File name: Pandora105s1_Helsinki_20240307_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T075017.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240307_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240307 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240307T055352.3Z 8832.245744 72 1 51.23 2 84.37 110.55 88.49 154.74 0.00 1 0.00 1 0 25 3.988e-01 4.068e-02 3.931e-01 3.851e-02 9.733288e-01 2.305186e-02 1.300153e-02 -6.000000e+00 2.336346e-01 223.62 -2.00 4.26 -2.00 322.07 0.00e+00 -1.110800e-02 7.945759e-03 1.138118e-03 -6.000000e+00 9.737923e-03 262.23 -2.00 20.00 -2.00 321.68 0.00e+00 9.006 0.019 302.00 328.00 3 -1.3472e-01 7.1431e-02 1.0855e-01 -6.0000e+00 5.8100e-01 1.8194e+00 8.2769e-02 6.0079e-02 -6.0000e+00 6.3487e-01 -1.9394e+00 6.3534e-02 3.2408e-02 -6.0000e+00 3.7245e-01 6.9823e-01 3.5590e-02 1.0954e-02 -6.0000e+00 1.5689e-01 2.8214e-05 -1.9718e-03 1.0539e-03 1.4127e-04 -6.0000e+00 1.0636e-02 2.5435e-02 -4.7122e-05 12 8 8 10 0 0 55.26 16.28 0.27 0.02544 0.01062 24 5 1 5 0 2134.310 19.54 15.01 16.28 1.72 28.2 965.19 25718 900000 -1959 226091 -50679 900000 42534 -39531 198755 2197 -59192 -38530 131261 900000 96589 13536 16917 -24170 -10236 7487 27685 9573 35177 -34205 40842 60092 10757 18953 -35653 -47535 -53005 900000 21367 16113 -40171 52151 11053 -44156 5331 79252 2887 7072 82063 53919 25133 -14581 13032 -10314 900000 39402 51306 38766 70644 44793 40694 30697 61980 5944 -34081 53457 -24501 5043 5569 14278 -8739 36487 -18124 28823 21176 17484 51621 43832 6935 -2358 -15522 -39762 34156 4336 -81 6548 3909 -25221 12117 -2249 11857 6104 3274 639 9473 -6468 11585 -10068 -10526 982 -5897 4570 7355 1449 2261 1246 -6107 5241 -10400 2244 -4191 5467 -3124 -3859 -3917 1312 731 -1675 -1540 -3067 1604 -1824 -2326 -2517 3812 2856 2119 -114 6646 8236 -681 -1850 -1005 2658 -2287 838 -3197 252 -2124 3081 198 2114 -755 819 -906 -347 -2368 850 1354 900000 -122 8482 -3469 900000 1596 -2701 7456 108 -5155 -2891 4924 900000 3624 923 1131 -2440 -866 510 1404 539 1643 -3493 2110 2510 662 926 -2726 -4340 -5855 900000 1434 1093 -4151 2148 734 -5907 531 4372 347 832 4467 3609 2108 -1715 1170 -1176 900000 3130 4038 3764 5459 4679 4610 3974 5952 914 -6934 4372 -4343 734 918 2395 -1858 4900 -4240 4628 4128 3948 8831 8024 1673 -568 -3715 -10734 4550 836 -19 1749 1250 -12022 4346 -956 4697 2613 1479 294 3923 -2941 4138 -4366 -4747 447 -3402 2784 4967 1184 1928 1029 -4865 3315 -7257 1473 -3145 3893 -2590 -3564 -4194 1556 958 -2378 -2201 -4339 2121 -2478 -3300 -3783 5614 4194 2945 -154 8183 9987 -865 -2336 -1274 3689 -3962 1611 -7028 574 -5326 7943 562 6013 -2225 2388 -2598 -918 -5852 1934 SS 20240307T060440.6Z 8832.253248 75 1 50.50 2 83.12 112.95 87.94 157.04 0.00 1 0.00 1 0 33 5.317e-01 3.214e-02 4.190e-01 2.470e-02 8.755094e-01 1.454003e-02 1.168126e-02 -6.000000e+00 3.130851e-01 223.62 -2.00 4.26 -2.00 322.05 0.00e+00 7.809269e-03 5.956473e-03 1.263843e-03 -6.000000e+00 1.294376e-02 262.23 -2.00 20.00 -2.00 321.70 0.00e+00 7.655 0.011 302.00 328.00 3 6.1628e-01 4.6067e-02 9.3984e-02 -6.0000e+00 7.7929e-01 1.2516e+00 5.5151e-02 5.4817e-02 -6.0000e+00 8.5088e-01 -1.5594e+00 4.8286e-02 2.9514e-02 -6.0000e+00 4.9959e-01 6.3721e-01 2.5623e-02 1.0019e-02 -6.0000e+00 2.0852e-01 5.7326e-05 -1.9514e-03 7.0660e-04 1.3721e-04 -6.0000e+00 1.4554e-02 2.4798e-02 2.5410e-05 12 8 8 10 0 0 99.90 16.30 0.27 0.02480 0.01013 50 10 1 5 0 1009.760 19.54 15.01 16.30 2.10 28.2 967.64 101166 -13488 20236 -48154 8134 -124842 900000 -85906 -93651 32612 -87602 62866 9867 900000 -53407 900000 -23332 56452 -43039 26402 41204 61348 15777 32529 97384 96685 900000 -49472 900000 12653 287218 -3628 14806 23568 298799 -4870 90360 -45488 31540 101450 89145 32369 43172 161939 10001 105406 13235 47131 -5804 34586 34113 38909 39078 38783 19266 28568 57316 19792 22597 26503 72042 13564 31506 22698 56438 24374 44410 -11302 9531 13143 12453 8205 -10069 3901 -5529 -6523 -6036 7128 -4701 -3024 -6080 8481 -5008 2141 -2980 5123 1487 12375 6189 1673 -1742 -13231 -8314 -9111 949 -5139 4730 -3606 581 -1260 3328 -7365 -7110 -4302 -1881 -4783 -4939 -3971 -2191 1681 -3470 15 772 33 419 -141 -1048 2900 -447 2588 618 1599 5848 -149 3689 -99 1737 1257 2333 417 2443 -331 -268 -1830 1499 -2320 796 67 527 -2 -1499 -985 2435 -502 532 -2119 196 -8584 900000 -4052 -4748 785 -3907 1513 244 900000 -3633 900000 -1411 1642 -3275 997 1239 1476 548 981 2344 2327 900000 -2828 900000 444 6912 -210 793 1142 7190 -270 2174 -4561 1746 3149 3296 2137 2582 3897 808 3395 1060 2844 -613 2654 2927 3460 3707 3882 2351 3258 4838 2299 2396 2625 4891 1807 4033 3554 6491 3698 5689 -2611 2048 3054 3052 2087 -2884 891 -1226 -1329 -1217 1408 -1235 -937 -2224 3029 -2183 910 -1412 2350 733 5492 2849 771 -779 -6405 -3903 -4842 533 -3616 3522 -3295 546 -1160 2632 -5676 -5240 -3290 -1507 -4123 -4486 -3926 -2442 2085 -5032 22 1123 47 567 -190 -1487 4195 -703 3929 907 2236 7661 -202 4715 -126 2226 1829 3954 817 5116 -747 -644 -4799 4046 -6644 2224 190 1440 -4 -3627 -2212 SS 20240307T131450.4Z 8832.551972 322 1 50.39 2 72.60 223.18 105.08 248.17 0.00 1 0.00 1 0 17 7.559e-02 6.543e-03 4.998e-02 2.956e-03 4.486129e-01 1.549971e-03 6.360517e-03 -6.000000e+00 4.392037e-02 223.64 -2.00 4.26 -2.00 319.86 0.00e+00 1.463940e-03 4.162234e-04 2.819392e-04 -6.000000e+00 1.792679e-03 262.25 -2.00 20.00 -2.00 319.55 0.00e+00 3.298 0.001 302.00 328.00 3 2.6182e+00 4.2789e-03 4.2765e-02 -6.0000e+00 1.0924e-01 1.1280e-01 5.0113e-03 2.7736e-02 -6.0000e+00 1.1913e-01 -3.0687e-02 4.4713e-03 1.4497e-02 -6.0000e+00 7.0136e-02 -8.8777e-04 2.3950e-03 4.5056e-03 -6.0000e+00 2.9423e-02 8.4357e-04 -2.4125e-04 8.5145e-05 4.5160e-05 -6.0000e+00 1.9976e-03 2.1902e-02 -2.9316e-05 11 8 0 10 0 0 99.92 16.47 -0.08 0.02190 0.02009 83 16 1 5 0 606.950 19.75 15.01 16.47 5.79 28.6 997.10 -43283 21645 -29517 27261 -33764 5776 -21948 -18014 -4733 -17978 -4236 -17438 8162 -19904 -3219 -5587 12897 -4095 3729 1021 10 138 2012 -1063 412 2168 1799 7326 -3937 2427 -4745 7335 -3195 4218 -5897 214 -7084 -2434 -3731 -633 -956 -1302 -629 -1215 -1252 -2454 7 -1287 2022 -1698 3670 -514 1493 1329 2851 948 1074 1240 203 1449 -469 1104 662 2571 -90 653 -2845 -150 -91 1523 -96 1608 572 1344 747 114 -2 -1431 -142 -1589 -456 -2313 -2175 -2044 -345 -441 601 501 824 614 904 585 -498 282 38 454 558 1164 66 84 -846 -126 -864 660 -466 -842 -709 -791 -445 40 370 -229 57 -410 -235 -99 79 108 570 -340 -68 131 496 242 636 -75 -247 1048 345 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