File name: Pandora105s1_Helsinki_20240304_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T074556.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240304_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240304T074410.4Z 8829.322343 175 1 27.66 2 74.11 136.34 95.66 216.46 0.00 1 0.00 1 0 25 2.152e-01 8.136e-03 2.556e-01 6.548e-03 5.852030e-01 3.490822e-03 8.133179e-03 -6.000000e+00 1.248764e-01 223.36 -2.00 4.26 -2.00 320.44 0.00e+00 1.680516e-03 1.121821e-03 4.834104e-04 -6.000000e+00 5.104740e-03 261.99 -2.00 20.00 -2.00 320.14 0.00e+00 3.590 0.001 302.00 328.00 3 3.3898e+00 9.8735e-03 5.0866e-02 -6.0000e+00 3.1039e-01 1.3962e-01 1.2318e-02 3.6489e-02 -6.0000e+00 3.3861e-01 -5.7442e-02 1.2939e-02 1.9720e-02 -6.0000e+00 1.9939e-01 9.0139e-03 6.7700e-03 6.3453e-03 -6.0000e+00 8.3674e-02 2.4467e-04 -6.5597e-04 1.8222e-04 6.2934e-05 -6.0000e+00 5.6912e-03 2.2951e-02 -7.3495e-05 12 9 1 12 1 1 99.97 16.45 -0.02 0.02295 0.01802 9 4 1 5 0 2765.420 19.64 14.99 16.45 5.66 28.8 996.51 122141 -118883 -8114 -32851 40504 -53686 64773 -54250 16933 52749 -92582 -19345 -46348 -19496 -25653 736 -14517 -1669 20919 34840 14913 -18306 -12356 18457 5901 -18939 -12600 9513 -25326 -9906 16285 376 -4074 -10743 -12933 -16315 -1807 -8721 288 -1393 4652 -2024 2497 -479 -5061 -1942 4459 204 2464 3205 -3601 1192 2939 4154 2623 1945 -80 2025 -23 157 2977 -2778 2345 2229 74 -363 3240 -1315 -418 2014 810 1895 899 709 4108 -133 -1404 -2792 -529 286 -1599 -1377 -2732 -1226 -1611 66 -1231 1431 531 1950 520 -48 219 -586 -605 -536 899 593 705 -754 -560 -1142 65 562 -121 -881 -89 -869 -226 3 721 122 -343 -754 90 459 351 -123 198 230 19 -376 -151 83 917 405 -356 474 52 945 423 -569 -519 -152 115 -203 -12 1026 126 -459 -183 -642 780 -2140 -53 -256 259 -487 414 -647 113 337 -1972 -239 -927 -379 -644 17 -414 -46 494 762 398 -673 -465 569 220 -937 -586 346 -1290 -481 734 23 -292 -829 -969 -1309 -144 -897 33 -186 643 -313 387 -77 -869 -330 724 36 439 611 -823 282 741 1106 738 572 -24 597 -7 46 900 -986 893 927 31 -146 1249 -560 -201 1066 455 1073 494 367 1875 -58 -596 -1271 -271 169 -1088 -1025 -2154 -1004 -1400 59 -1170 1333 487 1677 426 -38 168 -483 -563 -562 1033 754 914 -952 -650 -1206 66 613 -140 -1070 -112 -1164 -329 5 1195 205 -566 -1187 134 672 525 -194 328 382 32 -593 -233 124 1316 561 -492 709 86 1672 789 -1097 -1038 -320 253 -456 -28 2332 285 -997 -380 -1286 SS 20240304T083351.7Z 8829.356848 203 1 50.59 2 70.34 148.70 99.61 226.29 0.00 1 0.00 1 0 17 1.268e-01 8.401e-03 1.008e-01 5.552e-03 4.846441e-01 2.924169e-03 6.902154e-03 -6.000000e+00 7.356182e-02 223.37 -2.00 4.26 -2.00 320.01 0.00e+00 1.055620e-03 8.167119e-04 3.140340e-04 -6.000000e+00 3.007614e-03 261.99 -2.00 20.00 -2.00 319.71 0.00e+00 2.940 0.001 302.00 328.00 3 3.8862e+00 8.1100e-03 4.1885e-02 -6.0000e+00 1.8284e-01 1.2831e-01 9.5708e-03 2.9976e-02 -6.0000e+00 1.9948e-01 -5.2375e-02 8.7465e-03 1.5723e-02 -6.0000e+00 1.1746e-01 1.0552e-02 4.6687e-03 4.8920e-03 -6.0000e+00 4.9282e-02 3.1127e-04 -7.3470e-04 1.5875e-04 4.9946e-05 -6.0000e+00 3.3545e-03 2.3091e-02 -1.2279e-04 11 8 0 10 0 0 99.99 16.48 0.17 0.02309 0.01757 35 7 1 5 0 1445.080 19.75 15.00 16.48 5.75 28.9 996.61 -26400 -70456 -23487 -52713 -8025 -62761 30123 -55662 4254 -34764 3578 -28038 34341 -10477 3511 2843 -9833 -5525 -7213 -12957 -11819 -6368 -11844 5858 -4445 -3732 7713 10520 -2001 673 -3739 7411 4381 -1353 -506 -10428 -2683 -6487 -3089 -3815 2726 -2374 5353 -241 1560 99 3163 1886 1427 1389 1211 1472 471 3222 -2615 1641 286 2547 -813 1986 3049 1650 3793 2988 59 -2645 -197 -765 -821 294 1290 -1091 585 1345 666 497 -1072 -1590 1126 -1125 -279 -1699 -3045 -1228 -577 -264 -8 878 793 679 750 846 33 612 77 -218 600 1499 -213 -220 -308 -1359 -454 -230 -633 -1072 -1178 -1948 -363 138 763 270 -97 -92 -161 -211 -167 207 639 -95 -157 249 272 345 1147 22 370 817 1046 635 182 -546 -247 -328 323 -675 593 -5 111 -100 186 -1163 -427 -1942 -428 -1181 -107 -1443 316 -1535 74 -910 67 -799 650 -370 129 118 -498 -289 -405 -807 -732 -376 -775 355 -316 -277 501 639 -134 48 -317 642 438 -142 -49 -1157 -315 -957 -527 -751 542 -521 1122 -54 349 23 706 433 337 348 336 443 154 1084 -963 599 107 912 -293 705 1137 684 1714 1462 29 -1251 -90 -367 -446 178 815 -713 363 784 353 242 -506 -784 618 -722 -201 -1344 -2563 -1070 -535 -258 -8 887 784 639 653 693 27 517 72 -233 707 1912 -283 -281 -357 -1455 -479 -259 -763 -1349 -1539 -2717 -538 223 1291 459 -159 -141 -232 -302 -246 319 1039 -159 -254 389 417 507 1629 31 499 1182 1658 1097 327 -1014 -476 -666 690 -1477 1300 -11 244 -210 375 -2266 SS 20240304T095456.2Z 8829.413151 251 1 50.23 2 66.77 170.03 107.46 241.94 0.00 1 0.00 1 0 25 1.855e-01 2.019e-02 2.314e-01 1.683e-02 4.001408e-01 8.911553e-03 5.789464e-03 -6.000000e+00 1.099551e-01 223.37 -2.00 4.26 -2.00 319.59 0.00e+00 4.136810e-04 2.203797e-03 2.172608e-04 -6.000000e+00 4.610665e-03 262.00 -2.00 20.00 -2.00 319.28 0.00e+00 2.517 0.000 302.00 328.00 3 5.5204e+00 2.4395e-02 3.5184e-02 -6.0000e+00 2.7380e-01 5.8155e-02 2.8245e-02 2.4752e-02 -6.0000e+00 2.9937e-01 2.9387e-02 2.3906e-02 1.2871e-02 -6.0000e+00 1.7374e-01 -1.7015e-02 1.2858e-02 3.9499e-03 -6.0000e+00 7.2088e-02 1.0258e-04 -6.0626e-06 5.0268e-04 4.0033e-05 -6.0000e+00 5.0149e-03 2.2595e-02 -2.2319e-04 12 8 8 10 0 0 99.95 16.51 0.69 0.02259 0.02255 41 8 1 5 0 1224.810 19.75 15.00 16.51 6.51 28.8 1002.92 40474 38083 23721 -39809 900000 900000 900000 -65702 900000 -47095 76874 53257 78271 29393 21960 56 22914 -17165 -17468 23210 6165 83662 -5930 24714 -19212 -4595 -10401 63231 -31040 13270 2484 6303 7685 8296 -4537 -5198 10305 -10511 -10232 -3206 20932 -4897 9364 10944 11852 -4155 2947 -9892 3981 -9020 3010 1313 2323 -882 -2033 -454 -2581 6673 695 3728 -4840 2158 1118 3545 -2199 572 528 -50 2383 -1079 4223 747 1712 -3315 5291 -4531 5956 -4498 3903 -6078 1276 -1019 821 -2879 -2112 -1797 -1881 1325 -420 1290 363 6581 -4025 3004 -905 1974 -2280 3591 -1288 1105 -849 -468 -1687 -1308 1530 -2428 -594 -1075 3133 946 1945 -964 615 -1610 -700 -1206 -430 115 256 -889 -1498 1282 -174 2663 -1032 1852 -2421 1907 -711 1166 -710 870 -482 -979 1774 -404 1219 -708 665 -1297 546 -983 664 624 448 -1261 900000 900000 900000 -3244 900000 -2230 1260 1102 1531 1082 1010 4 1222 -1426 -1532 1452 455 2972 -524 1770 -2230 -482 -1128 3246 -3757 1123 265 720 955 1018 -584 -702 1383 -2055 -2405 -798 4434 -1388 2363 2724 2988 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