File name: Pandora133s1_Heidelberg_20250519_L2Fit_fout2c3d20240611p1-8.txt File generation date: 20250519T233029.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Andre Butz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 133 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora133_OF_v2d20240405.txt Instrument calibration file used: Pandora133s1_CF_v3d20240611.txt Level 1 file used: Pandora133s1_Heidelberg_20250519_L1_smca1c3d20240611p1-8.txt Full location name: Institute of Environmental Physics, Heidelberg University Short location name: Heidelberg Country of location: Germany Location latitude [deg]: 49.4173 Location longitude [deg]: 8.6746 Location altitude [m]: 144 Local noon date: 20250519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.0728 305.2141 305.3553 305.4966 305.6378 305.7790 305.9202 306.0614 306.2026 306.3438 306.4849 306.6261 306.7672 306.9083 307.0494 307.1905 307.3316 307.4727 307.6138 307.7548 307.8959 308.0369 308.1779 308.3189 308.4599 308.6009 308.7418 308.8828 309.0238 309.1647 309.3056 309.4465 309.5874 309.7283 309.8692 310.0100 310.1509 310.2917 310.4326 310.5734 310.7142 310.8550 310.9958 311.1365 311.2773 311.4180 311.5588 311.6995 311.8402 311.9809 312.1216 312.2623 312.4029 312.5436 312.6842 312.8249 312.9655 313.1061 313.2467 313.3872 313.5278 313.6684 313.8089 313.9494 314.0900 314.2305 314.3710 314.5115 314.6519 314.7924 314.9328 315.0733 315.2137 315.3541 315.4945 315.6349 315.7753 315.9157 316.0560 316.1964 316.3367 316.4770 316.6173 316.7576 316.8979 317.0382 317.1784 317.3187 317.4589 317.5991 317.7393 317.8795 318.0197 318.1599 318.3001 318.4402 318.5804 318.7205 318.8606 319.0007 319.1408 319.2809 319.4209 319.5610 319.7010 319.8411 319.9811 320.1211 320.2611 320.4011 320.5410 320.6810 320.8209 320.9609 321.1008 321.2407 321.3806 321.5205 321.6604 321.8002 321.9401 322.0799 322.2198 322.3596 322.4994 322.6392 322.7789 322.9187 323.0585 323.1982 323.3379 323.4776 323.6173 323.7570 323.8967 324.0364 324.1760 324.3157 324.4553 324.5949 324.7346 324.8741 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250519T043625.7Z 9270.191964 138 1 46.57 2 82.12 68.62 70.72 178.98 0.00 1 0.00 1 0 25 7.312e-01 2.016e-02 3.160e-01 6.852e-03 9.835399e-01 3.996811e-03 1.276713e-02 -6.000000e+00 4.272264e-01 231.24 -2.00 3.74 -2.00 322.28 0.00e+00 5.903338e-03 2.402403e-03 1.406871e-02 -6.000000e+00 1.931571e-02 277.92 -2.00 20.00 -2.00 321.88 0.00e+00 6.810 0.007 302.00 328.00 3 1.3923e+00 1.6003e-02 1.0886e-01 -6.0000e+00 1.0721e+00 8.3524e-01 2.3420e-02 9.1315e-02 -6.0000e+00 1.1599e+00 -1.1901e+00 2.3843e-02 4.9308e-02 -6.0000e+00 6.8718e-01 4.8389e-01 1.0760e-02 1.7174e-02 -6.0000e+00 2.9327e-01 5.9166e-05 2.5396e-03 1.8402e-04 4.8609e-04 -6.0000e+00 2.0192e-02 2.1590e-02 0.0000e+00 12 8 8 10 0 0 -1.91 22.07 0.24 0.02159 0.04067 101 29 4 8 0 460.920 19.98 22.07 15.11 26.11 26.21 1.9 840.03 -38204 -190464 900000 -148585 -139760 -229386 -119269 -233976 -170871 -164834 900000 -192994 -14838 -170793 -22651 -93483 280739 -33444 51476 -75912 -67325 -102944 125287 -42657 28488 -70795 -32648 -41799 11059 -13527 68103 -28355 15685 -30191 16543 -3150 -42964 -9958 68297 2682 86266 10046 100143 19862 429875 26048 11409 8668 38423 23012 42510 45388 37835 38422 63783 29799 54508 79184 39072 9831 29451 8705 32284 20219 23432 19914 25210 13209 19037 18663 18670 16508 11766 6608 5312 -1984 -3917 -3561 1192 2494 4213 13467 -2106 2445 1734 605 -319 2718 1542 1841 664 -279 -4753 -3343 -3821 -3728 -1739 -396 -1301 -1573 -2790 -2949 -2503 -2368 -3496 -5232 -1960 -1931 -189 14 -275 -1023 -374 -1059 -1413 312 -980 348 830 1591 1398 3017 2181 1138 1595 267 848 1393 269 607 -153 245 -604 109 -216 356 793 682 -98 -432 -1079 -1721 -255 -3710 900000 -1804 -1358 -4851 -941 -5599 -2490 -2302 900000 -4687 -99 -5323 -220 -2157 1875 -508 344 -1797 -1390 -2937 837 -725 242 -1633 -496 -660 107 -205 579 -757 305 -916 291 -69 -1565 -308 1161 101 1519 396 1642 723 2871 917 485 405 1446 1132 1961 2260 2228 2426 3253 2189 3111 3365 2348 782 2056 856 2940 2332 2689 2394 3030 1957 3063 3399 3593 3227 2257 1199 861 -318 -652 -670 262 657 1182 3920 -771 909 691 255 -140 1160 648 723 248 -113 -1936 -1540 -2122 -2481 -1348 -345 -1188 -1380 -2242 -2092 -1672 -1659 -2632 -4243 -1677 -1852 -207 18 -390 -1536 -560 -1558 -2021 441 -1466 541 1330 2481 2067 4180 2943 1496 2034 338 1119 2119 486 1250 -324 559 -1494 288 -608 1019 2281 1957 -270 -1099 -2548 -4187 SS 20250519T044514.6Z 9270.198085 142 1 48.51 2 80.78 70.22 70.69 181.11 0.00 1 0.00 1 0 25 7.781e-01 1.123e-02 2.321e-01 3.283e-03 8.822481e-01 1.872165e-03 1.170380e-02 -6.000000e+00 4.546242e-01 231.24 -2.00 3.74 -2.00 321.94 0.00e+00 3.631434e-03 1.056500e-03 1.189422e-02 -6.000000e+00 1.945992e-02 277.92 -2.00 20.00 -2.00 321.51 0.00e+00 5.929 0.004 302.00 328.00 3 1.2320e+00 7.0879e-03 9.4743e-02 -6.0000e+00 1.1409e+00 2.3069e-01 1.1366e-02 8.4946e-02 -6.0000e+00 1.2344e+00 -3.6696e-01 1.2882e-02 4.8875e-02 -6.0000e+00 7.3075e-01 1.4653e-01 5.7902e-03 1.6405e-02 -6.0000e+00 3.1013e-01 1.9121e-04 3.0016e-03 9.0499e-05 3.6147e-04 -6.0000e+00 2.1274e-02 2.1248e-02 0.0000e+00 12 8 8 10 0 0 24.05 22.08 0.29 0.02125 0.04380 208 60 2 8 0 223.580 20.01 22.08 15.99 26.11 26.32 1.9 846.90 -240131 -289622 -202753 -209280 -209880 -284081 -202729 -281571 -182339 -169752 -161432 -234777 -185881 -189007 -126290 -95038 -43058 -124214 -15383 -104957 900000 -86909 -78133 -98248 -88835 -105190 -54768 -87047 -57986 -56759 -32623 -43167 -2745 -38940 -34421 -34001 -49871 -24306 25791 -1248 319 -8809 4745 -98 25627 -4230 -749 -11356 4355 -3201 9694 13847 12353 12397 18412 8909 6107 13953 3612 -2131 814 3630 9216 7936 6999 6578 5514 3371 5049 5917 5705 7581 3417 854 1809 -1876 -6040 -4382 -1184 -1550 -834 2140 -722 -665 330 1086 1659 3185 2042 1322 1236 -1023 -3268 -2338 -2484 -1234 15 814 -47 -522 -1538 -2624 -1146 -1017 -1998 -2590 -752 -521 202 812 712 -2 -277 -913 -780 -313 -139 415 565 623 578 1473 1017 658 335 -706 388 631 208 161 -578 -325 -450 99 63 -32 922 535 -65 -217 -567 -884 -1139 -2610 -815 -849 -804 -2366 -848 -2887 -794 -711 -690 -2630 -1763 -2463 -1151 -774 -243 -1744 -81 -1383 900000 -988 -892 -1495 -1318 -1934 -620 -1331 -713 -841 -485 -871 -43 -880 -720 -751 -1483 -685 556 -41 11 -366 182 -4 841 -193 -34 -627 225 -200 615 949 948 1042 1542 857 607 1269 349 -219 88 434 1222 1184 1081 1030 919 629 1065 1394 1436 1883 839 198 373 -374 -1270 -1009 -318 -500 -312 874 -327 -318 167 575 902 1719 1087 670 594 -491 -1664 -1323 -1655 -947 14 794 -47 -513 -1396 -2158 -894 -837 -1764 -2409 -739 -562 243 1106 1051 -3 -427 -1375 -1139 -455 -209 654 913 1000 891 2169 1462 920 456 -955 535 980 369 316 -1235 -736 -1077 249 166 -85 2498 1463 -172 -542 -1346 -2018 SS 20250519T045827.4Z 9270.207262 147 1 49.59 2 78.74 72.60 70.75 184.30 0.00 1 0.00 1 0 25 5.758e-01 8.715e-03 8.544e-02 1.513e-03 7.631886e-01 8.358011e-04 1.004338e-02 -6.000000e+00 3.364152e-01 231.24 -2.00 3.74 -2.00 321.41 0.00e+00 4.034070e-03 4.140597e-04 7.976567e-03 -6.000000e+00 1.430065e-02 277.92 -2.00 20.00 -2.00 320.94 0.00e+00 4.947 0.002 302.00 328.00 3 9.8839e-01 2.8763e-03 7.3826e-02 -6.0000e+00 8.4424e-01 8.7295e-02 4.1914e-03 6.1430e-02 -6.0000e+00 9.1325e-01 -1.3228e-01 4.6152e-03 3.6529e-02 -6.0000e+00 5.4075e-01 4.4501e-02 2.1622e-03 1.2989e-02 -6.0000e+00 2.2933e-01 6.7674e-04 3.0157e-03 4.1817e-05 2.4380e-04 -6.0000e+00 1.5739e-02 2.1041e-02 0.0000e+00 11 8 0 10 0 0 12.34 22.12 0.14 0.02104 0.04370 439 127 2 8 0 105.940 19.97 22.12 17.33 26.11 26.32 1.9 855.07 -219072 -202024 -157402 -104777 -198891 -204387 -200716 -173744 -169468 -157738 -163206 -136716 -137453 -98075 -113549 -50089 -39464 -37553 -48965 -42518 -42425 -48462 -42496 -46232 -49866 -35339 -49813 -39402 -44409 -18899 -29237 -17818 -13765 -16301 -21142 -17281 -15455 -4890 -1730 2223 -1245 -2929 1119 2108 2139 274 -1447 -912 -1328 4180 3340 5250 3500 4679 5289 5617 2525 4796 1640 831 1498 3650 4479 5254 3115 2402 390 1160 3102 3379 3001 2746 1858 611 -372 -1782 -3758 -3793 -1932 -1516 -1202 -861 -1806 -722 -133 462 937 1383 1752 1200 833 -778 -2350 -1680 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