File name: Pandora133s1_Heidelberg_20240702_L2Fit_fout2c4d20240611p1-8.txt File generation date: 20250704T130643.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Andre Butz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 133 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora133_OF_v1d20240405.txt Instrument calibration file used: Pandora133s1_CF_v4d20240611.txt Level 1 file used: Pandora133s1_Heidelberg_20240702_L1_smca1c4d20240611p1-8.txt Full location name: Institute of Environmental Physics, Heidelberg University Short location name: Heidelberg Country of location: Germany Location latitude [deg]: 49.4173 Location longitude [deg]: 8.6746 Location altitude [m]: 144 Local noon date: 20240702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1331 305.2741 305.4152 305.5562 305.6973 305.8383 305.9793 306.1203 306.2613 306.4023 306.5432 306.6842 306.8251 306.9661 307.1070 307.2479 307.3888 307.5297 307.6705 307.8114 307.9523 308.0931 308.2339 308.3747 308.5155 308.6563 308.7971 308.9379 309.0787 309.2194 309.3601 309.5009 309.6416 309.7823 309.9230 310.0636 310.2043 310.3450 310.4856 310.6262 310.7669 310.9075 311.0481 311.1886 311.3292 311.4698 311.6103 311.7509 311.8914 312.0319 312.1724 312.3129 312.4534 312.5939 312.7343 312.8748 313.0152 313.1556 313.2960 313.4364 313.5768 313.7172 313.8576 313.9979 314.1383 314.2786 314.4189 314.5592 314.6995 314.8398 314.9801 315.1203 315.2606 315.4008 315.5410 315.6813 315.8215 315.9617 316.1018 316.2420 316.3822 316.5223 316.6624 316.8026 316.9427 317.0828 317.2229 317.3629 317.5030 317.6431 317.7831 317.9231 318.0631 318.2031 318.3431 318.4831 318.6231 318.7631 318.9030 319.0429 319.1829 319.3228 319.4627 319.6026 319.7424 319.8823 320.0222 320.1620 320.3018 320.4417 320.5815 320.7213 320.8611 321.0008 321.1406 321.2803 321.4201 321.5598 321.6995 321.8392 321.9789 322.1186 322.2583 322.3979 322.5376 322.6772 322.8168 322.9564 323.0960 323.2356 323.3752 323.5148 323.6543 323.7939 323.9334 324.0729 324.2124 324.3519 324.4914 324.6309 324.7703 324.9098 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240702T045818.2Z 8949.207155 164 1 47.63 2 77.56 69.07 46.32 109.76 0.00 1 0.00 1 0 17 3.852e-01 1.408e-02 2.251e-01 6.001e-03 6.470984e-01 3.332900e-03 8.158531e-03 -6.000000e+00 2.264178e-01 233.49 -2.00 3.74 -2.00 321.22 0.00e+00 3.004675e-03 1.563015e-03 4.827479e-03 -6.000000e+00 1.056182e-02 282.55 -2.00 20.00 -2.00 320.66 0.00e+00 4.508 0.002 302.00 328.00 3 4.0449e+00 1.1289e-02 6.2123e-02 -6.0000e+00 5.7180e-01 7.2293e-02 1.5235e-02 4.6884e-02 -6.0000e+00 6.1855e-01 -1.3332e-01 1.5074e-02 2.3755e-02 -6.0000e+00 3.6528e-01 5.0743e-02 7.1958e-03 6.5913e-03 -6.0000e+00 1.5576e-01 5.4428e-05 1.6544e-04 1.7642e-04 1.2130e-04 -6.0000e+00 1.0618e-02 1.4085e-02 0.0000e+00 12 9 8 11 8 0 99.89 22.34 0.31 0.01409 0.01533 48 13 4 8 0 992.190 19.98 22.34 20.28 26.21 26.41 1.8 874.54 900000 -139555 -218531 -82232 -112814 -21876 -198795 -121940 900000 -111475 900000 -80486 -61745 -58438 -57756 -31505 82161 275 -16868 -15924 -37565 -74753 -8746 -43161 26582 -42691 -27558 15531 -11535 21682 -22732 -15978 -394 -5908 -12648 -2522 -29699 3566 -3695 1526 -8928 1226 7604 6526 -2646 12505 -6521 7552 5992 7023 5817 14312 3143 9906 4778 9660 989 9873 -4504 4478 -4237 5588 2478 6491 -2999 4361 -3600 3554 1828 7464 1833 5923 1487 1915 -4404 2439 -5359 907 -3962 75 -4343 4113 -3612 -225 -1736 937 -661 2674 -1373 2712 -730 -284 -4203 -221 -3069 588 528 2145 -1770 195 -1570 -904 -2325 201 -3174 -979 -607 -442 -56 1463 220 930 -781 4 -1154 652 -1171 1338 259 690 644 2482 499 666 -232 -818 166 1089 43 659 -1301 -581 -695 239 -21 195 478 290 344 189 -1166 -442 900000 -1476 -4960 -481 -825 -128 -3947 -1321 900000 -1274 900000 -920 -755 -870 -1040 -509 498 4 -308 -304 -874 -2569 -175 -1290 436 -1408 -778 282 -285 457 -866 -667 -16 -245 -543 -107 -1865 198 -267 121 -840 111 668 595 -268 1126 -723 769 650 835 779 1959 515 1648 865 1744 194 1752 -894 838 -929 1257 653 1766 -876 1173 -1072 1063 634 2748 749 2356 590 705 -1551 746 -1756 305 -1631 34 -2377 2296 -2294 -148 -1229 681 -504 1992 -1036 1874 -486 -182 -2790 -155 -2528 535 543 2395 -2062 214 -1614 -845 -2191 196 -3396 -1068 -708 -554 -76 2181 351 1487 -1233 5 -1682 930 -1773 2074 425 1130 1021 3767 752 967 -328 -1135 234 1676 74 1210 -2589 -1194 -1498 541 -49 474 1183 719 831 435 -2596 -949 SS 20240702T051455.2Z 8949.218695 172 1 47.30 2 75.01 72.00 43.83 113.74 0.00 1 0.00 1 0 17 2.100e-01 8.449e-03 7.904e-02 2.688e-03 5.550122e-01 1.439466e-03 6.849790e-03 -6.000000e+00 1.232286e-01 233.49 -2.00 3.74 -2.00 320.55 0.00e+00 1.735132e-03 5.527577e-04 2.345842e-03 -6.000000e+00 5.316347e-03 282.55 -2.00 20.00 -2.00 319.93 0.00e+00 3.790 0.001 302.00 328.00 3 3.6495e+00 4.4518e-03 5.0143e-02 -6.0000e+00 3.1046e-01 -5.0007e-03 5.6274e-03 3.4199e-02 -6.0000e+00 3.3543e-01 -2.4061e-02 5.2291e-03 1.7297e-02 -6.0000e+00 1.9877e-01 2.3218e-03 2.6083e-03 4.9472e-03 -6.0000e+00 8.3969e-02 1.7658e-04 5.7494e-05 7.8202e-05 6.8840e-05 -6.0000e+00 5.7541e-03 1.2837e-02 0.0000e+00 11 8 0 10 0 0 99.91 22.38 0.19 0.01284 0.01327 69 18 4 8 0 685.430 20.00 22.38 20.91 26.32 26.51 1.7 876.40 -63981 -79308 -88784 -67187 -106887 -22215 -76806 -41383 -33475 -71686 -30302 -39508 -48526 -45644 -22426 -41 12980 -2557 -10537 -7132 -31676 -25744 -11243 -13942 -3546 -7661 -7348 -3801 -13065 2697 -14918 -2578 -12583 -3776 -11241 -3836 -5509 930 -2951 -642 -1525 144 -565 4226 2758 6414 -3694 3410 -640 3288 929 5062 1202 3834 1798 4189 832 1551 -937 820 1212 2803 2501 3391 -661 1382 -1506 193 745 2361 -344 2623 939 243 -1485 -1867 -4076 -2161 -2398 -1269 -1618 62 -2304 -1085 -456 879 76 1679 273 1208 -75 -830 -1804 219 -451 -22 635 1473 168 -349 -1557 -1468 -922 -704 -1885 -1047 -580 -80 741 1284 772 421 -279 -361 -491 -38 -335 603 389 90 301 1007 556 433 363 -527 331 19 -120 87 -705 -631 -579 -83 83 -21 720 525 106 106 -420 -638 -600 -952 -1191 -683 -1506 -149 -972 -430 -359 -1158 -354 -603 -998 -1124 -530 -1 276 -69 -323 -221 -1252 -989 -411 -562 -139 -326 -306 -148 -567 116 -876 -154 -916 -248 -774 -265 -446 85 -340 -83 -213 21 -86 625 418 962 -618 553 -112 605 193 1105 297 987 487 1148 238 436 -265 233 366 935 930 1329 -263 527 -590 80 346 1201 -189 1423 497 121 -685 -799 -1742 -971 -1243 -744 -1076 44 -1757 -874 -388 780 69 1534 249 1026 -61 -642 -1400 180 -414 -23 728 1808 211 -422 -1779 -1557 -960 -779 -2222 -1275 -744 -107 1074 1999 1256 689 -447 -552 -724 -56 -509 948 641 149 491 1597 860 651 531 -754 476 30 -202 156 -1336 -1236 -1173 -176 183 -47 1640 1204 239 229 -883 -1310 SS 20240702T052625.9Z 8949.226689 174 1 47.80 2 73.22 74.03 42.15 116.66 0.00 1 0.00 1 0 17 1.356e-01 7.590e-03 4.778e-02 2.060e-03 5.016959e-01 1.095346e-03 6.176982e-03 -6.000000e+00 7.959601e-02 233.49 -2.00 3.74 -2.00 320.30 0.00e+00 1.259721e-03 3.830084e-04 1.797473e-03 -6.000000e+00 3.433233e-03 282.55 -2.00 20.00 -2.00 319.65 0.00e+00 3.409 0.001 302.00 328.00 3 3.4609e+00 3.2985e-03 4.4897e-02 -6.0000e+00 2.0053e-01 -2.5240e-02 4.0593e-03 3.0144e-02 -6.0000e+00 2.1665e-01 -1.4173e-03 3.5908e-03 1.5090e-02 -6.0000e+00 1.2838e-01 -6.1573e-03 1.8197e-03 4.2694e-03 -6.0000e+00 5.4244e-02 3.2510e-04 1.1154e-04 6.0980e-05 5.4877e-05 -6.0000e+00 3.7160e-03 1.1710e-02 0.0000e+00 11 9 0 11 8 0 99.50 22.41 0.25 0.01171 0.01255 153 41 4 8 0 310.370 20.01 22.41 21.28 26.32 26.51 1.7 879.67 -26376 -60834 -45819 -35065 -39204 -63243 -50063 -43206 -6467 -47578 -16434 -46686 -11630 -21980 -3850 -10844 9405 -10150 291 -11173 -2201 -14873 4364 -15394 1342 -12724 1136 -16394 -2993 -4936 3136 -6702 -1077 -9253 786 -5973 -4790 -4217 3264 -2894 772 -3082 2695 -1159 3083 -412 -318 -2535 949 396 3514 567 3343 -261 2229 1801 2331 -349 649 -1163 3235 2123 4079 1430 1428 -765 -898 -812 2500 1247 1671 623 1217 -55 -269 -1901 -2263 -1944 -695 -2167 -1102 -1485 -1497 -1349 246 65 749 758 1008 578 937 -971 -681 -863 -207 -321 1178 526 160 -414 -1036 -1806 -657 -609 -1444 -1341 -479 -336 668 716 767 113 284 -610 -313 -86 -6 288 862 -84 598 770 681 200 386 -788 372 536 -194 -21 -489 -661 -526 -7 14 72 783 273 60 -2 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