File name: Pandora105s1_Helsinki_20240508_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T082437.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240508_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T025923.5Z 8894.124578 94 1 50.87 2 84.29 64.96 82.50 64.54 0.00 1 0.00 1 0 41 6.909e-01 8.074e-02 5.034e-01 6.781e-02 1.292913e+00 4.388983e-02 1.697169e-02 -6.000000e+00 4.190059e-01 230.64 -2.00 4.26 -2.00 321.91 0.00e+00 -3.603410e-02 1.063929e-02 7.218670e-04 -6.000000e+00 1.873826e-02 271.30 -2.00 20.00 -2.00 321.43 0.00e+00 8.885 0.018 302.00 328.00 3 -1.3675e-01 1.3203e-01 1.1967e-01 -6.0000e+00 1.0617e+00 3.0954e+00 1.4992e-01 7.6445e-02 -6.0000e+00 1.1560e+00 -2.7404e+00 8.9943e-02 3.8943e-02 -6.0000e+00 6.7133e-01 7.8457e-01 5.1026e-02 1.2214e-02 -6.0000e+00 2.7616e-01 1.4173e-05 -5.3856e-04 1.5930e-03 1.3195e-04 -6.0000e+00 1.9066e-02 2.5617e-02 -3.3281e-06 12 8 8 10 0 0 16.82 16.33 0.71 0.02562 0.02157 18 4 1 5 0 2825.410 19.54 15.01 16.33 999.00 -9.0 -9.00 158765 154901 138763 -6215 -63476 110933 -5141 900000 136285 900000 54347 181451 38622 900000 -13946 76150 114877 72718 23174 131218 10269 -55325 900000 9699 900000 -18212 900000 -78532 900000 -44387 108122 83404 900000 7075 338898 31930 259704 1055 28331 900000 108762 78747 60477 -2687 -65406 107701 89236 32532 -39087 900000 14212 65650 20872 -2594 25873 63273 96711 -46151 37505 -35571 11541 59191 91167 4099 104990 -28252 212442 21625 17173 80089 27837 29381 13518 -234 -40157 175818 -12775 37326 -22230 21481 -15728 53696 4896 -15419 42695 31777 41947 6502 10689 -30678 27106 -16636 5532 -33357 22665 8348 6804 4869 6740 -1980 -10596 -7458 -2800 840 -13617 13450 -8880 29744 -160 -1508 1848 11562 2245 -996 207 970 466 -2388 6421 -6505 7060 -3841 12377 -1868 5363 -4384 5466 -9293 2546 -4166 -471 -2190 -5027 1509 -1087 2357 -730 4636 -1310 732 -3592 4672 10476 10221 9156 -765 -11288 7320 -626 900000 8993 900000 5474 11973 4382 900000 -2777 6281 7580 5845 2758 8659 1133 -10952 900000 1489 900000 -4042 900000 -20445 900000 -7051 7135 5504 900000 821 22363 2465 17137 150 3809 900000 8143 7595 6216 -435 -17264 7107 5888 2890 -7490 900000 1966 6031 3178 -540 4334 7859 8509 -14934 4513 -7640 1493 5234 6617 769 7344 -7274 14018 4024 3755 10464 6319 6359 3086 -53 -11288 11602 -2461 4926 -6190 4592 -5729 11425 1784 -7143 11382 9604 11693 2446 3611 -14413 6899 -6455 1885 -19149 9034 4407 4238 3515 4981 -1513 -7747 -4590 -1527 467 -9278 7263 -6422 16463 -142 -1590 2156 13215 2898 -1316 262 1210 604 -3340 8586 -9289 8205 -4645 12467 -2138 5583 -4847 5794 -13440 3998 -8197 -1004 -5208 -13268 4095 -3246 6939 -2226 13679 -3920 1962 -9061 10055 SS 20240508T031031.4Z 8894.132308 97 1 50.04 2 83.02 67.31 81.25 66.76 0.00 1 0.00 1 0 33 5.512e-01 2.985e-02 4.503e-01 2.310e-02 1.229470e+00 1.473087e-02 1.573411e-02 -6.000000e+00 3.286504e-01 230.64 -2.00 4.26 -2.00 322.62 0.00e+00 1.320302e-03 6.248529e-03 2.088718e-03 -6.000000e+00 1.396040e-02 271.30 -2.00 20.00 -2.00 322.27 0.00e+00 7.553 0.011 302.00 328.00 3 1.0994e-01 4.9730e-02 1.1084e-01 -6.0000e+00 8.3033e-01 2.1248e+00 5.8820e-02 7.7935e-02 -6.0000e+00 9.0115e-01 -2.4859e+00 4.8468e-02 4.1832e-02 -6.0000e+00 5.2824e-01 9.2845e-01 2.6939e-02 1.4353e-02 -6.0000e+00 2.1972e-01 5.6921e-05 -1.8753e-03 5.9972e-04 2.0791e-04 -6.0000e+00 1.4745e-02 2.6023e-02 2.1027e-06 12 8 8 10 0 0 31.55 16.34 0.40 0.02602 0.01193 46 9 1 5 0 1087.560 19.64 15.01 16.34 999.00 -9.0 -9.00 312105 -1277 900000 43267 -83545 -105161 106147 -77783 -28615 -45240 900000 -35380 199418 17625 97115 50913 -3055 -5649 -27654 -14097 87269 -16145 -60454 106855 89914 118113 -52955 18394 -58938 -1850 -21888 87806 33651 202351 27521 21591 27621 -24505 22565 -9070 52696 -1392 178318 24054 39441 -39567 134075 39883 101051 3204 67211 56922 27887 30494 45361 92240 17794 -366 6914 63646 5020 46655 -10901 18386 23776 37977 31063 21019 38844 26814 21473 17812 20615 -556 50758 -10989 7987 13737 2866 2004 18766 -798 5603 -699 11531 5426 8383 8858 3445 12637 -11660 11335 -17188 12256 -9953 2087 -6193 1420 -309 -915 673 -8722 -1113 -9977 -4606 -6903 1008 -4909 -3665 -1924 269 -3734 2954 -1313 1523 -3167 -842 7 -1847 1927 573 2100 3030 8281 -631 4687 -1009 2273 -540 4424 401 7 -635 -384 -571 497 212 614 715 -839 -183 -3014 7028 -55 900000 974 -4860 -6709 2390 -3649 -879 -1574 900000 -1231 4490 541 2187 1459 -156 -301 -1755 -721 1965 -661 -3836 2406 2025 2660 -2710 414 -2775 -57 -1031 1977 1171 4557 845 663 848 -1455 970 -594 1942 -88 4015 1192 1599 -3159 3019 1706 2503 231 2876 2948 2072 2335 3064 3946 1563 -35 560 2723 396 2732 -1326 1904 2409 3335 3078 2509 4461 3864 3385 2848 2925 -85 4000 -1460 899 1670 478 411 3845 -228 1615 -224 3401 1759 2700 2812 1109 3472 -3860 2961 -6348 3947 -4886 1095 -4197 1036 -244 -700 450 -5460 -594 -6133 -2863 -4585 665 -3869 -3392 -2097 329 -5129 3897 -1791 1965 -4286 -1163 10 -2811 2737 759 2554 3569 9118 -746 5087 -1193 3107 -928 8468 895 17 -1699 -1113 -1769 1546 661 1907 2123 -2313 -450 -6977 SS 20240508T032151.7Z 8894.140182 100 1 50.45 2 81.71 69.70 79.96 69.02 0.00 1 0.00 1 0 17 5.192e-01 2.022e-02 3.641e-01 9.837e-03 1.119100e+00 5.921377e-03 1.413526e-02 -6.000000e+00 3.094927e-01 230.64 -2.00 4.26 -2.00 322.42 0.00e+00 6.383545e-03 2.745100e-03 2.126713e-03 -6.000000e+00 1.231405e-02 271.30 -2.00 20.00 -2.00 322.07 0.00e+00 6.515 0.007 302.00 328.00 3 1.7902e-01 2.0098e-02 9.9435e-02 -6.0000e+00 7.8219e-01 1.2836e+00 2.9527e-02 7.4330e-02 -6.0000e+00 8.4885e-01 -1.6345e+00 3.2314e-02 4.2432e-02 -6.0000e+00 4.9714e-01 6.4192e-01 1.5513e-02 1.4956e-02 -6.0000e+00 2.0547e-01 1.8853e-04 -1.6555e-03 2.5641e-04 1.9308e-04 -6.0000e+00 1.3751e-02 2.5626e-02 1.1286e-05 12 8 8 10 0 0 0.26 16.34 0.18 0.02563 0.01319 94 18 1 5 0 536.600 19.64 15.00 16.34 999.00 -9.0 -9.00 -164030 -27355 -91215 -28600 -140010 -135875 -87996 -149031 -166098 -147272 -90558 -169339 -130512 -127939 -64903 -90294 12091 -85874 -37219 -51896 18056 -11881 -33827 16486 -33718 -44834 10754 -59222 -80684 -9282 -58549 70458 -26533 122542 -32580 13221 -39648 102948 26205 101074 45342 26650 46742 17816 22568 21574 53850 51104 44027 29767 104026 12872 73447 38900 59810 49470 61168 24016 15321 12930 9907 20819 19856 28547 21791 30480 15798 24579 11265 24907 27175 22623 19907 30273 24069 -5388 14522 -1242 11988 293 6637 1355 7724 316 4880 -375 5402 3378 6983 1666 1937 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