File name: Pandora133s1_Heidelberg_20241002_L2Fit_fout2c3d20240611p1-8.txt File generation date: 20241002T232106.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Andre Butz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 133 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora133_OF_v2d20240405.txt Instrument calibration file used: Pandora133s1_CF_v3d20240611.txt Level 1 file used: Pandora133s1_Heidelberg_20241002_L1_smca1c3d20240611p1-8.txt Full location name: Institute of Environmental Physics, Heidelberg University Short location name: Heidelberg Country of location: Germany Location latitude [deg]: 49.4173 Location longitude [deg]: 8.6746 Location altitude [m]: 144 Local noon date: 20241002 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.0728 305.2141 305.3553 305.4966 305.6378 305.7790 305.9202 306.0614 306.2026 306.3438 306.4849 306.6261 306.7672 306.9083 307.0494 307.1905 307.3316 307.4727 307.6138 307.7548 307.8959 308.0369 308.1779 308.3189 308.4599 308.6009 308.7418 308.8828 309.0238 309.1647 309.3056 309.4465 309.5874 309.7283 309.8692 310.0100 310.1509 310.2917 310.4326 310.5734 310.7142 310.8550 310.9958 311.1365 311.2773 311.4180 311.5588 311.6995 311.8402 311.9809 312.1216 312.2623 312.4029 312.5436 312.6842 312.8249 312.9655 313.1061 313.2467 313.3872 313.5278 313.6684 313.8089 313.9494 314.0900 314.2305 314.3710 314.5115 314.6519 314.7924 314.9328 315.0733 315.2137 315.3541 315.4945 315.6349 315.7753 315.9157 316.0560 316.1964 316.3367 316.4770 316.6173 316.7576 316.8979 317.0382 317.1784 317.3187 317.4589 317.5991 317.7393 317.8795 318.0197 318.1599 318.3001 318.4402 318.5804 318.7205 318.8606 319.0007 319.1408 319.2809 319.4209 319.5610 319.7010 319.8411 319.9811 320.1211 320.2611 320.4011 320.5410 320.6810 320.8209 320.9609 321.1008 321.2407 321.3806 321.5205 321.6604 321.8002 321.9401 322.0799 322.2198 322.3596 322.4994 322.6392 322.7789 322.9187 323.0585 323.1982 323.3379 323.4776 323.6173 323.7570 323.8967 324.0364 324.1760 324.3157 324.4553 324.5949 324.7346 324.8741 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241002T075019.5Z 9041.326615 102 1 48.83 2 69.06 123.80 65.70 126.68 0.00 1 0.00 1 0 17 4.664e-02 7.048e-03 1.052e-02 8.918e-04 4.136556e-01 4.564099e-04 5.088605e-03 -6.000000e+00 2.674657e-02 226.38 -2.00 3.74 -2.00 319.39 0.00e+00 1.231807e-03 1.205229e-04 6.998812e-04 -6.000000e+00 1.162750e-03 278.86 -2.00 20.00 -2.00 318.77 0.00e+00 2.770 0.000 302.00 328.00 3 2.6575e+00 1.2782e-03 3.5397e-02 -6.0000e+00 6.6326e-02 -1.0593e-02 1.4938e-03 2.2549e-02 -6.0000e+00 7.2012e-02 9.9988e-03 1.1643e-03 1.1700e-02 -6.0000e+00 4.2830e-02 -1.1586e-02 6.1246e-04 4.0055e-03 -6.0000e+00 1.8353e-02 1.4771e-03 2.4583e-03 2.6313e-05 4.2868e-05 -6.0000e+00 1.2737e-03 2.6153e-02 0.0000e+00 11 8 0 10 0 0 99.81 22.42 0.13 0.02615 0.04463 421 122 1 8 0 110.470 20.01 22.42 19.50 26.32 26.51 1.8 869.18 -18916 -8770 -9424 -12278 -22644 -19059 -17108 -11395 -11346 -13413 -13951 -11277 -7420 -5260 -3588 -1751 -1173 -893 -124 17 -2683 -2339 -2036 -934 -1431 -2390 -2149 -3403 -3095 -693 -840 -94 189 -2727 -5277 -5236 -5055 -2875 -755 -1123 -610 -357 267 192 1141 834 148 109 -214 427 898 964 1468 957 947 1204 750 707 506 328 1179 1753 2640 2059 400 332 -713 -286 860 883 860 1037 849 782 -62 -1045 -2368 -1881 -1455 -1808 -1401 -1762 -2142 -1234 -526 7 494 1105 1141 883 895 -339 -836 -517 -501 -173 1046 703 79 -91 -925 -1625 -713 -600 -1335 -913 -656 -423 536 847 860 238 270 -506 -400 -174 -170 273 443 -145 201 351 558 406 373 -688 630 758 233 214 -290 -412 -288 145 117 -116 706 251 -157 -136 -329 -848 -474 -218 -241 -296 -557 -464 -452 -322 -357 -450 -481 -428 -327 -272 -216 -115 -82 -67 -10 1 -227 -199 -184 -90 -146 -256 -226 -341 -303 -72 -98 -12 27 -397 -745 -777 -857 -571 -178 -280 -163 -100 77 55 330 243 43 32 -64 135 310 359 584 406 415 541 342 317 223 147 557 908 1496 1238 236 185 -394 -163 547 632 605 738 636 548 -40 -609 -1329 -1086 -948 -1358 -1092 -1514 -1950 -1185 -539 8 550 1240 1251 906 846 -301 -721 -467 -506 -197 1232 908 104 -113 -1158 -1879 -807 -730 -1618 -1154 -875 -600 813 1292 1370 377 437 -768 -568 -242 -246 417 718 -241 328 556 852 589 518 -995 899 1083 365 360 -517 -709 -514 274 234 -239 1475 531 -325 -268 -624 -1565 SS 20241002T075548.5Z 9041.330422 105 1 10.75 2 68.32 125.04 65.03 127.96 0.00 1 0.00 1 0 17 3.998e-02 7.664e-03 6.531e-03 7.952e-04 3.997122e-01 4.035913e-04 4.910462e-03 -6.000000e+00 2.294170e-02 226.38 -2.00 3.74 -2.00 318.86 0.00e+00 1.369854e-03 9.144748e-05 5.714899e-04 -6.000000e+00 9.968151e-04 278.86 -2.00 20.00 -2.00 318.23 0.00e+00 2.683 0.000 302.00 328.00 3 1.2688e+00 1.1059e-03 3.4138e-02 -6.0000e+00 5.6892e-02 -4.3059e-03 1.2724e-03 2.1550e-02 -6.0000e+00 6.1756e-02 -3.5374e-03 9.2408e-04 1.1080e-02 -6.0000e+00 3.6731e-02 -4.0404e-03 4.8885e-04 3.8639e-03 -6.0000e+00 1.5750e-02 6.5518e-03 3.0058e-03 2.3083e-05 3.9345e-05 -6.0000e+00 1.0917e-03 2.2058e-02 0.0000e+00 12 9 1 12 1 1 70.35 22.43 0.16 0.02206 0.04464 194 261 2 8 0 51.400 19.99 22.43 19.96 26.32 26.51 1.7 870.70 -12204 -6453 -9603 -10654 -15008 -15414 -14099 -10623 -14681 -11429 -15167 -11849 -7559 -3775 -3159 -417 -1041 206 562 -188 -1364 -734 -549 -1064 -751 -980 -907 -2981 -3127 -1638 -765 746 122 -3812 -4332 -3979 -4295 -2063 -904 -463 -583 130 468 706 939 950 577 275 -750 623 733 817 1595 1155 1460 1307 823 367 448 737 933 1757 2747 2304 500 489 -988 -494 688 471 916 753 741 660 -152 -913 -2121 -1989 -1476 -1797 -1409 -2007 -2120 -1372 -606 -92 427 1143 1138 860 837 -398 -746 -444 -484 -145 1029 748 129 -181 -1038 -1614 -650 -672 -1337 -872 -700 -319 673 884 892 298 204 -496 -327 -136 -92 495 563 -166 299 529 531 339 333 -710 644 759 202 285 -285 -383 -356 206 119 -85 733 263 -282 -212 -405 -861 -440 -241 -375 -385 -519 -547 -544 -448 -715 -560 -786 -668 -490 -256 -251 -36 -96 20 57 -20 -148 -80 -63 -132 -98 -133 -121 -381 -391 -218 -113 121 22 -704 -759 -729 -902 -507 -265 -142 -193 45 165 251 335 341 206 99 -277 240 308 370 767 591 767 706 452 199 238 395 532 1010 1723 1527 325 299 -600 -310 480 370 708 591 608 507 -107 -581 -1404 -1356 -1045 -1465 -1197 -1882 -2099 -1434 -631 -101 483 1302 1267 897 860 -384 -697 -435 -527 -166 1312 980 171 -229 -1305 -1877 -741 -823 -1758 -1121 -950 -458 972 1376 1448 482 314 -758 -467 -190 -133 759 864 -262 463 796 818 497 467 -963 917 1090 318 453 -479 -663 -641 369 226 -167 1454 501 -555 -398 -732 -1514 SS 20241002T080051.2Z 9041.333925 107 1 48.32 2 67.66 126.19 64.42 129.15 0.00 1 0.00 1 0 17 3.727e-02 7.614e-03 4.576e-03 5.379e-04 3.916423e-01 2.721128e-04 4.827493e-03 -6.000000e+00 2.137285e-02 226.38 -2.00 3.74 -2.00 318.93 0.00e+00 1.186553e-03 6.297511e-05 5.945655e-04 -6.000000e+00 9.292081e-04 278.86 -2.00 20.00 -2.00 318.29 0.00e+00 2.608 0.000 302.00 328.00 3 2.0056e+00 7.4729e-04 3.3324e-02 -6.0000e+00 5.3000e-02 -3.3056e-03 8.6096e-04 2.1165e-02 -6.0000e+00 5.7545e-02 9.6038e-04 6.2889e-04 1.0828e-02 -6.0000e+00 3.4226e-02 -6.5710e-03 3.3221e-04 3.5934e-03 -6.0000e+00 1.4664e-02 3.3938e-03 2.3734e-03 1.5700e-05 3.7240e-05 -6.0000e+00 1.0179e-03 2.6737e-02 0.0000e+00 11 8 0 10 0 0 99.91 22.44 0.15 0.02674 0.04457 611 176 1 8 0 76.200 19.99 22.44 20.38 26.32 26.51 1.7 874.41 -11631 -6457 -7235 -11465 -15595 -14681 -15942 -10574 -9625 -9508 -12189 -9301 -7426 -3904 -2514 -1077 -996 513 -198 1423 -1079 -239 -1044 -470 -1206 -518 -2233 -2717 -3276 -908 -992 247 26 -2885 -4277 -4058 -4568 -2322 -1536 -444 -772 341 -8 834 748 979 68 185 -634 824 641 1145 1378 1213 1084 1523 606 622 -30 601 995 1973 2568 2398 363 519 -1011 -400 673 755 763 1088 839 866 -169 -981 -2494 -2084 -1756 -1833 -1544 -1751 -2264 -1122 -533 117 368 1214 1122 854 612 -536 -960 -463 -498 -128 957 796 79 -134 -1064 -1579 -774 -568 -1418 -754 -745 -185 593 972 911 357 242 -462 -429 -96 -133 319 504 -95 183 573 500 310 384 -676 575 732 243 174 -380 -462 -319 199 139 -49 717 298 -137 -176 -391 -870 -385 -222 -254 -423 -549 -524 -635 -451 -410 -463 -563 -468 -439 -266 -198 -93 -91 50 -20 149 -116 -26 -120 -58 -157 -70 -299 -343 -406 -118 -145 40 5 -517 -733 -729 -942 -559 -444 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