File name: Pandora133s1_Heidelberg_20250623_L2Fit_fwvt1c3d20240611p1-8.txt
File generation date: 20250623T233523.9Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Andre Butz
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 133
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora133_OF_v2d20240405.txt
Instrument calibration file used: Pandora133s1_CF_v3d20240611.txt
Level 1 file used: Pandora133s1_Heidelberg_20250623_L1_smca1c3d20240611p1-8.txt
Full location name: Institute of Environmental Physics, Heidelberg University
Short location name: Heidelberg
Country of location: Germany
Location latitude [deg]: 49.4173
Location longitude [deg]: 8.6746
Location altitude [m]: 144
Local noon date: 20250623
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1646 1795
Nominal wavelengths inside fitting window [nm]: 492.1119 492.2330 492.3542 492.4753 492.5964 492.7175 492.8386 492.9596 493.0806 493.2017 493.3227 493.4437 493.5646 493.6856 493.8065 493.9274 494.0483 494.1692 494.2901 494.4110 494.5318 494.6526 494.7734 494.8942 495.0150 495.1357 495.2565 495.3772 495.4979 495.6186 495.7392 495.8599 495.9805 496.1011 496.2217 496.3423 496.4629 496.5834 496.7040 496.8245 496.9450 497.0655 497.1859 497.3064 497.4268 497.5472 497.6676 497.7880 497.9084 498.0287 498.1491 498.2694 498.3897 498.5100 498.6302 498.7505 498.8707 498.9909 499.1111 499.2313 499.3515 499.4716 499.5917 499.7119 499.8320 499.9520 500.0721 500.1921 500.3122 500.4322 500.5522 500.6722 500.7921 500.9121 501.0320 501.1519 501.2718 501.3917 501.5115 501.6314 501.7512 501.8710 501.9908 502.1106 502.2303 502.3501 502.4698 502.5895 502.7092 502.8288 502.9485 503.0681 503.1878 503.3074 503.4270 503.5465 503.6661 503.7856 503.9051 504.0246 504.1441 504.2636 504.3830 504.5025 504.6219 504.7413 504.8607 504.9800 505.0994 505.2187 505.3380 505.4573 505.5766 505.6959 505.8151 505.9343 506.0536 506.1727 506.2919 506.4111 506.5302 506.6494 506.7685 506.8876 507.0066 507.1257 507.2447 507.3637 507.4828 507.6017 507.7207 507.8397 507.9586 508.0775 508.1964 508.3153 508.4342 508.5530 508.6719 508.7907 508.9095 509.0283 509.1470 509.2658 509.3845 509.5032 509.6219 509.7406 509.8593 509.9779
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250623T040830.3Z 9305.172573 120 1 47.13 2 84.26 60.22 62.82 83.68 0.00 1 0.00 1 0 22 3.120e-03 3.091e-03 2.118e-04 2.115e-04 1.410133e+04 1.576594e+01 9.504703e+02 -6.000000e+00 1.835550e+02 281.63 -2.00 20.00 -2.00 505.37 0.00e+00 1.751761e-03 6.020416e-06 1.120824e-04 -6.000000e+00 8.935732e-05 281.63 -2.00 20.00 -2.00 500.81 0.00e+00 8.110033e-01 4.274988e-03 9.312381e-02 -6.000000e+00 6.395288e-02 233.37 -2.00 3.74 -2.00 502.35 0.00e+00 8.837 0.014 489.00 513.00 1 4.4192e+00 3.2860e-04 1.5116e-02 -6.0000e+00 4.9231e-03 -3.5119e-02 8.0746e-05 2.4296e-03 -6.0000e+00 1.2461e-03 6.1490e-03 9.1916e-04 2.3395e-05 9.6349e-05 -6.0000e+00 3.8573e-04 2.0468e-02 -9.7642e-05 10 0 0 10 0 0 86.27 23.81 0.86 0.02047 0.02684 209 60 1 2 0 223.290 20.00 23.81 28.70 27.35 27.67 1.4 920.94 -265 -54 177 139 239 567 685 584 456 321 268 27 -245 -182 -208 -252 -58 186 85 1 136 158 275 435 333 211 203 -93 -452 -410 -300 -382 46 227 -133 -299 -122 -128 -179 -87 -45 -14 117 282 244 228 140 72 -199 -481 -561 -658 -609 -360 -132 -143 -180 -89 83 194 416 383 282 221 156 -42 -51 -24 -283 -333 -245 -267 -132 13 -147 -437 -482 -333 -358 -271 -284 -355 -296 -103 -67 -312 -203 -59 82 149 364 586 567 352 273 164 -32 -190 -524 -753 -753 -572 -276 -179 -419 -453 -476 -286 5 184 55 52 220 381 442 638 631 367 119 83 0 80 396 413 233 250 161 11 180 86 -302 -289 -172 -384 82 317 67 94 223 272 260 342 325 247 167 32 -242 -323 -318 -240 -243 -51 170 133 234 564 688 589 458 320 264 26 -236 -175 -200 -246 -57 188 84 1 136 159 278 441 339 214 204 -92 -440 -406 -297 -383 45 229 -137 -309 -125 -130 -181 -88 -46 -15 122 284 247 230 141 74 -201 -475 -543 -654 -585 -351 -132 -146 -180 -90 83 196 421 388 286 224 156 -43 -51 -24 -281 -328 -242 -265 -132 13 -147 -435 -473 -324 -345 -261 -274 -346 -291 -102 -67 -314 -204 -59 82 150 367 572 571 350 264 154 -31 -176 -483 -695 -707 -534 -267 -179 -415 -452 -475 -284 5 184 56 53 226 393 443 644 643 375 121 83 0 82 399 418 237 255 164 11 184 87 -304 -289 -171 -384 83 324 67 97 232 287 267 354 338 256 173 34 -253 -334 -328 -249
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SQ 20250623T043054.2Z 9305.188128 127 1 27.44 2 81.04 64.25 59.27 87.56 0.00 1 0.00 1 0 22 2.634e-03 2.621e-03 1.131e-04 1.130e-04 1.046743e+04 8.120025e+00 7.161283e+02 -6.000000e+00 1.549326e+02 281.63 -2.00 20.00 -2.00 505.34 0.00e+00 1.340082e-03 3.203228e-06 8.657938e-05 -6.000000e+00 7.542357e-05 281.63 -2.00 20.00 -2.00 500.72 0.00e+00 5.481929e-01 2.292059e-03 7.143786e-02 -6.000000e+00 5.398086e-02 233.37 -2.00 3.74 -2.00 502.28 0.00e+00 6.078 0.005 489.00 513.00 1 3.0172e+00 1.7618e-04 1.0701e-02 -6.0000e+00 4.1554e-03 -2.6701e-02 4.3591e-05 1.8282e-03 -6.0000e+00 1.0518e-03 3.7928e-02 5.8012e-04 1.2803e-05 7.5915e-05 -6.0000e+00 3.2558e-04 3.0651e-02 -1.6137e-04 10 0 0 10 0 0 90.27 23.78 0.71 0.03065 0.03467 661 191 1 2 0 39.640 19.99 23.78 29.03 27.26 27.67 1.4 923.13 -202 -17 153 82 173 466 577 521 362 279 250 25 -142 -139 -169 -241 -96 198 30 -69 71 149 233 416 306 155 218 -13 -389 -295 -202 -295 28 212 -140 -311 -183 -67 -158 -108 -20 11 101 219 216 187 104 77 -148 -395 -470 -513 -536 -330 -159 -193 -196 -157 6 184 380 364 238 221 105 -2 12 32 -194 -262 -157 -164 -128 28 -129 -445 -431 -221 -306 -270 -246 -331 -329 -94 -94 -275 -216 -38 52 87 254 494 402 258 230 135 -32 -184 -386 -550 -592 -494 -159 -162 -411 -418 -363 -261 49 189 93 60 208 277 324 538 595 320 165 114 22 74 333 333 150 180 83 -10 201 109 -216 -218 -175 -327 83 288 63 1 207 224 216 285 273 210 137 -4 -223 -300 -230 -191 -189 -16 150 79 173 473 592 519 359 283 250 25 -140 -136 -165 -238 -97 196 30 -70 73 152 239 428 315 160 222 -13 -383 -294 -201 -298 27 216 -145 -324 -189 -68 -161 -110 -21 11 104 222 220 190 105 79 -149 -390 -470 -506 -531 -321 -158 -196 -203 -158 6 185 383 368 241 223 105 -2 12 32 -191 -256 -153 -162 -126 27 -128 -440 -420 -212 -293 -258 -237 -321 -322 -93 -93 -275 -216 -38 52 87 256 500 406 258 224 128 -30 -173 -359 -511 -559 -480 -154 -162 -406 -416 -359 -257 48 188 93 61 213 285 335 540 601 323 166 117 22 74 332 333 151 181 83 -10 202 109 -214 -214 -170 -320 82 288 64 1 211 230 224 297 285 219 142 -4 -226 -301 -230 -192
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