File name: Pandora133s1_Heidelberg_20250805_L2Fit_fout2c4d20240611p1-8.txt File generation date: 20250805T233837.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Andre Butz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 133 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora133_OF_v2d20240405.txt Instrument calibration file used: Pandora133s1_CF_v4d20240611.txt Level 1 file used: Pandora133s1_Heidelberg_20250805_L1_smca1c4d20240611p1-8.txt Full location name: Institute of Environmental Physics, Heidelberg University Short location name: Heidelberg Country of location: Germany Location latitude [deg]: 49.4173 Location longitude [deg]: 8.6746 Location altitude [m]: 144 Local noon date: 20250805 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1331 305.2741 305.4152 305.5562 305.6973 305.8383 305.9793 306.1203 306.2613 306.4023 306.5432 306.6842 306.8251 306.9661 307.1070 307.2479 307.3888 307.5297 307.6705 307.8114 307.9523 308.0931 308.2339 308.3747 308.5155 308.6563 308.7971 308.9379 309.0787 309.2194 309.3601 309.5009 309.6416 309.7823 309.9230 310.0636 310.2043 310.3450 310.4856 310.6262 310.7669 310.9075 311.0481 311.1886 311.3292 311.4698 311.6103 311.7509 311.8914 312.0319 312.1724 312.3129 312.4534 312.5939 312.7343 312.8748 313.0152 313.1556 313.2960 313.4364 313.5768 313.7172 313.8576 313.9979 314.1383 314.2786 314.4189 314.5592 314.6995 314.8398 314.9801 315.1203 315.2606 315.4008 315.5410 315.6813 315.8215 315.9617 316.1018 316.2420 316.3822 316.5223 316.6624 316.8026 316.9427 317.0828 317.2229 317.3629 317.5030 317.6431 317.7831 317.9231 318.0631 318.2031 318.3431 318.4831 318.6231 318.7631 318.9030 319.0429 319.1829 319.3228 319.4627 319.6026 319.7424 319.8823 320.0222 320.1620 320.3018 320.4417 320.5815 320.7213 320.8611 321.0008 321.1406 321.2803 321.4201 321.5598 321.6995 321.8392 321.9789 322.1186 322.2583 322.3979 322.5376 322.6772 322.8168 322.9564 323.0960 323.2356 323.3752 323.5148 323.6543 323.7939 323.9334 324.0729 324.2124 324.3519 324.4914 324.6309 324.7703 324.9098 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250805T061108.9Z 9348.257741 110 1 3.12 2 70.85 86.15 150.51 303.96 0.00 1 0.00 1 0 17 3.375e-02 6.970e-03 2.158e-02 2.624e-03 3.779517e-01 1.359625e-03 4.714558e-03 -6.000000e+00 1.980080e-02 232.75 -2.00 3.74 -2.00 318.90 0.00e+00 1.382121e-03 3.038753e-04 5.135666e-04 -6.000000e+00 8.591002e-04 283.89 -2.00 20.00 -2.00 318.15 0.00e+00 3.012 0.001 302.00 328.00 3 1.9890e+00 3.7647e-03 3.6631e-02 -6.0000e+00 4.9773e-02 3.8269e-03 4.3094e-03 2.1368e-02 -6.0000e+00 5.3757e-02 -3.8967e-03 3.0455e-03 1.0482e-02 -6.0000e+00 3.1902e-02 -4.6335e-03 1.5964e-03 3.0415e-03 -6.0000e+00 1.3548e-02 2.3948e-03 -6.1286e-04 7.7128e-05 3.2264e-05 -6.0000e+00 9.2456e-04 -2.9224e-03 0.0000e+00 12 9 1 12 1 1 -112.22 23.45 0.14 -0.00292 -0.00753 20 107 4 8 0 125.660 20.01 23.45 26.56 27.05 27.35 1.5 908.79 -15694 -6231 -14265 -11760 -14910 -5579 -16960 -6936 -5562 -3494 -3130 -5697 -7323 -419 1850 -809 -626 644 -106 -3108 -1655 846 -419 -826 -1135 -2848 -1610 -3667 -604 -1329 631 635 1087 -3140 -4897 -3586 -1847 808 -571 -384 -191 -912 -226 -76 1594 1001 -1533 361 -1702 319 1605 1663 1268 602 839 1299 -138 326 101 930 790 1572 2395 1964 -263 -90 -1483 -421 1287 1300 878 994 960 238 -239 -492 -2647 -1887 -1097 -1457 -1258 -1323 -2167 -748 -466 393 590 941 970 562 416 -156 -923 16 -684 -398 711 681 -140 -32 -928 -1209 -701 -442 -1294 -1247 -560 -234 521 711 671 189 56 -399 -334 155 -33 447 488 112 115 411 898 852 272 -519 295 414 -121 188 -205 -409 -153 4 131 -266 656 257 -32 -150 -149 -954 -594 -233 -584 -428 -515 -194 -679 -284 -248 -158 -143 -300 -467 -30 149 -74 -61 66 -12 -362 -191 96 -51 -108 -157 -415 -227 -495 -77 -183 95 107 199 -590 -884 -673 -390 198 -160 -123 -66 -330 -84 -28 589 373 -582 134 -653 127 686 764 587 297 425 673 -74 170 52 481 435 944 1567 1277 -168 -57 -931 -270 858 976 707 814 765 180 -165 -325 -1684 -1219 -790 -1135 -1102 -1202 -2097 -759 -482 427 666 1077 1088 594 427 -149 -849 16 -725 -448 893 890 -187 -41 -1164 -1401 -796 -537 -1698 -1628 -767 -339 767 1125 1060 298 88 -586 -481 218 -48 653 760 181 183 639 1342 1271 390 -717 420 598 -183 303 -348 -684 -265 8 243 -512 1283 511 -63 -281 -281 -1755 SS 20250805T061726.0Z 9348.262106 113 1 46.79 2 69.83 87.33 151.30 306.10 0.00 1 0.00 1 0 17 2.907e-02 6.998e-03 1.563e-02 1.785e-03 3.637782e-01 9.259372e-04 4.548550e-03 -6.000000e+00 1.705481e-02 232.75 -2.00 3.74 -2.00 319.13 0.00e+00 9.956575e-04 2.203998e-04 5.714412e-04 -6.000000e+00 7.399528e-04 283.89 -2.00 20.00 -2.00 318.39 0.00e+00 2.869 0.000 302.00 328.00 3 3.9408e+00 2.5874e-03 3.5071e-02 -6.0000e+00 4.2870e-02 7.8413e-03 2.9813e-03 2.0690e-02 -6.0000e+00 4.6301e-02 8.9444e-03 2.1447e-03 1.0140e-02 -6.0000e+00 2.7477e-02 -9.2957e-03 1.1209e-03 2.8602e-03 -6.0000e+00 1.1669e-02 3.9376e-04 -4.9584e-04 5.3269e-05 3.1336e-05 -6.0000e+00 7.9633e-04 -3.0189e-03 0.0000e+00 11 8 0 10 0 0 99.98 23.46 0.17 -0.00302 -0.00674 121 35 1 8 0 383.420 20.01 23.46 26.94 27.15 27.35 1.5 912.15 -9233 -6212 -2621 2618 -9867 -5293 -14962 -6169 -4191 -4219 -14157 -10397 -1325 -4847 -3536 685 -131 2116 3194 2160 -2532 -3926 -695 -8 -1781 -756 -3209 -1579 -2349 3092 1746 9 1019 -4686 -4952 -2107 -4169 -2602 -543 6 -569 -926 -400 -304 1198 624 -991 -158 -1580 653 655 1309 1314 601 979 591 467 1452 329 83 1690 1904 2415 2328 -356 65 -1056 -675 1304 1253 734 1312 643 375 -728 -775 -2239 -1691 -981 -1370 -1485 -1435 -1964 -1055 -333 -48 129 1034 703 643 802 62 -627 29 33 0 953 721 -52 -227 -990 -1536 -673 -531 -1374 -1125 -721 -506 316 602 833 303 281 -443 -435 161 -176 265 367 -23 329 711 648 459 578 -706 671 562 128 -48 -529 -329 -308 159 -105 -89 750 176 60 -102 -208 -887 -320 -227 -93 82 -318 -170 -578 -247 -182 -189 -702 -555 -77 -339 -281 57 -12 197 309 220 -271 -430 -78 -1 -226 -99 -423 -194 -283 376 236 1 168 -804 -804 -350 -800 -588 -143 2 -180 -308 -136 -104 406 215 -344 -54 -554 236 255 543 576 281 469 292 234 708 159 41 871 1063 1453 1469 -222 38 -615 -404 840 899 559 1011 486 272 -491 -477 -1328 -1017 -650 -1019 -1218 -1275 -1833 -1027 -344 -51 145 1168 781 683 790 58 -570 27 34 0 1152 937 -68 -291 -1207 -1771 -758 -635 -1756 -1488 -992 -720 475 952 1357 492 441 -662 -618 226 -253 397 577 -37 528 1122 998 678 832 -992 918 813 198 -78 -899 -569 -547 295 -203 -177 1506 357 120 -199 -396 -1665 SS 20250805T063230.2Z 9348.272572 117 1 3.29 2 67.38 90.17 153.12 311.62 0.00 1 0.00 1 0 17 5.075e-02 1.214e-02 5.189e-02 9.419e-03 3.276538e-01 4.868606e-03 4.082899e-03 -6.000000e+00 2.977254e-02 232.75 -2.00 3.74 -2.00 318.23 0.00e+00 1.838314e-03 8.973150e-04 1.092972e-04 -6.000000e+00 1.291705e-03 283.89 -2.00 20.00 -2.00 317.48 0.00e+00 2.578 0.000 302.00 328.00 3 4.5921e+00 1.3221e-02 3.1467e-02 -6.0000e+00 7.4839e-02 2.5175e-02 1.4942e-02 1.8500e-02 -6.0000e+00 8.0827e-02 1.7831e-02 9.7483e-03 8.9813e-03 -6.0000e+00 4.7967e-02 -1.3201e-02 5.0324e-03 2.8800e-03 -6.0000e+00 2.0372e-02 2.7973e-04 -7.4130e-04 2.7551e-04 2.9189e-05 -6.0000e+00 1.3901e-03 -3.2367e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.50 0.04 -0.00324 -0.00881 1 8 1 8 0 1639.240 20.00 23.50 27.18 27.15 27.45 1.4 910.32 -25230 2579 -9141 2800 -10534 -2801 2040 5609 6079 -736 9339 18592 -4523 -3121 953 788 5446 -3394 2883 2263 33658 -2282 -3480 -589 686 -5073 -2993 3776 -11934 -2818 17245 1227 -1741 2627 -4123 -12452 1520 2126 -2321 541 297 -1798 -376 -1406 2898 -1392 -3332 855 1552 -2367 -1999 2078 4143 345 821 -41 1139 2294 548 844 2467 1772 1584 444 -1138 -776 -1513 -1472 3911 1007 1371 -851 -388 -944 1023 -2736 -2101 -2265 761 -1991 -2538 -1700 -2767 -282 -442 -90 1225 825 1189 698 261 525 638 -471 1776 -341 1037 -12 892 -47 954 -1221 30 -714 -1997 -2019 547 -549 1303 716 1244 -115 -152 -1374 154 -1444 -312 482 -417 -399 1290 345 1058 366 703 -865 -331 164 -406 -970 -132 -72 489 -1 256 -257 1237 -397 358 259 13 -1263 -1781 152 -601 152 -592 -150 114 340 402 -53 617 1249 -436 -349 117 106 739 -529 442 363 4049 -385 -622 -108 130 -1053 -595 666 -2367 -544 3028 271 -428 610 -964 -3292 398 647 -855 219 127 -813 -172 -655 1311 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