2497 -1740 -970 -387 237 378 1439 1695 636 1104 -336 -977 339 -1551 160 584 272 675 251 -365 -1315 -680 -342 -664 140 -155 -182 1527 2805 1646 2020 1358 580 -267 55 357 -947 -478 -550 161 253 290 -188 -773 -1404 208 -410 -1442 -1026 -387 -1206 28 -261 -204 -148 1409 1181 595 343 220 -771 -420 SS 20250804T124554.5Z 9347.531881 111 1 50.00 2 61.19 89.76 169.87 333.56 0.00 1 0.00 1 0 17 1.431e-02 8.032e-03 1.422e-03 5.324e-04 2.699827e-01 2.714915e-04 3.127129e-03 -6.000000e+00 8.251413e-03 231.93 -2.00 3.43 -2.00 317.01 0.00e+00 8.901095e-04 3.676090e-05 2.018792e-04 -6.000000e+00 3.736576e-04 292.02 -2.00 20.00 -2.00 316.11 0.00e+00 2.065 0.000 302.00 328.00 3 2.6566e+00 7.1825e-04 2.4895e-02 -6.0000e+00 2.0646e-02 -1.3445e-02 8.0528e-04 1.3757e-02 -6.0000e+00 2.2315e-02 -1.1025e-02 4.7266e-04 6.6346e-03 -6.0000e+00 1.3318e-02 1.9009e-03 2.2908e-04 1.8444e-03 -6.0000e+00 5.6848e-03 3.4491e-03 -2.0149e-04 1.5049e-05 1.9929e-05 -6.0000e+00 3.8242e-04 -4.0661e-03 0.0000e+00 11 8 0 10 0 0 99.97 20.67 0.36 -0.00407 -0.00558 388 78 1 5 0 128.840 24.25 20.02 20.67 32.54 35.5 1022.97 508 255 -961 -4193 -4131 -5087 -1940 -2287 -1652 -3921 -3926 -2190 -1063 658 1125 965 1925 1834 1656 2356 472 1925 1196 1040 166 -110 -1498 -1971 -2691 -1311 -625 216 -976 -3723 -3770 -3863 -2269 -602 134 201 514 657 315 751 829 389 177 -156 -536 601 815 988 1208 1044 1183 1084 438 302 408 537 1338 1684 2079 1530 217 -282 -1112 -704 643 -17 119 204 76 -137 -1001 -1470 -2611 -2514 -2238 -2244 -1700 -1925 -1824 -925 -417 190 563 692 1131 745 561 -354 -501 -254 -691 -274 394 657 228 -55 -496 -678 -222 -182 -1076 -324 -178 291 1228 1301 1305 1009 936 466 174 -52 -249 -162 -2 -222 -142 146 265 39 -31 -1013 -594 -28 -650 -389 -597 -543 -208 -48 -157 -47 388 501 286 203 -24 -339 21 68 37 -140 -570 -505 -624 -251 -336 -264 -657 -648 -378 -193 136 263 245 502 500 470 689 132 565 342 316 53 -36 -495 -610 -791 -384 -196 73 -362 -1420 -1336 -1380 -890 -258 69 111 305 383 190 452 499 235 105 -96 -326 367 501 650 839 724 842 789 326 223 296 388 1000 1357 1726 1354 192 -229 -895 -557 518 -15 113 202 74 -129 -882 -1224 -2103 -1944 -1834 -1980 -1598 -1910 -1924 -1015 -467 218 678 856 1394 884 643 -390 -507 -263 -730 -305 466 826 305 -72 -638 -802 -259 -220 -1372 -417 -239 392 1724 1879 1991 1508 1400 676 233 -68 -327 -222 -2 -324 -211 214 379 56 -43 -1376 -764 -38 -895 -553 -864 -808 -315 -76 -253 -77 650 858 496 344 -39 -555 33 SS 20250804T125126.5Z 9347.535723 114 1 49.97 2 60.09 90.59 170.29 339.85 0.00 1 0.00 1 0 17 1.372e-02 8.195e-03 2.878e-03 1.036e-03 2.615475e-01 5.276087e-04 3.036230e-03 -6.000000e+00 7.913314e-03 231.93 -2.00 3.43 -2.00 317.09 0.00e+00 9.124239e-04 7.305614e-05 2.065239e-04 -6.000000e+00 3.583451e-04 292.02 -2.00 20.00 -2.00 316.18 0.00e+00 1.997 0.000 302.00 328.00 3 3.9717e+00 1.3987e-03 2.4092e-02 -6.0000e+00 1.9800e-02 -1.1746e-02 1.5703e-03 1.3347e-02 -6.0000e+00 2.1400e-02 -8.6203e-03 9.2619e-04 6.4462e-03 -6.0000e+00 1.2772e-02 4.3400e-04 4.5108e-04 1.7993e-03 -6.0000e+00 5.4519e-03 1.0017e-03 -2.0961e-04 2.9409e-05 1.9331e-05 -6.0000e+00 3.6675e-04 -4.1183e-03 0.0000e+00 11 8 0 10 0 0 99.96 20.68 0.27 -0.00412 -0.00569 138 28 1 5 0 362.100 24.25 20.02 20.68 32.89 35.5 1022.98 -180 -882 -1494 -1578 -3427 -3969 -934 -2716 567 -2816 -4467 -1795 -46 -61 1661 1238 2594 1820 1383 1853 596 1515 823 769 -283 336 -2300 -1873 -2506 -1005 -697 375 -1482 -4306 -3632 -4264 -2821 -6 327 -204 551 588 87 632 610 184 479 -248 -471 686 822 1033 1293 1018 1225 1159 469 314 429 518 1252 1470 2047 1647 315 -190 -809 -963 1016 8 246 390 58 -436 -1028 -1323 -2857 -2296 -2517 -2290 -1790 -2078 -1847 -920 -448 154 362 845 1189 761 688 -413 -394 -132 -709 -248 376 433 226 22 -475 -692 -385 -177 -1019 -226 -53 223 1237 1467 1259 946 1107 357 203 -161 -268 -460 36 -197 -139 114 263 -13 -82 -1186 -443 -45 -756 -430 -623 -577 -144 63 -164 26 524 559 287 24 13 -313 11 -23 -121 -205 -196 -413 -478 -119 -375 83 -436 -692 -287 -8 -13 364 295 631 466 369 510 167 418 237 234 -91 111 -766 -578 -733 -292 -217 125 -520 -1551 -1270 -1509 -1043 -3 158 -109 315 350 53 387 374 113 287 -147 -274 400 510 656 865 718 885 856 340 226 315 381 911 1155 1669 1427 272 -157 -628 -738 827 7 230 378 56 -406 -927 -1117 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